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Reaction Kinetics, Mechanisms and Catalysis

, Volume 126, Issue 1, pp 237–247 | Cite as

Alkaline–modified montmorillonite K10: an efficient catalyst for green condensation reaction of aromatic aldehydes with active methylene compounds

  • Manef Chtourou
  • Achraf Lahyani
  • Mahmoud TrabelsiEmail author
Article
  • 35 Downloads

Abstract

An efficient and reusable catalyst, alkaline–modified Montmorillonite K10, has been developed and used in the Knoevenagel condensation. A series of condensation reactions based on ultrasound irradiation of different types of active methylene compounds and a variety of aromatic aldehydes showed the high efficiency of the prepared catalyst. This protocol has notable advantages, such as being eco-friendly, the ease of the work-up and reuse of the catalyst. The isolated compounds were synthesized in high yields (83–100%) in a short reaction time and were obtained, after crystallization, in pure form (IR, NMR and GC) without further purification. When ethyl cyanoacetate was used as active methylene compound, the reaction is highly stereoselective with only E geometry.

Keywords

Alkaline modification Knoevenagel condensation Montmorillonite K10 Ultrasound irradiation 

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2018

Authors and Affiliations

  • Manef Chtourou
    • 1
  • Achraf Lahyani
    • 1
  • Mahmoud Trabelsi
    • 1
    Email author
  1. 1.Laboratory of Organic Chemistry, Faculty of Sciences of SfaxUniversity of SfaxSfaxTunisia

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