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Multicolor photoluminescent carbon nanodots regulated by degree of oxidation for multicolor patterning, invisible inks, and detection of metal ions

  • Bing Chen
  • Houpeng Xie
  • Sui WangEmail author
  • Zhiyong Guo
  • Yufang Hu
  • Hongzhen Xie
Research Paper
  • 39 Downloads

Abstract

A strategy for preparing multicolor photoluminescent carbon nanodots (CNs) has been proposed. Using three types of phenylenediamine and methacrylic acid as raw materials and ethanol as a solvent, a series of novel CNs were synthesized by solvothermal one-pot method. Prepared CNs showed bright green, yellow, and indigo blue fluorescence under ultraviolet (UV) light, respectively. Three types of CNs were spherical-like nano-sized particles, and their particle sizes were approximately 5 nm, 10 nm, and 10 nm, respectively. The optical properties of CNs were characterized using ultraviolet visible spectra and fluorescence spectra. The microscopic morphology was characterized by transmission electron microscopy (TEM) and dynamic light scattering (DLS). The elemental composition was characterized by Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectra (XPS). We proposed that the different fluorescence emissions of CNs might be attributed to the surface oxygen content of the CNs. The CNs could also be applied for multicolor patterning and polymer films, invisible inks, and detection of metal ions.

Keywords

Carbon nanodots Photoluminescence One-pot synthesis Fluorescent inks Detection of metal ions 

Notes

Funding information

This research was supported by the National Natural Science Foundation of China (41576098, 81773483), the Science and Technology Department of Zhejiang Province of China (2016C33176, LGF18B070002), the Natural Science Foundation of Ningbo city (2017A610231, 2017A610228, 2017A610069), and the K.C. Wong Magna Fund in Ningbo University.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11051_2019_4515_MOESM1_ESM.docx (5.9 mb)
ESM 1 (DOCX 6049 kb)

References

  1. Al Awak MM, Wang P, Wang S, Tang Y, Sun Y-P, Yang L (2017) Correlation of carbon dots’ light-activated antimicrobial activities and fluorescence quantum yield. RSC Adv 7:30177–30184.  https://doi.org/10.1039/c7ra05397e CrossRefGoogle Scholar
  2. Bao L, Liu C, Zhang ZL, Pang DW (2015) Photoluminescence-tunable carbon nanodots: surface-state energy-gap tuning. Adv Mater 27:1663–1667.  https://doi.org/10.1002/adma.201405070 CrossRefGoogle Scholar
  3. Carrara S, Arcudi F, Prato M, De Cola L (2017) Amine-rich nitrogen-doped carbon nanodots as a platform for self-enhancing electrochemiluminescence. Angew Chem 56:4757–4761.  https://doi.org/10.1002/anie.201611879 CrossRefGoogle Scholar
  4. Choudhary R, Patra S, Madhuri R, Sharma PK (2016) Equipment-free, single-step, rapid, “on-site” kit for visual detection of lead ions in soil, water, bacteria, live cells, and solid fruits using fluorescent cube-shaped nitrogen-doped carbon dots. ACS Sustain Chem Eng 4:5606–5617.  https://doi.org/10.1021/acssuschemeng.6b01463 CrossRefGoogle Scholar
  5. Ding H, Yu SB, Wei JS, Xiong HM (2016) Full-color light-emitting carbon dots with a surface-state-controlled luminescence mechanism. ACS Nano 10:484–491.  https://doi.org/10.1021/acsnano.5b05406 CrossRefGoogle Scholar
  6. Dong Y, Wang R, Li G, Chen C, Chi Y, Chen G (2012) Polyamine-functionalized carbon quantum dots as fluorescent probes for selective and sensitive detection of copper ions. Anal Chem 84:6220–6224.  https://doi.org/10.1021/ac3012126 CrossRefGoogle Scholar
  7. Feng XT, Zhang F, Wang YL, Zhang Y, Yang YZ, Liu XG (2015a) Luminescent carbon quantum dots with high quantum yield as a single white converter for white light emitting diodes. Appl Phys Lett 107:213102–203106.  https://doi.org/10.1063/1.4936234 CrossRefGoogle Scholar
  8. Feng Y, Zhong D, Miao H, Yang X (2015b) Carbon dots derived from rose flowers for tetracycline sensing. Talanta 140:128–133.  https://doi.org/10.1016/j.talanta.2015.03.038 CrossRefGoogle Scholar
  9. Gao S, Chen Y, Fan H, Wei X, Hu C, Wang L, Qu L (2014) A green one-arrow-two-hawks strategy for nitrogen-doped carbon dots as fluorescent ink and oxygen reduction electrocatalysts. J Mater Chem A 2:6320–6326.  https://doi.org/10.1039/c3ta15443b CrossRefGoogle Scholar
  10. Gong X, Zhang Q, Gao Y, Shuang S, Choi MM, Dong C (2016) Phosphorus and nitrogen dual-doped hollow carbon dot as a nanocarrier for doxorubicin delivery and biological imaging. ACS Appl Mater Interfaces 8:11288–11297.  https://doi.org/10.1021/acsami.6b01577 CrossRefGoogle Scholar
  11. Han L, Liu SG, Dong JX, Liang JY, Li LJ, Li NB, Luo HQ (2017) Facile synthesis of multicolor photoluminescent polymer carbon dots with surface-state energy gap-controlled emission. J Mater Chem C 5:10785–10793.  https://doi.org/10.1039/c7tc03314a CrossRefGoogle Scholar
  12. Hu S, Liu J, Yang J, Wang Y, Cao S (2011) Laser synthesis and size tailor of carbon quantum dots. J Nanopart Res 13:7247–7252.  https://doi.org/10.1007/s11051-011-0638-y CrossRefGoogle Scholar
  13. Jiang K, Sun S, Zhang L, Lu Y, Wu A, Cai C, Lin H (2015) Red, green, and blue luminescence by carbon dots: full-color emission tuning and multicolor cellular imaging. Angew Chem 54:5360–5363.  https://doi.org/10.1002/anie.201501193 CrossRefGoogle Scholar
  14. Kozák O, Datta KKR, Greplová M, Ranc V, Kašlík J, Zbořil R (2013) Surfactant-derived amphiphilic carbon dots with tunable photoluminescence. J Phys Chem C 117:24991–24996.  https://doi.org/10.1021/jp4040166 CrossRefGoogle Scholar
  15. Kumar A, Chowdhuri AR, Laha D, Mahto TK, Karmakar P, Sahu SK (2017) Green synthesis of carbon dots from Ocimum sanctum for effective fluorescent sensing of Pb 2+ ions and live cell imaging. Sensors Actuators B Chem 242:679–686.  https://doi.org/10.1016/j.snb.2016.11.109 CrossRefGoogle Scholar
  16. Li Q, Ohulchanskyy TY, Liu R, Koynov K, Wu D, Best A, Kumar R, Bonoiu A, Prasad PN (2010) Photoluminescent carbon dots as biocompatible nanoprobes for targeting cancer cells in vitro. J Phys Chem C 114:12062–12068.  https://doi.org/10.1021/jp911539r CrossRefGoogle Scholar
  17. Li W, Zhang Z, Kong B, Feng S, Wang J, Wang L, Yang J, Zhang F, Wu P, Zhao D (2013) Simple and green synthesis of nitrogen-doped photoluminescent carbonaceous nanospheres for bioimaging. Angew Chem 52:8151–8155.  https://doi.org/10.1002/anie.201303927 CrossRefGoogle Scholar
  18. Li L, Yu B, You T (2015) Nitrogen and sulfur co-doped carbon dots for highly selective and sensitive detection of Hg (II) ions. Biosens Bioelectron 74:263–269.  https://doi.org/10.1016/j.bios.2015.06.050 CrossRefGoogle Scholar
  19. Liang Z, Zeng L, Cao X, Wang Q, Wang X, Sun R (2014) Sustainable carbon quantum dots from forestry and agricultural biomass with amplified photoluminescence by simple NH4OH passivation. J Mater Chem C 2:9760–9766.  https://doi.org/10.1039/c4tc01714e CrossRefGoogle Scholar
  20. Lim SY, Shen W, Gao Z (2015) Carbon quantum dots and their applications. Chem Soc Rev 44:362–381.  https://doi.org/10.1039/c4cs00269e CrossRefGoogle Scholar
  21. Liu S, Tian J, Wang L, Luo Y, Sun X (2012) A general strategy for the production of photoluminescent carbon nitride dots from organic amines and their application as novel peroxidase-like catalysts for colorimetric detection of H2O2and glucose. RSC Adv 2:411–413.  https://doi.org/10.1039/c1ra00709b CrossRefGoogle Scholar
  22. Liu Y, Zhou L, Li Y, Denga R, Zhang H (2016) Highly fluorescent nitrogen-doped carbon dots with excellent thermal and photo stability applied as invisible ink for loading important information and anti-counterfeiting. Nanoscale 9:491–496.  https://doi.org/10.1039/C6NR07123F CrossRefGoogle Scholar
  23. Ma Z, Ming H, Huang H, Liu Y, Kang Z (2012) One-step ultrasonic synthesis of fluorescent N-doped carbon dots from glucose and their visible-light sensitive photocatalytic ability. New J Chem 36:861–864.  https://doi.org/10.1039/c2nj20942j CrossRefGoogle Scholar
  24. Mewada A, Pandey S, Thakur M, Jadhav D, Sharon M (2014) Swarming carbon dots for folic acid mediated delivery of doxorubicin and biological imaging. J Mater Chem B 2:698–705.  https://doi.org/10.1039/c3tb21436b CrossRefGoogle Scholar
  25. Pan D, Zhang J, Li Z, Wu M (2010) Hydrothermal route for cutting graphene sheets into blue-luminescent graphene quantum dots. Adv Mater 22:734–738.  https://doi.org/10.1002/adma.200902825 CrossRefGoogle Scholar
  26. Peng J, Gao W, Gupta BK, Liu Z, Romero-Aburto R, Ge L, Song L, Alemany LB, Zhan X, Gao G, Vithayathil SA, Kaipparettu BA, Marti AA, Hayashi T, Zhu JJ, Ajayan PM (2012) Graphene quantum dots derived from carbon fibers. Nano Lett 12:844–849.  https://doi.org/10.1021/nl2038979 CrossRefGoogle Scholar
  27. Qiao ZA, Wang Y, Gao Y, Li H, Dai T, Liu Y, Huo Q (2010) Commercially activated carbon as the source for producing multicolor photoluminescent carbon dots by chemical oxidation. Chem Commun 46:8812–8814.  https://doi.org/10.1039/c0cc02724c CrossRefGoogle Scholar
  28. Qu S, Wang X, Lu Q, Liu X, Wang L (2012) A biocompatible fluorescent ink based on water-soluble luminescent carbon nanodots. Angew Chem 51:12215–12218.  https://doi.org/10.1002/anie.201206791 CrossRefGoogle Scholar
  29. Ravindran S, Chaudhary S, Colburn B, Ozkan M, CSO (2003) Covalent coupling of quantum dots to multiwalled carbon nanotubes for electronic device applications. Nano Lett 3:447–453.  https://doi.org/10.1021/nl0259683 CrossRefGoogle Scholar
  30. Sahu S, Behera B, Maiti TK, Mohapatra S (2012) Simple one-step synthesis of highly luminescent carbon dots from orange juice: application as excellent bio-imaging agents. Chem Commun 48:8835–8837.  https://doi.org/10.1039/c2cc33796g CrossRefGoogle Scholar
  31. Sarkar S, Banerjee D, Ghorai UK, Das NS, Chattopadhyay KK (2016) Size dependent photoluminescence property of hydrothermally synthesized crystalline carbon quantum dots. J Lumin 178:314–323.  https://doi.org/10.1016/j.jlumin.2016.05.033 CrossRefGoogle Scholar
  32. Shi L et al (2015) Facile and eco-friendly synthesis of green fluorescent carbon nanodots for applications in bioimaging, patterning and staining. Nanoscale 7:7394–7401.  https://doi.org/10.1039/c5nr00783f CrossRefGoogle Scholar
  33. Shi L et al (2016) Carbon dots with high fluorescence quantum yield: the fluorescence originates from organic fluorophores. Nanoscale 8:14374–14378.  https://doi.org/10.1039/c6nr00451b CrossRefGoogle Scholar
  34. Tao S, Song Y, Zhu S, Shao J, Yang B (2017) A new type of polymer carbon dots with high quantum yield: from synthesis to investigation on fluorescence mechanism. Polymer 116:472–478.  https://doi.org/10.1016/j.polymer.2017.02.039 CrossRefGoogle Scholar
  35. Wang L, Zhou HS (2014) Green synthesis of luminescent nitrogen-doped carbon dots from milk and its imaging application. Anal Chem 86:8902–8905.  https://doi.org/10.1021/ac502646x CrossRefGoogle Scholar
  36. Wang X, Cao L, Yang ST, Lu F, Meziani MJ, Tian L, Sun KW, Bloodgood MA, Sun YP (2010) Bandgap-like strong fluorescence in functionalized carbon nanoparticles. Angew Chem 49:5310–5314.  https://doi.org/10.1002/anie.201000982 CrossRefGoogle Scholar
  37. Wang F, Xie Z, Zhang H, Liu C-Y, Zhang Y-G (2011a) Highly luminescent organosilane-functionalized carbon dots. Adv Funct Mater 21:1027–1031.  https://doi.org/10.1002/adfm.201002279 CrossRefGoogle Scholar
  38. Wang X, Qu K, Xu B, Ren J, Qu X (2011b) Microwave assisted one-step green synthesis of cell-permeable multicolor photoluminescent carbon dots without surface passivation reagents. J Mater Chem 21:2445–2450.  https://doi.org/10.1039/c0jm02963g CrossRefGoogle Scholar
  39. Wang TY, Chen CY, Wang CM, Tan YZ, Liao WS (2017) Multicolor functional carbon dots via one-step refluxing synthesis. ACS Sensors 2:354–363.  https://doi.org/10.1021/acssensors.6b00607 CrossRefGoogle Scholar
  40. Xu Y, Wu M, Liu Y, Feng XZ, Yin XB, He XW, Zhang YK (2013) Nitrogen-doped carbon dots: a facile and general preparation method, photoluminescence investigation, and imaging applications. Chemistry 19:2276–2283.  https://doi.org/10.1002/chem.201203641 CrossRefGoogle Scholar
  41. Xue M, Zhan Z, Zou M, Zhang L, Zhao S (2016) Green synthesis of stable and biocompatible fluorescent carbon dots from peanut shell for multicolor living cell imaging. New J Chem 40:1698–1703.  https://doi.org/10.1039/C5NJ02181B CrossRefGoogle Scholar
  42. Yan F, Zou Y, Wang M, Mu X, Yang N, Chen L (2014) Highly photoluminescent carbon dots-based fluorescent chemosensors for sensitive and selective detection of mercury ions and application of imaging in living cells. Sens Actuators B Chem 192:488–495.  https://doi.org/10.1016/j.snb.2013.11.041 CrossRefGoogle Scholar
  43. Yu X, Liu R, Zhang G, Cao H (2013) Carbon quantum dots as novel sensitizers for photoelectrochemical solar hydrogen generation and their size-dependent effect. Nanotechnology 24:335401.  https://doi.org/10.1088/0957-4484/24/33/335401 CrossRefGoogle Scholar
  44. Yuan M, Zhong R, Gao H, Li W, Yun X, Liu J, Zhao X, Zhao G, Zhang F (2015) One-step, green, and economic synthesis of water-soluble photoluminescent carbon dots by hydrothermal treatment of wheat straw, and their bio-applications in labeling, imaging, and sensing. Appl Surf Sci 355:1136–1144.  https://doi.org/10.1016/j.apsusc.2015.07.095 CrossRefGoogle Scholar
  45. Zhang Z, Sun W, Wu P (2015) Highly photoluminescent carbon dots derived from egg white: facile and green synthesis, photoluminescence properties, and multiple applications. ACS Sustain Chem Eng 3:1412–1418.  https://doi.org/10.1021/acssuschemeng.5b00156 CrossRefGoogle Scholar
  46. Zhu L, Yin Y, Wang C-F, Chen S (2013a) Plant leaf-derived fluorescent carbon dots for sensing, patterning and coding. J Mater Chem C 1:4925–4932.  https://doi.org/10.1039/c3tc30701h CrossRefGoogle Scholar
  47. Zhu S et al (2013b) Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging. Angew Chem Int Ed 125:4045–4049.  https://doi.org/10.1039/C4RA16233A CrossRefGoogle Scholar
  48. Zhu J-H, Li M-M, Liu S-P, Liu Z-F, Li Y-F, Hu X-L (2015) Fluorescent carbon dots for auramine O determination and logic gate operation. Sensors Actuators B Chem 219:261–267.  https://doi.org/10.1016/j.snb.2015.05.032 CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Faculty of Materials Science and Chemical Engineering, State Key Laboratory Base of Novel Functional Materials and Preparation ScienceNingbo UniversityNingboPeople’s Republic of China

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