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On the water stability of ionic liquids/Cu-BTC composites: an experimental study

  • Xiaoxiao Xia
  • Wei Li
  • Song LiEmail author
Research Paper

Abstract

Ionic liquids/metal-organic framework composites are recognized as promising adsorbents for CO2 capture due to the outstanding adsorption performance, whereas their water stability, which is critical for the real application of ILs/MOF composites, has not been taken into consideration. In this work, the water stability of two ILs/Cu-BTC composites, i.e., 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]) /Cu-BTC and 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) /Cu-BTC, were investigated. We found that the loading of ILs does not impose remarkable impacts on the crystalline structure of Cu-BTC upon water exposure; whereas the thermal stability and surface area of Cu-BTC were decreased by the incorporation of ILs, thereby leading to the reduced CO2 uptake in spite of the enhanced CO2 heat of adsorption. Furthermore, it was revealed that the decomposition of Cu-BTC occurred within the first hour of water exposure. Nevertheless, the loading of ILs retarded the decomposition of Cu-BTC according to the variations in BET surface area upon water exposure.

Graphical abstract

Keywords

Metal-organic frameworks Water exposure Ionic liquids Surface area CO2 adsorption Nanocomposite materials 

Notes

Acknowledgments

We thank the support from Analytical and Testing Center of Huazhong University of Science and Technology, and the National Supercomputer Center of Shenzhen.

Author contributions

For research articles with several authors, a short paragraph specifying their individual contributions must be provided. The following statements should be used “Conceptualization, S. L. (Song Li); Methodology, X. X. (Xiaoxiao Xia); Software, X. X and W. L. (Wei Li); Validation, X.X.; Formal Analysis, X.X.; Investigation, X.X.; Resources, X.X.; Data Curation, X.X.; Writing-Original Draft Preparation, X.X.; Writing-Review & Editing, S.L.; Visualization, W. L. (Wei Li); Supervision, S.L.; Project Administration, S.L.; Funding Acquisition, S.L.”

Funding

This work was funded by the National Natural Science Foundation of China (NSFC) under Project No. 51606081.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflicts of interest.

Supplementary material

11051_2019_4475_MOESM1_ESM.docx (10.2 mb)
ESM 1 (DOCX 10416 kb)

References

  1. Abroshan H, Kim HJ (2015) On the structural stability of ionic liquid-IRMOF composites: a computational study. Phys Chem Chem Phys 17:6248–6254CrossRefGoogle Scholar
  2. Alvarez JR et al (2017) Structure stability of HKUST-1 towards water and ethanol and their effect on its CO2 capture properties. Dalton Trans 46:9192–9200CrossRefGoogle Scholar
  3. Babucci M, Akcay A, Baci V, Uzun A (2015) Thermal stability limits of imidazolium ionic liquids immobilized on metal-oxides. Langmuir 31:9163–9176CrossRefGoogle Scholar
  4. Burtch NC, Jasuja H, Walton KS (2014) Water stability and adsorption in metal-organic frameworks. Chem Rev 114:10575–10612CrossRefGoogle Scholar
  5. Cao Y, Chen Y, Sun X, Zhang Z, Mu T (2012) Water sorption in ionic liquids: kinetics, mechanisms and hydrophilicity. Phys Chem Chem Phys 14:12252–12262CrossRefGoogle Scholar
  6. Chen Y, Hu Z, Gupta KM, Jiang J (2011) Ionic liquid/metal-organic framework composite for CO2 capture: a computational investigation. J Phys Chem C 115:21736–21742CrossRefGoogle Scholar
  7. Cohen SM (2012) Postsynthetic methods for the functionalization of metal-organic frameworks. Chem Rev 112:970–1000CrossRefGoogle Scholar
  8. Cook TR, Zheng YR, Stang PJ (2013) Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials. Chem Rev 113:734–777CrossRefGoogle Scholar
  9. Couck S, Denayer JFM, Baron GV, Rémy T, Gascon J, Kapteijn F (2009) An amine-functionalized MIL-53 metal-organic framework with large separation power for CO2 and CH4. J Am Chem Soc 131:6326–6327CrossRefGoogle Scholar
  10. Darunte LA, Oetomo AD, Walton KS, Sholl DS, Jones CW (2016) Direct air capture of CO2 using amine functionalized MIL-101(Cr). ACS Sustain Chem Eng 4:5761–5768CrossRefGoogle Scholar
  11. DeCoste JB, Peterson GW, Schindler BJ, Killops KL, Browe MA, Mahle JJ (2013) The effect of water adsorption on the structure of the carboxylate containing metal-organic frameworks Cu-BTC, Mg-MOF-74, and UiO-66. J Mater Chem A 1:11922–11932CrossRefGoogle Scholar
  12. Demessence A, D’Alessandro DM, Foo ML, Long JR (2009) Strong CO2 binding in a water-stable, triazolate-bridged metal-organic framework functionalized with ethylenediamine. J Am Chem Soc 131:8784–8786CrossRefGoogle Scholar
  13. Dhumal NR, Singh MP, Anderson JA, Kiefer J, Kim HJ (2016) Molecular interactions of a u-based metal-organic framework with a confined imidazolium-based ionic liquid: a combined density functional theory and experimental vibrational spectroscopy study. J Phys Chem C 120:3295–3304CrossRefGoogle Scholar
  14. Drenchev N, Ivanova E, Mihaylov M, Hadjiivanov K (2010) CO as an IR probe molecule for characterization of copper ions in a basolite C300 MOF sample. Physi Chem Chem Phys 12:6423–6427CrossRefGoogle Scholar
  15. Freire MG, Neves CMSS, Marrucho IM, Coutinho JAP, Fernandes AM (2010) Hydrolysis of tetrafluoroborate and hexafluorophosphate counter ions in imidazolium-based ionic liquids. J Phys Chem A 114:3744–3749CrossRefGoogle Scholar
  16. Fujie K, Ikeda R, Otsubo K, Yamada T, Kitagawa H (2015) Lithium ion diffusion in a metal-organic framework mediated by an ionic liquid. Chem Mater 27:7355–7361CrossRefGoogle Scholar
  17. Furukawa H, Ko N, Go YB, Aratani N, Choi SB, Choi E, Yazaydin AO, Snurr RQ, O'Keeffe M, Kim J, Yaghi OM (2010) Ultrahigh porosity in metal-organic frameworks. Science 329:424–428CrossRefGoogle Scholar
  18. Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM (2013) The chemistry and applications of metal-organic frameworks. Science 341:1230444CrossRefGoogle Scholar
  19. Gupta KM, Chen Y, Hu Z, Jiang J (2012) Metal-organic framework supported ionic liquid membranes for CO2 capture: anion effects. Phys Chem Chem Phys 14:5785–5794CrossRefGoogle Scholar
  20. Gupta KM, Chen Y, Jiang J (2013) Ionic liquid membranes supported by hydrophobic and hydrophilic metal-organic frameworks for CO2 capture. J Phys Chem C 117:5792–5799CrossRefGoogle Scholar
  21. Hartmann M, Kunz S, Himsl D, Tangermann O, Ernst S, Wagener A (2008) Adsorptive separation of isobutene and isobutane on Cu3(BTC)2. Langmuir 24:8634–8642CrossRefGoogle Scholar
  22. Ho MT, Allinson GW, Wiley DE (2008) Reducing the cost of CO2 capture from flue gases using pressure swing adsorption. Ind Eng Chem Res 47:4883–4890CrossRefGoogle Scholar
  23. Holomb R, Martinelli A, Albinsson I, Lassègues JC, Johansson P, Jacobsson P (2008) Ionic liquid structure: the conformational isomerism in 1-butyl-3-methyl-imidazolium tetrafluoroborate ([Bmim][BF4]). J Raman Spectrosc 39:793–805CrossRefGoogle Scholar
  24. Howarth AJ, Peters AW, Vermeulen NA, Wang TC, Hupp JT, Farha OK (2017) Best practices for the synthesis, activation, and characterization of metal-organic frameworks. Chem Mater 29:26–39CrossRefGoogle Scholar
  25. Hu Y, Verdegaal WM, Yu SH, Jiang HL (2014) Alkylamine-tethered stable metal-organic framework for CO2 capture from flue gas. ChemSusChem 7:734–737CrossRefGoogle Scholar
  26. Kanchanalai P, Lively RP, Realff MJ, Kawajiri Y (2013) Cost and energy savings using an optimal design of reverse osmosis membrane pretreatment for dilute bioethanol purification. Ind Eng Chem Res 52:11132–11141CrossRefGoogle Scholar
  27. Khan NA, Hasan Z, Jhung SH (2014) Ionic liquids supported on metal-organic frameworks: remarkable adsorbents for adsorptive desulfurization. Chemistry 20:376–380CrossRefGoogle Scholar
  28. Kinik FP, Altintas C, Balci V, Koyuturk B, Uzun A, Keskin S (2016) [BMIM][PF6] incorporation doubles CO2 selectivity of ZIF-8: elucidation of interactions and their consequences on performance. ACS Appl Mater Interfaces 8:30992–31005CrossRefGoogle Scholar
  29. Koyuturk B, Altintas C, Kinik FP, Keskin S, Uzun A (2017) Improving gas separation performance of ZIF-8 by [BMIM][BF4] incorporation: interactions and their consequences on performance. J Phys Chem C 121:10370–10381CrossRefGoogle Scholar
  30. Lei Z, Dai C, Chen B (2014) Gas solubility in ionic liquids. Chem Rev 114:1289–1326CrossRefGoogle Scholar
  31. Li JR, Kuppler RJ, Zhou HC (2009) Selective gas adsorption and separation in metal-organic frameworks. Chem Soc Rev 38:1477–1504CrossRefGoogle Scholar
  32. Lin KS, Adhikari AK, Ku CN, Chiang CL, Kuo H (2012) Synthesis and characterization of porous HKUST-1 metal organic frameworks for hydrogen storage. Int J Hydrog Energy 37:13865–13871CrossRefGoogle Scholar
  33. Lin Y, Lin H, Wang H, Suo Y, Li B, Kong C, Chen L (2014a) Enhanced selective CO2 adsorption on polyamine/MIL-101(Cr) composites. J Mater Chem A 2:14658–14665CrossRefGoogle Scholar
  34. Lin Z, Lu J, Hong M, Cao R (2014b) Metal-organic frameworks based on flexible ligands (FL-MOFs): structures and applications. Chem Soc Rev 43:5867–5895CrossRefGoogle Scholar
  35. Majano G, Martin O, Hammes M, Smeets S, Baerlocher C, Pérez-Ramírez J (2014) Solvent-mediated reconstruction of the metal-organic framework HKUST-1 (Cu3(BTC)2). Adv Funct Mater 24:3855–3865CrossRefGoogle Scholar
  36. Olajire AA (2010) CO2 capture and separation technologies for end-of-pipe applications – a review. Energy 35:2610–2628CrossRefGoogle Scholar
  37. Prestipino C, Regli L, Vitillo JG, Bonino F, Damin A, Lamberti C, Zecchina A, Solari PL, Kongshaug KO, Bordiga S (2006) Local structure of framework Cu(II) in HKUST-1 metal-organic framework: spectroscopic characterization upon activation and interaction with adsorbates. Chem Mater 18:1337–1346CrossRefGoogle Scholar
  38. Rees NV, Compton RG (2011) Electrochemical CO2 sequestration in ionic liquids; a perspective. Energy Environ Sci 4:403–408CrossRefGoogle Scholar
  39. Rowsell JLC, Yaghi OM (2004) Metal-organic frameworks: a new class of porous materials. Microporous Mesoporous Mater 73:3–14CrossRefGoogle Scholar
  40. Schoenecker PM, Carson CG, Jasuja H, Flemming CJJ, Walton KS (2012) Effect of water adsorption on retention of structure and surface area of metal-organic frameworks. Ind Eng Chem Res 51:6513–6519CrossRefGoogle Scholar
  41. Seo YK, Hundal G, Jang IT, Hwang YK, Jun CH, Chang JS (2009) Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture. Microporous Mesoporous Mater 119:331–337CrossRefGoogle Scholar
  42. Sezginel KB, Keskin S, Uzun A (2016) Tuning the gas separation performance of CuBTC by ionic liquid incorporation. Langmuir 32:1139–1147CrossRefGoogle Scholar
  43. Silva P, Vilela SM, Tome JP, Almeida Paz FA (2015) Multifunctional metal-organic frameworks: from academia to industrial applications. Chem Soc Rev 44:6774–6803CrossRefGoogle Scholar
  44. Singh MP, Dhumal NR, Kim HJ, Kiefer J, Anderson JA (2016) Influence of water on the chemistry and structure of the metal-organic framework Cu3(BTC)2. J Phys Chem C 120:17323–17333CrossRefGoogle Scholar
  45. Singh MP, Dhumal NR, Kim HJ, Kiefer J, Anderson JA (2017) Removal of confined ionic liquid from a metal organic framework by extraction with molecular solvents. J Phys Chem C 121:10577–10586CrossRefGoogle Scholar
  46. Sumida K, Rogow DL, Mason JA, McDonald TM, Bloch ED, Herm ZR, Bae TH, Long JR (2012) Carbon dioxide capture in metal-organic frameworks. Chem Rev 112:724–781CrossRefGoogle Scholar
  47. Vicent-Luna JM, Gutiérrez-Sevillano JJ, Anta JA, Calero S (2013) Effect of room-temperature ionic liquids on CO2 separation by a Cu-BTC metal-organic framework. J Phys Chem C 117:20762–20768CrossRefGoogle Scholar
  48. Wang Z, Cohen SM (2009) Postsynthetic modification of metal-organic frameworks. Chem Soc Rev 38:1315–1329CrossRefGoogle Scholar
  49. Wang QM et al (2002) Metallo-organic molecular sieve for gas separation and purification. Microporous Mesoporous Mater 55:217–230CrossRefGoogle Scholar
  50. Wang B, Qin L, Mu T, Xue Z, Gao G (2017a) Are ionic liquids chemically stable? Chem Rev 117:7113–7131CrossRefGoogle Scholar
  51. Wang J, Xie D, Zhang Z, Yang Q, Xing H, Yang Y, Ren Q, Bao Z (2017b) Efficient adsorption separation of acetylene and ethylene via supported ionic liquid on metal-organic framework. AICHE J 63:2165–2175CrossRefGoogle Scholar
  52. Watanabe S, Takiwatari K, Nakano M, Miyake K, Tsuboi R, Sasaki S (2013) Molecular behavior of room-temperature ionic liquids under lubricating condition. Tribol Lett 51:227–234CrossRefGoogle Scholar
  53. Wilson M, Madden PA (1994) “Prepeaks” and “first sharp diffraction peaks” in computer simulations of strong and fragile ionic liquids. Phys Rev Lett 72:3033–3036CrossRefGoogle Scholar
  54. Xue W, Li Z, Huang H, Yang Q, Liu D, Xu Q, Zhong C (2016) Effects of ionic liquid dispersion in metal-organic frameworks and covalent organic frameworks on CO2 capture: a computational study. Chem Eng Sci 140:1–9CrossRefGoogle Scholar
  55. Zhang X, Zhang X, Dong H, Zhao Z, Zhang S, Huang Y (2012) Carbon capture with ionic liquids: overview and progress. Energy Environ Sci 5:6668–6681CrossRefGoogle Scholar
  56. Zhou HC, Kitagawa S (2014) Metal-organic frameworks (MOFs). Chem Soc Rev 43:5415–5418CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.State Key Laboratory of Coal Combustion, School of Energy and Power EngineeringHuazhong University of Science and TechnologyWuhanChina
  2. 2.Nano Interface Centre for Energy, School of Energy and Power EngineeringHuazhong University of Science and TechnologyWuhanChina

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