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Catalysis of sugarcane-bagasse pyrolysis by Co, Ni, and Cu single and mixed oxide nanocomposites

  • Mahmoud Mohamed EmaraEmail author
  • Shrouq Hossam Ali
  • Taher Salah Edin Kassem
  • P. Gregory Van Patten
Research Paper
  • 59 Downloads

Abstract

Pyrolysis of biomass is an important process in which renewable biological waste is converted to energy products and preliminary chemicals. Therefore, various types of catalysts, including metal oxides, have been investigated for more efficient and selective biomass pyrolysis. Co, Ni, and Cu single and mixed metal oxide (SMO and MMO) nanoparticles (NPs) of 3 to 47 nm were synthesized, characterized, and studies for their catalytic activities towards pyrolysis of sugarcane bagasse (PSCB). After mixing the oxide NPs with bagasse, thermogravimetry was performed at a heating rate of 5 °C/min from ambient temperature to 600 °C. Thermogravimetric analysis followed by kinetic calculations of the activation energy through Coats−Redfern model show that all oxide NPs of this study exhibit catalytic activity towards cellulose and hemicellulose thermal degradation during PSCB, in the order MMO > SMO. Cu-containing SMO and MMO NPs show exceptional catalytic activities compared to their analogues. On the other hand, lignin degradation kept proceeding over a wide range of high temperature, just like that of the plain PSCB. This is considered selective enhancement of the catalysis of cellulose and hemicellulose thermal degradation versus lignin degradation, which is promising for improving the composition and quality of PSCB products. Only Cu-containing double and triple MMOs were so catalytically active that they catalyzed lignin degradation along with the cellulose and hemicellulose.

Keywords

Bagasse Cellulose Oxides Nanocomposites Thermogravimetry Catalysis 

Abbreviations

BET

Brunauer–Emmett–Teller

DTG

Derivative thermogravimetry

FWHM

Full width at half maximum

ICP-AES

Inductively coupled plasma atomic emission spectroscopy

JCPDS

Joint Committee on Powder Diffraction Standards

MMO

Mixed metal oxide

NPs

Nanoparticles

PSCB

Pyrolysis of sugarcane bagasse

SCB

Sugarcane bagasse

SMO

Single metal oxide

TEM

Transmission electron microscopy

TG

Thermogravimetry

XRD

X-ray diffraction

Notes

Funding information

Financial support granted by the Ministry of Scientific Research and the Academy of Scientific Research and Technology (ASRT) through the program Scientists of Next Generation-2015 (SNG-5).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11051_2019_4749_MOESM1_ESM.docx (749 kb)
ESM 1 (DOCX 748 kb)

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Copyright information

© Springer Nature B.V. 2020

Authors and Affiliations

  1. 1.Chemistry Department, Faculty of ScienceAlexandria UniversityAlexandriaEgypt
  2. 2.Department of ChemistryMiddle Tennessee State UniversityMurfreesboroUSA

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