Reaction Kinetics, Mechanisms and Catalysis

, Volume 126, Issue 1, pp 307–325 | Cite as

Effect of iron oxide precursor on the properties and ammonia synthesis activity of fused iron catalysts

  • Ali JafariEmail author
  • Abbas Ebadi
  • Saeed Sahebdelfar


Triply (Al, Ca and K) promoted wustite-based iron catalyst was prepared and compared with a similarly prepared magnetite catalyst for textural properties and performance in ammonia synthesis. The catalysts were synthesized by fusion method using Fe3O4 and metallic iron with similar nominal loading of promoters in both catalysts. The samples were characterized by N2 adsorption/desorption, XRD, H2-TPR, H2-TPD and EDS-mapping techniques. The Fe2+/Fe3+ ratio in the samples was measured by chemical titration. The stability and activity tests were performed in a fixed-bed reactor under kinetically controlled conditions (T = 350–530 °C, P = 30 bar, catalyst loading = 1 g, feed flow rate = 120 Nml/min and H2/N2 = 3/1 mol/mol). The catalysts exhibited different distribution of the promoters. Catalytic test results for ammonia synthesis showed that the activity of the wustite catalyst was higher than that of magnetite catalyst under the same reaction conditions. The former was also more readily activated by H2-reduction. The wustite catalyst showed similar thermostability and mechanical strength as the magnetite catalyst. The ammonia synthesis reaction was not intra-particle diffusion limited on either catalyst. The favorable properties of wustite-based catalysts can be employed to reduce the energy consumption and related emissions of ammonia plants significantly.


Ammonia synthesis Iron catalyst Wustite Magnetite Diffusion limitation 


Compliance with Ethical Standard

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11144_2018_1498_MOESM1_ESM.docx (702 kb)
Supplementary material 1 (DOCX 701 kb)


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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2018

Authors and Affiliations

  1. 1.Catalyst Research Group, Petrochemical Research and Technology CompanyNational Petrochemical CompanyTehranIran

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