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Simulation analysis of graphene contacted perovskite solar cells using SCAPS-1D

  • Aniseh Kafi Kang
  • M. Hossein Zandi
  • Nima E. GorjiEmail author
Article
  • 35 Downloads

Abstract

To understand what cause the low performance in a perovskite cell with graphene back contact, we have performed simulations of device characteristics using SCAPs-1D simulation platform. The impact of increasing defect concentration at the interface of perovskite/graphene (RGO) and also graphene thickness on the current density, voltage, fill factor, and conversion efficiency of the cell was investigated. We converted the graphene nanostructure to a planar p-type layer at the top side of the cell as a hole transporting layer in order to enable to insert it into the SCAPS simulation platform. The simulation analysis were compared to the experimental data reported in literature. The voltage and fill factor of the simulation and experiments are almost the same but the current density is showing to be higher in simulation analysis which reminds a imperfect thickness and absorption by the graphene layer. Graphene was also compared to Spiro-MeOTAD showing to be a promising materials to act as both hole transporting layer and back contact. The experimental process could be improved by looking at our results as a method to fabricate a high performance cell with graphene electrode. It is shown that such a hybrid structure suffers from imperfect interface at graphene and perovskite junction where a high concentration of trap density impedes the carrier collection.

Keywords

Perovskite Graphene Solar cell SCAPS-1D Simulations 

Notes

References

  1. Ansari, Z.A., Singh, T.J., Islam, S.M., Singh, S., Mahala, P., Khan, A., Singh, K.J.: Photovoltaic solar cells based on graphene/gallium arsenide Schottky junction. Optik Int J Light Electron Opt 182, 500–506 (2019)CrossRefGoogle Scholar
  2. Basith, M.A., Ahsan, R., Zarin, I., Jalil, M.A.: Enhanced photocatalytic dye degradation and hydrogen production ability of Bi25 FeO40 -rGO nanocomposite and mechanism insight. Sci. Rep. 8(1), 11090 (2018).  https://doi.org/10.1038/s41598-018-29402-w ADSCrossRefGoogle Scholar
  3. Batmunkh, M., Shearer, C.J., Biggs, M.J., Shapter, J.G.: Solution processed graphene structures for perovskite solar cells. J. Mater. Chem. A 4, 2605–2616 (2016).  https://doi.org/10.1039/c5ta08996d CrossRefGoogle Scholar
  4. Chowdhury, T.H., Akhtaruzzaman, M., Kayesha, M., Kaneko, R., et al.: Low temperature processed inverted planar perovskite solar cells by r-GO/ CuSCN hole-transport bilayer with improved stability. Solar Energy 171, 652–657 (2018).  https://doi.org/10.1016/j.solener.2018.07.022 ADSCrossRefGoogle Scholar
  5. Houshmand, M., Zandi, M., Gorji, N.E.: Degradation & device physics modeling of SWCNT/CdTe thin film photovoltaics. Superlattices Microstruct. 88, 365–370 (2016)ADSCrossRefGoogle Scholar
  6. Iqbal, T., Haqnawaz, M., Sultan, M., Tahir, M.B., et al.: Novel graphene-based transparent electrodes for perovskite solar cells. Int. J. Energy Res. 42(13), 1–9 (2018)Google Scholar
  7. Jang, C.W., Kim, J.M., Choi, S.-H.: Lamination-produced semi-transparent/flexible perovskite solar cells with doped-graphene anode and cathode. J. Alloys Compd. 775, 905–911 (2019).  https://doi.org/10.1016/j.jallcom.2018.10.190 CrossRefGoogle Scholar
  8. Kakavelakis, G., Kymakis, E., Petridis, K.: 2D materials beyond graphene for metal halide perovskite solar cells. Adv. Mater. Interfaces 5, 1800339 (2018).  https://doi.org/10.1002/admi.201800339 CrossRefGoogle Scholar
  9. Kuhn, L., Gorji, N.E.: Review on the graphene/nanotube application in thin film solar cells. Mater. Lett. 171, 323–326 (2016) (featured letter) CrossRefGoogle Scholar
  10. Lang, F., Gluba, M.A., Albrecht, S., Rappich, J., Korte, L., Rech, B., Nickel, N.H.: Perovskite solar cells with large-area CVD-graphene for tandem solar cells. J. Phys. Chem. Lett. 6, 2745–2750 (2015).  https://doi.org/10.1021/acs.jpclett.5b01177 CrossRefGoogle Scholar
  11. Lee, D.-Y., Na, S.-I., Kim, S.-S.: Graphene oxide/PEDOT:PSS composite hole transport layer for efficient and stable planar heterojunction perovskite solar cells. Nanoscale 8, 1513–1522 (2016).  https://doi.org/10.1039/c5nr05271h ADSCrossRefGoogle Scholar
  12. Milic, J.V., Arora, N., Dar, M., Zakeeruddin, ShM, Grätzel, M.: Reduced graphene oxide as a stabilizing agent in perovskite solar cells. Adv. Mater. Interfaces 5, 1800416 (2018).  https://doi.org/10.1002/admi.201800416 CrossRefGoogle Scholar
  13. Minemoto, T., Murat, M.: Device modeling of perovskite solar cells based on structural similarity with thin film inorganic semiconductor solar cells. J. Appl. Phys. 116, 054505 (2014).  https://doi.org/10.1063/1.4891982 ADSCrossRefGoogle Scholar
  14. Minemoto, T., Murata, M.: Impact of work function of back contact of perovskite solar cells without hole transport material analyzed by device simulation. Curr. Appl. Phys. 14, 1428–1433 (2014).  https://doi.org/10.1016/j.cap.2014.08.002 ADSCrossRefGoogle Scholar
  15. Najafi, L., Taheri, B., Martín-García, B., Bellani, S., Girolamo, D., et al.: \(\text{ MoS }_2\) quantum dot/graphene hybrids for advanced interface engineering of a \(\text{CH}_3\text{NH}_3\text{PbI}_3\) perovskite solar cell with an efficiency of over 20%. ACS Nano 12(11), 10736–10754 (2018).  https://doi.org/10.1021/acsnano.8b05514 CrossRefGoogle Scholar
  16. Palma, A.L., Cinàa, L., Pescetelli, S., et al.: Reduced graphene oxide as efficient and stable hole transporting material in mesoscopic perovskite solar cells. Nano Energy 22, 349–360 (2016).  https://doi.org/10.1016/j.nanoen.2016.02.027 CrossRefGoogle Scholar
  17. Wang, Ch., Tang, Y., Hu, Y., Huang, L., Fu, J., Jin, J., Shi, W.: Graphene/\(\text{SrTiO}_3\) nanocomposites used as an effective electron-transporting layer for highperformance perovskite solar cells. RSC Adv. 5, 52041–52047 (2015).  https://doi.org/10.1039/c5ra09001f CrossRefGoogle Scholar
  18. Yang, Y., Xiao, J., Wei, H., Zhu, L., Li, D., et al.: An all-carbon counter electrode for highly efficient hole-conductor-free organo-metal perovskite solar cells. RSC Adv. 4, 52825–52830 (2014).  https://doi.org/10.1039/c4ra09519g CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Aniseh Kafi Kang
    • 1
  • M. Hossein Zandi
    • 1
  • Nima E. Gorji
    • 2
    Email author
  1. 1.Department of PhysicsShahid Bahonar University of KermanKermanIran
  2. 2.Optoelectronics Research Group, Faculty of Electrical and Electronics EngineeringTon Duc Thang UniversityHo Chi Minh CityVietnam

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