Reaction Kinetics, Mechanisms and Catalysis

, Volume 124, Issue 2, pp 651–667 | Cite as

Preparation and performances of nanorod-like inverse CeO2–CuO catalysts derived from Ce-1,3,5-Benzene tricarboxylic acid for CO preferential oxidation

  • Chunlei GuEmail author
  • Ran Qi
  • Ying Wei
  • Xiangjing Zhang


A facile one-pot strategy of using CeBTC MOF as template and precursor was explored to prepare rod-like inverse CeO2–CuO catalysts. The inverse CeO2–CuO catalysts were characterized by using techniques of N2 adsorption and desorption, XRD, TEM, TPR and XPS. The results indicated that the rod-like inverse CeO2–CuO catalysts maintained the shapes of CeBTC MOF templates. The Cu0.71Ce0.29 catalysts exhibited excellent catalytic performance which was attributed to the strong synergistic effect between CuO and CeO2 and subsequent formation of reduced copper species.


Metal organic frameworks CO preferential oxidation Copper oxide Ceria Template 



The financial supports of this work by National Natural Science Foundation of China (21406053), Natural Science Foundation of Hebei province of China (B2014208141) are gratefully acknowledged.

Supplementary material

11144_2018_1374_MOESM1_ESM.doc (11.8 mb)
Supplementary material 1 (DOC 12119 kb)


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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2018

Authors and Affiliations

  1. 1.College of Chemical and Pharmaceutical EngineeringHebei University of Science and TechnologyShijiazhuangPeople’s Republic of China
  2. 2.Department of Catalysis Science and Technology, School of Chemical EngineeringTianjin UniversityTianjinPeople’s Republic of China

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