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Selective production of hydrogen by acetone steam reforming over Ni–Co/olivine catalysts

  • Sanchari Basu
  • Narayan C. PradhanEmail author
Article
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Abstract

Acetone steam reforming was carried out over olivine supported cobalt and nickel catalysts for producing hydrogen in high selectivity. The wet impregnation process was used for the preparation of the catalyst. The chemical and physical properties of synthesized catalysts were determined by BET, H2-TPR, SEM (coupled with EDS) and XRD. The reforming activity was examined at atmospheric pressure in a tubular reactor. The olivine supported bimetallic (Ni–Co) catalysts exhibited significant acetone steam reforming activity with around 99% conversion of acetone. Around 80% selectivity to hydrogen was obtained over bimetallic 5% (Ni25Co75)/olivine. A LHHW type kinetic model was established for the reforming process consisting of complex reaction networks. The activation energy for the LHHW model was found to be 63 kJ/mol.

Keywords

Steam reforming Acetone Olivine Nickel catalyst Hydrogen selectivity Kinetics 

Notes

Supplementary material

11144_2019_1542_MOESM1_ESM.doc (4 mb)
Supplementary material 1 (DOC 4065 kb)

References

  1. 1.
    Anzelmo B, Wilcox J, Liguori S (2017) Natural gas steam reforming reaction at low temperature and pressure conditions for hydrogen production via Pd/PSS membrane reactor. J Membr Sci 522:343–350CrossRefGoogle Scholar
  2. 2.
    Zhu L, Xie N, Jiang P, Li L, Chen H (2016) Double-stage chemical looping combustion combined with sorption enhanced natural gas steam reforming process for hydrogen and power cogeneration: thermodynamic investigation. Chem Eng Res Des 114:247–257CrossRefGoogle Scholar
  3. 3.
    Kechagiopoulos PN, Angeli SD, Lemonidou AA (2017) Low temperature steam reforming of methane: a combined isotopic and microkinetic study. Appl Catal B 205:238–253CrossRefGoogle Scholar
  4. 4.
    Ali S, Al-Marri MJ, Abdelmoneim AG, Kumar A, Khader MM (2016) Catalytic evaluation of nickel nanoparticles in methane steam reforming. Int J Hydrogen Energy 41:22876–22885CrossRefGoogle Scholar
  5. 5.
    Chou YS, Huang MH, Hsu NY, Jeng KT, Lee RY, Yen SC (2016) Development of ring-shape supported catalyst for steam reforming of natural gas in small SOFC systems. Int J Hydrogen Energy 41:12953–12961CrossRefGoogle Scholar
  6. 6.
    Alhamdani YA, Hassim MH, Ng RTL, Hurme M (2016) The estimation of fugitive gas emissions from hydrogen production by natural gas steam reforming. Int J Hydrogen Energy 42:9342–9351CrossRefGoogle Scholar
  7. 7.
    Fan J, Zhu L, Jiang P, Li L, Liu H (2016) Comparative exergy analysis of chemical looping combustion thermally coupled and conventional steam methane reforming for hydrogen production. J Clean Prod 131:247–258CrossRefGoogle Scholar
  8. 8.
    Gangadharan P, Kanchi KC, Lou HH (2012) Evaluation of the economic and environmental impact of combining dry reforming with steam reforming of methane. Chem Eng Res Des 90:1956–1968CrossRefGoogle Scholar
  9. 9.
    Azenha CSR, Pedrero CM, Queiros S, Concepcion P, Mendes A (2017) Innovative ZrO2-supported CuPd catalysts for the selective production of hydrogen from methanol steam reforming. Appl Catal B 203:400–407CrossRefGoogle Scholar
  10. 10.
    Liu D, Men Y, Wang J, Kolb G, Liu X, Wang Y, Sun Q (2016) Highly active and durable Pt/In2O3/Al2O3 catalysts in methanol steam reforming. Int J Hydrogen Energy 41:21990–21999CrossRefGoogle Scholar
  11. 11.
    Cao L, Lu M, Li G, Zhang S (2018) Hydrogen production from methanol steam reforming catalysed by Fe modified Cu supported on attapulgite clay. Reac Kinet Mech Cat 1:11–22.  https://doi.org/10.1007/s11144-018-1493-y Google Scholar
  12. 12.
    Bej B, Pradhan NC, Neogi S (2017) Production of hydrogen by steam reforming of ethanol over alumina supported nano-NiO/SiO2 catalyst. Catal Today 237:80–88CrossRefGoogle Scholar
  13. 13.
    Bepari S, Basu S, Pradhan NC, Dalai AK (2017) Steam reforming of ethanol over cerium-promoted Ni-Mg-Al hydrotalcite catalysts. Catal Today 291:47–57CrossRefGoogle Scholar
  14. 14.
    Bilal M, Jackson SD (2017) Ethanol steam reforming over Pt/Al2O3 and Rh/Al2O3 catalysts: the effect of impurities on selectivity and catalyst deactivation. Appl Catal A 529:98–107CrossRefGoogle Scholar
  15. 15.
    Song JH, Han SJ, Yoo J, Park S, Kim DH, Song IK (2016) Hydrogen production by steam reforming of ethanol overNi-Sr-Al2O3-ZrO2 aerogel catalyst. J Mol Catal A 424:342–350CrossRefGoogle Scholar
  16. 16.
    Bepari S, Pradhan NC, Dalai AK (2017) Selective production of hydrogen by steam reforming of glycerol over Ni/Fly ash catalyst. Catal Today 291:36–46CrossRefGoogle Scholar
  17. 17.
    Menor M, Sayas S, Chica A (2017) Natural sepiolite promoted with Ni as new and efficient catalyst for the sustainable production of hydrogen by steam reforming of the biodiesel by-products glycerol. Fuel 193:351–358CrossRefGoogle Scholar
  18. 18.
    Demsash HD, Mohan R (2016) Steam reforming of glycerol to hydrogen over ceria promoted nickel-alumina catalysts. Int J Hydrogen Energy 41:22732–22742CrossRefGoogle Scholar
  19. 19.
    Cichy M, Dobosz J, Borowiecki T, Zawadzki M (2017) Glycerol steam reforming over calcium deficient hydroxyapatite supported nickel catalysts. Reac Kinet Mech Cat 122:69–83CrossRefGoogle Scholar
  20. 20.
    Higo T, Saito H, Ogo S, Sugiura Y, Sekine Y (2017) Promotive effect of Ba addition on the catalytic performance of Ni/LaAlO3 catalysts for steam reforming of toluene. Appl Catal A 530:125–131CrossRefGoogle Scholar
  21. 21.
    Rached JA, Hayek CE, Dahdah E, Gennequin C, Aouad S, Tidahy HL, Estephane J, Nsouli B, Aboukaïs A, Aad EA (2017) Ni based catalysts promoted with cerium used in the steam reforming of toluene for hydrogen production. Int J Hydrogen Energy 42:12829–12840CrossRefGoogle Scholar
  22. 22.
    Hu X, Zhang L, Lu G (2016) Steam reforming of acetic acid over Cu-Zn-Co catalyst for hydrogen generation: synergistic effects of the metal species. Int J Hydrogen Energy 41:13960–13969CrossRefGoogle Scholar
  23. 23.
    Barman S, Pradhan NC, Acharya A, Pramanik P (2006) Kinetics of reductive isopropylation of benzene with acetone over nano-copper chromite-loaded H-mordenite. Ind Eng Chem Res 45:3481–3487CrossRefGoogle Scholar
  24. 24.
    Shutkina OV, Ponomareva OA, Kots PA, Ivanova II (2013) Selective hydrogenation of acetone in the presence of benzene. Catal Today 218:30–34CrossRefGoogle Scholar
  25. 25.
    Sun J, Mei D, Karim AM, Datye AK, Wang Y (2013) Minimizing the formation of coke and methane on Co nanoparticles in steam reforming of biomass-derived oxygenates. Chem Cat Chem 5:1299–1303Google Scholar
  26. 26.
    Navarro RM, Guil-Lopez R, Ismail AA, Al-Sayari SA, Fierro JLG (2015) Ni- and PtNi-catalysts supported on Al2O3 for acetone steam reforming: effect of the modification of support with Ce, La and Mg. Catal Today 242:60–70CrossRefGoogle Scholar
  27. 27.
    Braga AH, Sodre ER, Santos JBO, De Paula Marques CM, Bueno JMC (2016) Steam reforming of acetone over Ni- and Co-based catalysts: effect of the composition of reactants and catalysts on reaction pathways. Appl Catal B 195:16–28CrossRefGoogle Scholar
  28. 28.
    Guil-Lopez R, Navarro RM, Ismail AA, Al-Sayari SA, Fierro JLG (2015) Influence of Ni environment on the reactivity of Ni-Mg-Al catalysts for the acetone steam reforming reaction. Int J Hydrogen Energy 40:5289–5296CrossRefGoogle Scholar
  29. 29.
    Hu X, Zhang L, Lu G (2012) Pruning of the surface species on Ni/Al2O3 catalyst to selective production of hydrogen via acetone and acetic acid steam reforming. Appl Catal A 427:49–57CrossRefGoogle Scholar
  30. 30.
    Michel R, Łamacz A, Krzton A, Djéga-Mariadassou G, Burg P, Courson C, Gruber R (2013) Steam reforming of a-methylnaphthalene as a model tar compound over olivine and olivine supported nickel. Fuel 109:653–660CrossRefGoogle Scholar
  31. 31.
    Constantinou DA, Fierro JLG, Efstathiou AM (2010) A comparative study of the steam reforming of phenol towards H2 production over natural calcite, dolomite and olivine materials. Appl Catal B 95:255–269CrossRefGoogle Scholar
  32. 32.
    Virginie M, Courson C, Kiennemann A (2010) Toluene steam reforming as tar model molecule produced during biomass gasification with an iron/olivine catalyst. C R Chim 13:1319–1325CrossRefGoogle Scholar
  33. 33.
    Yang X, Xu S, Xu H, Liu X, Liu C (2010) Nickel supported on modified olivine catalysts for steam reforming of biomass gasification tar. Catal Commun 11:383–386CrossRefGoogle Scholar
  34. 34.
    Zhang R, Wang Y, Brown RC (2007) Steam reforming of tar compounds over Ni/olivine catalysts doped with CeO2. Energ Convers Manag 48:68–77CrossRefGoogle Scholar
  35. 35.
    Gou Y, Liang X, Chen B (2013) Porous Ni–Co bimetal oxides nanosheets and catalytic properties for CO oxidation. J Alloys Compd 574:181–187CrossRefGoogle Scholar
  36. 36.
    Sawierczynski D, Courson C, Bedel L, Kiennemann A, Vilminot S (2006) Oxidation reduction behavior of iron-bearing olivines (FexMg1-x)2SiO4 used as catalysts for biomass gasification. Chem Mater 18:897–905CrossRefGoogle Scholar
  37. 37.
    Wang G, Xu S, Jiang L, Wang C (2016) Nickel supported on iron-bearing olivine for CO2 methanation. Int J Hydrogen Energy 41:12910–12919CrossRefGoogle Scholar
  38. 38.
    Virginie M, Courson C, Niznansky D, Chaoui N, Kiennemann A (2010) Characterization and reactivity in toluene reforming of a Fe/olivine catalyst designed for gas cleanup in biomass gasification. Appl Catal B 101:90–100CrossRefGoogle Scholar
  39. 39.
    Courson C, Makaga E, Petit C, Kiennemann A (2000) Development of Ni catalysts for gas production from biomass gasification. Reactivity in steam- and dry-reforming. Catal Today 63:427–437CrossRefGoogle Scholar
  40. 40.
    Lovon ASP, Lovon-Quintana JJ, Almerindo GI, Valenca GP, Bernardi MIB, Araujo VD, Rodrigues TS, Robles-dutenhefner PA, Fajardo HV (2012) Preparation, structural characterization and catalytic properties of Co/CeO2 catalysts for the steam reforming of ethanol and hydrogen production. J Power Sources 216:281–289CrossRefGoogle Scholar
  41. 41.
    Xu W, Liu Z, Johnston-Peck AC, Senanayake SD, Zhou G, Stacchiola D, Stach EA, Rodriguez JA (2013) Steam reforming of ethanol on Ni/CeO2: reaction pathway and interaction between Ni and the CeO2 support. ACS Catal 3:975–984CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.Chemical Engineering DepartmentIndian Institute of TechnologyKharagpurIndia

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