A general method for the synthesis of graphene-metal sulphide nanosheets

Research Paper
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Abstract

One general method was developed for the synthesis of graphene-metal sulphide nanoplates. This method was utilized for the syntheses of graphene-CdS nanoplates (G-CdS nanoplates), graphene-CuS nanoplates (G-CuS nanoplates), and graphene-SnS nanoplates (G-SnS nanoplates). As a concept proof, the G-CdS nanoplates were selected as the model to evaluate the photocatalytic activity, whereas a significant enhancement in the photoactivity was observed. This method demonstrated a general approach towards the fabrication of graphene-metal sulphide nanoplates as promising for the photocatalytic fields.

Keywords

Graphene Metal sulphide nanoplates Photocatalysts Synthesis methods 

Notes

Acknowledgments

This work was supported by the Natural Science Foundation of China (NSFC, No. 50972043), the Construct Program of the Key Discipline in Hunan Province and Project of the Natural Science Foundation of Hunan Province (2017JJ2191), and the General project of Hunan Provincial Education Department (14C0793).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

References

  1. Agileo HG, García-Mendoza C, Alvarez-Lemus MA et al (2015) Photocatalytic reduction of Cr(VI) by using stacked ZnS layers of ZnS (en)x complex. Journal of environmental chemical engineering 3:3048–3054CrossRefGoogle Scholar
  2. Bai S, Shen XP (2012) Graphene–inorganic nanocomposites. RSC Adv 2:64–98CrossRefGoogle Scholar
  3. Cao SY, Chen CS, Zhang JY et al (2015) MnOx quantum dots decorated reduced graphene oxides/TiO2 nanohybrids for enhanced activity by a UV pre-catalytic microwave method. Appl Catal B Environ 176:500–512CrossRefGoogle Scholar
  4. Chen Z, Siqi Liu SQ, Yang MQ et al (2013) Synthesis of uniform CdS nanospheres/graphene hybrid nanocomposites and their application as visible light photocatalyst for selective reduction of nitro organics in water. ACS Appl Mater Interfaces 5:4309–4319CrossRefGoogle Scholar
  5. Chen CS, Yu WW, Liu TG et al (2017) Graphene oxides/WS2/Mg-doped ZnO nanocomposites for solar-light catalytic and anti-bacterial applications. Solar cells 160:43–53CrossRefGoogle Scholar
  6. Dacula J, Mangadlao, Cao PF et al (2017) Photoreduction of graphene oxide and photochemical synthesis of graphene−metal nanoparticle hybrids by Ketyl radicals. ACS Appl Mater Interfaces 9:24887–24898CrossRefGoogle Scholar
  7. He J, Chen L, Yi ZQ, Ding D, Au CT, Yin SF (2017) Fabrication of two-dimensional porous CdS nanoplates decorated with C3N4 nanosheets for highly efficient photocatalytic hydrogen production from water splitting. Catal Commun 99:79–82CrossRefGoogle Scholar
  8. Lei YG, Yang C, Hou JH et al (2017) Strongly coupled CdS/graphene quantum dots nanohybrids for highlyefficient photocatalytic hydrogen evolution: unraveling the essentialroles of graphene quantum dots. Appl Catal B Environ 216:59–69CrossRefGoogle Scholar
  9. Liu JY, Guo Z, Meng FL et al (2009) Novel porous single-crystalline ZnO nanosheets fabricated by annealing ZnS(en)0.5 (en = ethylenediamine) precursor. Application in a gas sensor for indoor air contaminant detection. Nanotechnology 20:125501–125508CrossRefGoogle Scholar
  10. Liu Y, Hu JC, Zhou TF et al (2011) Self-assembly of layered wurtzite ZnS nanorods/nanowires as highly efficient photocatalysts. J Mater Chem 21:16621–16627CrossRefGoogle Scholar
  11. Liu FZ, Shao X, Wang JQ et al (2013) Solvothermal synthesis of graphene–CdS nanocomposites for highly efficient visible-light photocatalyst[J]. J Alloys Compd 551:327–332CrossRefGoogle Scholar
  12. Titipun T, Chalermchai P, Somchai T (2010) Large-scale synthesis of CuS hexaplates in mixed solvents using a solvothermal method. Mater Lett 64:111–114CrossRefGoogle Scholar
  13. Xian JG, Li DZ, Chen J et al (2014) TiO2 nanotube array-graphene-CdS quantum dots composite film in Z-scheme with enhanced photoactivity and photostability. ACS Appl Mater Interfaces 6:13157–13166CrossRefGoogle Scholar
  14. Xiong DN, Huang GF, Zhou BX, Yan Q, Pan AL, Huang WQ (2016) Facile ion-exchange synthesis of mesoporous Bi2S3/ZnS nanoplate with high adsorption capability and photocatalytic activity. J Colloid Interface Sci 464:103–109CrossRefGoogle Scholar
  15. Zeng B, Chen XH (2016) A general method for the synthesis of metal (Cd, Zn) sulphide nanorods/graphene for use as a high performance photocatalyst. Digest journal of nanomaterials and biostructures 11(2):559–566Google Scholar
  16. Zeng B, Chen XH, Tang QX et al (2014) Ordered mesoporous necklace-like ZnS on graphene for use as a high performance photocatalyst. Appl Surf Sci 308:321–327CrossRefGoogle Scholar
  17. Zhang N, Zhang YH, Pan XY et al (2011) Assembly of CdS nanoparticles on the two-dimensional graphene scaffold as visible-light-driven photocatalyst for selective organic transformation under ambient conditions. J Phys Chem C 115:23501–23511CrossRefGoogle Scholar
  18. Zhang YG, Tian JQ, Li HY et al (2012) Biomolecule-assisted, environmentally friendly, one-pot synthesis of CuS/reduced graphene oxide nanocomposites with enhanced photocatalytic performance. Langmuir 28:12893–12900CrossRefGoogle Scholar

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© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Mechanical EngineeringHunan University of Arts and ScienceChangdePeople’s Republic of China
  2. 2.Hunan Collaborative Innovation Center for Construction and Development of Dongting Lake Ecological Economic ZoneChangdePeople’s Republic of China

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