Melting of Gold-Containing Concentrates with Copper Production Lead Slags
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Results are presented for a study of the pyrometallurgical treatment of gold-arsenic concentrates with lead osmium-rhenium-containing slags. Conditions are found for preparing alloy ingots consisting of lead, or predominantly of lead sulfide, or both phases. It is shown that with gravitation deposition up to 65–68% osmium is concentrated in 17–25% matte. Gold is almost uniformly distributed over the height of ingots. For industrial application of the results obtained, it is recommended that molten products are poured into a mold heated to 500–550°C, and after natural cooling the lower 25% of alloy is separated for osmium extraction, and gold is extracted from the rest of the alloy by well-known technology. Reduction kinetics are studied for gold, osmium, rhenium, and arsenic. According to kinetic curves, recovery of rhenium in slag proceeds rapidly; osmium recovery ceases in 20–25 min; gold is concentrated in the alloy in 10 min. arsenic is transferred into a gas phase in 10 min, and its concentration in alloy comprises 0.2% on average, and in slags 0.27–0.63%.
Keywords
gold-arsenic concentrate lead osmium rhenium-containing slag meltingReferences
- 1.S. T. Shalgymbaev, A. S. Bolotova, and B. Dzhalalov, “Hydrometallurgical technology for processing carbonaceous gold-containing sulfide ores,” Prom. Kazakhstana, No. 1 (82), 50–55 (2014).Google Scholar
- 2.V. S. Chekushin and S. V. Olenikova, “Treatment of gold-containing ire concentrates (review of methods),” Izv. Chelyabinsk. Nauch. Tsentra, No. 4 (30), 94–101 (2005).Google Scholar
- 3.M. G. Aylmore and D. M. Muir, “Thiosulphate leaching of gold – a review,” Minerals Eng., 14, No. 2, 135–174 (2001).CrossRefGoogle Scholar
- 4.G. Hilson and A. I. Monhemius, “Alternatives to cyanide in the gold mining industry: What prospects for the future?” J. Production, Nо. 14, 1158–1167 (2006).Google Scholar
- 5.D. V. Gradov, D. M. Sizyakov, and M. Neuvonen, “Study of the effect of oxidation of concentrate on thiosulfate leaching of gold,” Zap. Gorn. Inst., 202, 72–74 (2013).Google Scholar
- 6.Sh. R. Samikhov and Z. A. Zinchenko, “Study of thiosulfate leaching of gold-arsenic containing ore of the Chore deposit,” Dokl. AN Resp. Tadzhikistan, 52, No. 2, 145–150 (2014).Google Scholar
- 7.K. G. Thomas. Research, Engineering Design and Operation of a Pressure Hydrometallurgy Facility for Gold Extraction, Delft, The Netherlands (1994).Google Scholar
- 8.I. A. Rojas-Chapana and H. Tributsch, “Biochemistry of sulfur extraction in biocorrоsion of pyrite by Thiobacillius ferrooxidans,” Hydrometallurgy, 59, No. 2–3, 291–300 (2001).Google Scholar
- 9.Ji Jinxig, C. A Fleming, G. Paul, and P. Ralph, Patents 6.660.059, 7.066.983 USA, “Method for thiosulfate leaching of precious metal-containing matenais” (2003, 2006).Google Scholar
- 10.A. S. Gudkov, G. G. Minaev, and I. A. Zhuchkov, “Evaluation of autoclave oxidation of sulfide concentrates applied to successive thiosulfate leaching of precious metals,” Vestn. IrGTU, No. 3 (43), 80–84 (2010).Google Scholar
- 11.K. G. Thomas and D. A. Mike, Developments in Mineral Processing. Advances in Gold Ore Processing, B. A. Wills (Series ed.) (2005), No. 15, pp. 346–370.Google Scholar
- 12.C. J. Ferron, Recovery of Gold as Byproduct from the Base-Metals Industries. Advances in Gold Ore Processing, M. D. Adams (ed.) (2005), Chpt. 35, pp. 861–896.Google Scholar
- 13.A. Paul and Kohe, Electrodeposition of Gold. Modern Electroplating, John Wiley & Sons, Inc., (2010), 5th ed., pp. 115–130.Google Scholar
- 14.A. V. Epiforov, S. S. Gudkov, and S. V. Balikov, Patent 2528300 RF, IPC C22B/00, “Method for treating sulfide raw material containing precious metals,” subm. 11.19.2012, publ. 09.10.2014.Google Scholar
- 15.A. V. Epiforov, et al., “Selection of treatment technology for Bereznyakovskoe deposit ore flotation concentrate,” Tsvet. Met., No. 11, 32–35 (2013).Google Scholar
- 16.A. P. Epoforov, R. N. Nabiulin, and S. V. Balikov, “Low-temperature autoclave oxidation of tenacious sulfide gold-copper flotation concentrates followed by sulfite leaching of precious metals from oxidized slags,” Izv. VUZ., Prikl. Khim. Biotekhnol., No. 3 (80), 31–38 (2014).Google Scholar
- 17.A. N. Zagorodnyaya, Z. S. Abisheva, and A. S. Sharipova, “Contemporary state of ammonium perrhenate production in Kazakhstan,” ibid., 27–30.Google Scholar
- 18.A. A. Zharmenov, O. A. Sydykov, E. A. Mazulevskii, et al., Patent 27199 RK, “Method for treating lead-containing materials,” subm. 06.08.2011, publ. 07.05.2013.Google Scholar
- 19.A. O. Sadykov, E. A. Mazulevskii, F. A. Berdikulova, et al., “Study of the effect of chemical composition of lead slag on production indices of reduced melt,” Prom. Kazakhstana, No. 8, 73–75 (2011).Google Scholar