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Polythiophene-tungsten selenide/nitrogen-doped graphene oxide nanocomposite for visible light-driven photocatalysis

  • Yanan Liu
  • Han Yin
  • Chengcheng Xu
  • Xingchen Zhuge
  • Jun WanEmail author
Research Paper
  • 27 Downloads

Abstract

The organic dye pollutants are of more concern due to their toxic effects on human health, animals, and plants, and researchers thus should pay more attention to their removal. The nanocomposite photocatalysts of polythiophene-tungsten selenide/nitride-doped graphene oxide (PTh-WSe2/NG) were synthesized by a facile hydrothermal method. The catalytic activity of the nanocomposite was detected by degradation methylene blue (MB) under visible light. The as-prepared nanocomposite was characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray powder diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). The results showed that the photocatalytic performance of the composites was better than those of WSe2 and PTh. This was mainly due to the PTh-WSe2/NG which contains excellent conductivity and charge separation characteristics of PTh, WSe2, and NG. They effectively inhibit the recombination of electron-hole pairs of PTh-WSe2/NG. 12.5 wt% PTh-WSe2/NG (12.5 wt% of PTh) was the most efficient catalyst, with the removal rate reaching to 94.8% of 1.0 × 10–4 mol/L MB within 60 min of visible light irradiation.

Keywords

Polythiophene Tungsten selenide Photocatalytic Degradation wastewater Nanostructured catalyst 

Notes

Funding information

This work was supported by the Shandong Province Natural Science Foundation (ZR2017MB049) and the Shandong Province University of Science and Technology Plan Projects (J17KA108).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11051_2019_4648_MOESM1_ESM.doc (2.9 mb)
ESM 1 (DOC 2993 kb)

References

  1. Akrama H, Mateos-Pedrerod C, Gallegos-Suáreza E, Guerrero-RuízabA CT, Rodríguez-Ramosab I (2014) Effect of electrolytes nature and concentration on the morphology and structure of MoS2 nanomaterials prepared using the one-pot solvothermal method. Appl Surf Sci 307:319–326.  https://doi.org/10.1016/j.apsusc.2014.04.034 CrossRefGoogle Scholar
  2. An BH, Liu YN, Xu CC, Wang H, Wan J (2018) Novel magnetically separable Fe3O4-WSe2/NG photocatalysts: synthesis and photocatalytic performance under visible-light irradiation. New J Chem 42:8914–8923.  https://doi.org/10.1039/c8nj00406d CrossRefGoogle Scholar
  3. Ansari MO, Khan MM, Ansari SA, Cho MH (2015) Polythiophene nanocomposites for photodegradation applications: past, present and future. J Saudi Chem Soc 19:494–540.  https://doi.org/10.1016/j.jscs.2015.06.004 CrossRefGoogle Scholar
  4. Antunez PD, Webber DH, Brutchey RL (2013) ChemInform abstract: solution-phase synthesis of highly conductive tungsten diselenide nanosheets. Cheminform 25(12):2385–2387.  https://doi.org/10.1021/cm400790z CrossRefGoogle Scholar
  5. Bharathidasan P, Idris MB, Kim DW, Sivakkumar SR, Devaraj S (2018) Enhanced capacitance properties of nitrogen doped reduced graphene oxide obtained by simultaneous reduction and nitrogen doping. FlatChem 11:24–31.  https://doi.org/10.1016/j.flatc.2018.10.001 CrossRefGoogle Scholar
  6. Bosecher ND, Carmalt CJ, Parkin IP (2006) Atmospheric pressure chemical vapor deposition of WSe2 thin films on glass-highly hydrophobic sticky surfaces. J Mater Chem 16:122–127.  https://doi.org/10.1039/B514440J CrossRefGoogle Scholar
  7. Chandra MR, Reddy PSP, Rao TS, Pammi SVN, Kumar KS, Babu KV, Kumar CK, Hemalathab KPJ (2017) Enhanced visible-light photocatalysis and gas sensor properties of polythiophene supported tin doped titanium nanocomposite. J Phys Chem Solids 105:99–105.  https://doi.org/10.1016/j.jpcs.2017.02.014 CrossRefGoogle Scholar
  8. Chen FJ, Wang J, Li B, Yao C, Bao H, Shi (2014) Nanocasting synthesis of ordered mesoporous crystalline WSe2 as anode material for Li-ion batteries. Mater Lett 136:191–194.  https://doi.org/10.1016/j.matlet.2014.08.050 CrossRefGoogle Scholar
  9. Chen LC, Yeh TF, Lee YL, Teng H (2016) Incorporating nitrogen-doped graphene oxide dots with graphene oxide sheets for stable and effective hydrogen production through photocatalytic water decomposition. Appl Catal A-Gen 521:118–124.  https://doi.org/10.1016/j.apcata.2015.11.037 CrossRefGoogle Scholar
  10. Chiritescu C, Cahill DG, Nguyen N, Johnson D, Bodapati A, Keblinski P, Zschack P (2007) Ultralow thermal conductivity in disordered, layered WSe2 crystals. Science 315:351–353.  https://doi.org/10.1126/science.1136494 CrossRefGoogle Scholar
  11. Daniel G, Annelise KA (2016) Solution-processable exfoliation and suspension of atomically thin WSe2. J Colloid Interface Sci 468:247–252.  https://doi.org/10.1016/j.jcis.2016.01.073 CrossRefGoogle Scholar
  12. Delphine SM, Jayachandran M, Sanjeeviraja C (2003) Pulsed electrosynthesis and characterisation of tungsten diselenide thin films. Mater Chem Phys 81:78–83.  https://doi.org/10.1016/S0254-0584(03)00136-6 CrossRefGoogle Scholar
  13. Feng X, Zhao X, Chen L (2019) BiVO4/BiO0.67F1.66 heterojunction enhanced charge carrier separation to boost photocatalytic activity. J Nanopart Res 21:61.  https://doi.org/10.1007/s11051-019-4506-5 CrossRefGoogle Scholar
  14. Gao BL, Ke SH, Song G, Zhang J, Zhou L, Li GN, Liang F, Wang Y, Dang C (2017) Structural and electronic properties of zigzag and armchair WSe2 nanotubes. J. Alloys Compd 695:2751–2756.  https://doi.org/10.1016/j.jallcom.2016.11.197 CrossRefGoogle Scholar
  15. Han GH, Kybert NJ, Naylor CH, Lee BS, Ping J, Park JH, Kang J, Lee SY, Lee YH, Agarwal R, Charlie Johnson AT (2015) Seeded growth of highly crystalline molybdenum disulphide monolayers at controlled locations. Nat Commun 6:6128.  https://doi.org/10.1038/ncomms7128 CrossRefGoogle Scholar
  16. Huang JM, Kelley DF (2016) Synthesis and characterization of MoSe2 and WSe2 nanoclusters. Chem Mater 12(10):2825–2828.  https://doi.org/10.1021/cm0002517 CrossRefGoogle Scholar
  17. Huang Q, Sun HJ, Yang YH (2011) Spectroscopy characterization and analysis of graphite oxide, Chinese. J Inorg Chem 27:1721–1726.  https://doi.org/10.1515/MGMC.2011.009 CrossRefGoogle Scholar
  18. Kao E, Liang QH, Bertholet GR, Zang X, Park HS, Bae J, Lu J, Lin L (2018) Electropolymerized polythiophene photoelectrodes for photocatalytic water splitting and hydrogen production. Sensor Actuat A-Phys 277:18–25.  https://doi.org/10.1016/j.sna.2018.04.037 CrossRefGoogle Scholar
  19. Kim K, Larentis S, Fallahazad B, Lee K, Xue J, Dillen DC, Corbet CM, Tutuc E (2015) Band alignment in WSe2-graphene Heterostructures. ACS Nano 9:4527–4532.  https://doi.org/10.1021/acsnano.5b01114 CrossRefGoogle Scholar
  20. Kulkarni G, Kandesar P, Velhal N, Phadtare VA (2019) Exceptional electromagnetic interference shielding and microwave absorption properties of room temperature synthesized polythiophene thin films with double negative characteristics (DNG) in the Ku-band region. Chem Eng J 355:196–207.  https://doi.org/10.1016/j.cej.2018.08.114 CrossRefGoogle Scholar
  21. Kumara K, Shetty TCS, Maidur SR, Patil PS, Dharmaprakash SM (2019) Continuous wave laser induced nonlinear optical response of nitrogen doped graphene oxide. Optik 178:384–393.  https://doi.org/10.1016/j.ijleo.2018.09.181 CrossRefGoogle Scholar
  22. Li HC, Gao D, Li K, Pang MD, Xie SL, Zou JP (2017) Texture control and growth mechanism of WSe2 film prepared by rapid selenization of W film. Appl Sur Sci 394(1):142–148.  https://doi.org/10.1016/j.apsusc.2016.10.050 CrossRefGoogle Scholar
  23. Liu B, Fathi M, Chen L, Abbas A, Ma Y, Zhou C (2015) Chemical vapor deposition growth of monolayer WSe2 with tunable device characteristics and growth mechanism study. ACS Nano 9:6119–6127.  https://doi.org/10.1021/acsnano.5b01301 CrossRefGoogle Scholar
  24. Liu JQ, Zhao W, Wen GL, Xu J, Chen X, Zhang Q, Wang Y, Zhang Y, Wu YC (2019) Hydrothermal synthesis of well-standing δ -MnO2 nanoplatelets on nitrogen-doped reduced graphene oxide for high-performance supercapacitor. J Alloy Compd 787:309–317.  https://doi.org/10.1016/j.jallcom.2019.02.090 CrossRefGoogle Scholar
  25. Ma G, Liang X, Li L, Qiao R, Jiang D, Ding Y (2014) Cu-doped zinc oxide and its polythiophene composites: preparation and antibacterial properties. Chemosphere 100:146–151.  https://doi.org/10.1016/j.chemosphere.2013.11.053 CrossRefGoogle Scholar
  26. Mamba G, Mishra AK (2016) Graphitic carbon nitride (g-C3N4) nanocomposites: a new and exciting generation of visible light driven photocatalysts for environmental pollution remediation. Appl Catal B Environ 198:347–377.  https://doi.org/10.1016/j.apcatb.2016.05.052 CrossRefGoogle Scholar
  27. Mao LB, Ji KL, Yao LL, Xue XJ, Wen W, Zhang XH, Wang SF (2019) Molecularly imprinted photoelectrochemical sensor for fumonisin B1 based on GO-CdS heterojunction. Biosens Bioelectron 127(15):57–63.  https://doi.org/10.1016/j.bios.2018.11.040 CrossRefGoogle Scholar
  28. Mohamed HH, Alsanea AA, Alomair NA, Akhtar S, Bahnemann DW (2019) ZnO@ porous graphite nanocomposite from waste for superior photocatalytic activity. Eviron Sci Pollut Res 26(12):12288–12301.  https://doi.org/10.1007/s11356-019-04684-3 CrossRefGoogle Scholar
  29. Nath M, Govindaraj A, Rao CNR (2001) Simple synthesis of MoS2 and WS2 nanotubes. Adv Mater 13:283–286.  https://doi.org/10.1002/1521-4095(200102)13:4<283::AID-ADMA283>3.0.CO;2-H CrossRefGoogle Scholar
  30. Nguyen NT, Berseth PA, Lin Q, Chiritescu C (2010) Synthesis and properties of turbostratically disordered, ultrathin WSe2 film. Chem Mater 22:2750–2756.  https://doi.org/10.1021/cm903633w CrossRefGoogle Scholar
  31. Özkan A, Özkan MH, Gürkan R, Akcay M, Sökmen M (2004) Photocatalytic degradation of a azo textile dye, Sirius Gelb GC on TiO2, or Ag-TiO2, particles in the absence and presence of UV irradiation: the effects of some inorganic anions on the photocatalysis. J Photochem Photobiol A Chem 163:29–35.  https://doi.org/10.1016/S1010-6030(03)00426-X CrossRefGoogle Scholar
  32. Qi HP, Wang HL, Zhao DY, Jiang WF (2019) Preparation and photocatalytic activity of Ag-modifified GO-TiO2 mesocrystals under visible light irradiation. Appl Sur Sci 480:105–114.  https://doi.org/10.1016/j.apsusc.2019.02.194 CrossRefGoogle Scholar
  33. Ren X, Sun Y, Xing H, Wu K, Wang W, Yin J, Yao S, Zhao X, Yang H (2019) 3D/2D Ln3+-doped BiOBr/rGO heterostructure with enhanced photocatalytic performance. J Nanopart Res 21:111.  https://doi.org/10.1007/s11051-019-4552-z CrossRefGoogle Scholar
  34. Sfyris D, Sfyris GI, Galiotis C (2015) Constitutive modeling of some 2D crystals: graphene, hexagonal BN, MoS2, WSe2 and NbSe2. Int J Solids Struct 66:98–110.  https://doi.org/10.1016/j.ijsolstr.2015.03.030 CrossRefGoogle Scholar
  35. Tong M, Yang J, Jin Q, Zhang X, Gao J, Li G (2019) Facile preparation of amorphous carbon-coated tungsten trioxide containing oxygen vacancies as photocatalysts for dye degradation. J Mater Sci 54:10656–10669.  https://doi.org/10.1007/s10853-019-03645-y CrossRefGoogle Scholar
  36. Velazquez JM, Saadi FH, Pieterick AP, Spurgeon JM, Soriaga MP, Brunschwig BS, Lewis NS (2014) Synthesis and hydrogen-evolution activity of tungsten selenide thin films deposited on tungsten foils. J Electroanal Chem 716:45–48.  https://doi.org/10.1016/j.jelechem.2013.11.030 CrossRefGoogle Scholar
  37. Wan J, An B, Chen Z, Zhang J, Yu WW (2018) Nitrogen-doped graphene oxide modified WSe2, nanorods for visible light photocatalysis. J Alloys Compd 750:499–506.  https://doi.org/10.1016/j.jallcom.2018.04.047 CrossRefGoogle Scholar
  38. Wang CC, Lee CK, Lyu MD, Juang LC (2008) Photocatalytic degradation of C.I. basic violet 10 using TiO2, catalysts supported by Y zeolite: an investigation of the effects of operational parameters. Dyes Pigments 76:817–824.  https://doi.org/10.1016/j.dyepig.2007.02.004 CrossRefGoogle Scholar
  39. Wang R, Liu B, Liu M, Yang JF, Tian LH (2019) RCQDs @ Ag/VO x nanorods for enhanced visible-light photocatalytic activity. J Nanopart Res 21:51.  https://doi.org/10.1007/s11051-019-4477-6 CrossRefGoogle Scholar
  40. Yu Z, Li F, Yang Q, Shi H (2017) Nature-mimic method to fabricate polydopamine/graphitic carbon nitride for enhancing photocatalytic degradation performance. ACS Sustain Chem Eng 5:7840–7850.  https://doi.org/10.1021/acssuschemeng.7b01313 CrossRefGoogle Scholar
  41. Zhang F, Shi Y, Zhao Z, Song W, Cheng Y (2014) Influence of semiconductor/insulator/semiconductor structure on the photo-catalytic activity of Fe3O4/SiO2/polythiophene core/shell submicron composite. Appl Catal B Environ 150-151:472–478.  https://doi.org/10.1016/j.apcatb.2013.12.049 CrossRefGoogle Scholar
  42. Zhao Z, Sun Y, Dong F (2015) Graphitic carbon nitride based nanocomposites: a review. Nanoscale 7:15–37.  https://doi.org/10.1039/c4nr03008g CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.School of Environment and Safety EngineeringQingdao University of Science and TechnologyQingdaoChina

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