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Journal of Thermal Analysis and Calorimetry

, Volume 138, Issue 4, pp 2955–2967 | Cite as

Early hydration calorimetric study of the sewage sludge incinerated waste streams Portland cement-based binders: technological implications

  • Lidia Natalia TrusilewiczEmail author
  • Wiesława Nocuń-Wczelik
  • Piotr Górak
  • Piotr Woyciechowski
Article

Abstract

The research study forms a part of the “Management of municipal water waste treatment plants potential by-products of sewage sludge ash type, as active or non-active additions to Portland cement-based binders” project’s outcomes (H2020-MSCA-IF-2016-746830). Based on the applied techniques characteristics (non-isothermal and non-adiabatic differential micro-calorimeter, SEM/EDS and XRF analysis), this study comprises the very first stage for a sustainable conversion of each of the considered 190114 and 190107* waste streams into a value-added by-product for specific constructive applications. Provided technical requirements regarding the designed cementitious products handling and suggested industrial application are focused on the early performance of the tested for quality and consistency, pastes, mortars and concretes. In detail, the obtained physical–chemical parameters show substantial differences of the original waste streams regarding their technological origin, seasonability and geographical localisation. Consequently, the calorimetric curves exhibit diverse early chemistry of the produced cements, showing the considerable variations in mineral nature (siliceous, aluminous) or hydraulic factor contents (reactive silica, SiO2r−, and reactive alumina, Al2O3r−) of the observed pozzolanic activities. Setting retarding phenomenon and shrinkage reducing effects are also carefully discussed. All the calorimetric and pozzolanic activity related data is contrasted with two other reference materials, fly ash and granulated blast furnace slag, standard behaviour.

Keywords

Sewage sludge ash Eco-cements Fluidised-bed combustion Heat hydration Supplementary cementitious materials Strength development 

Notes

Acknowledgements

Research data and results dissemination of this article was funded by the European Union’s Horizon 2020 Marie Skłodowska Curie—Individual Fellowship research and innovation programme under Grant Agreement No. 746830 (H2020-MSCA-IF-2016). https://sewagesludgeinpc.wordpress.com. The authors would like to thank “GOŚ-Łódź” and “Czajka” Municipal Wastewater Treatment plants for the provided waste stream materials. Special thanks belong also to both CEMEX Poland and Odra SA Cement Mill in Poland for the provided standardised materials.

References

  1. 1.
    JCR 53238 report. End-of-Waste Criteria. 2009. ISBN 978-92-79-13422-7.  https://doi.org/10.2791/28650.
  2. 2.
    Nocun-Wczelik W, Trybalska B, Żugaj E. Application of calorimetry in evaluation the effect of carbonate additives on cement hydration. J Therm Anal Calorim. 2013;113:351–6.  https://doi.org/10.1007/s10973-013-2994-6.CrossRefGoogle Scholar
  3. 3.
    European norm EN 450-1:2012. Fly ash for concrete. Definition, specifications and conformity criteria.Google Scholar
  4. 4.
    European norm EN 15167-1:2016. Ground granulated blast furnace slag for use in concrete, mortar and grout. Part 1: Definitions, specifications and conformity criteria.Google Scholar
  5. 5.
    European norm EN 197-1:2011. Cement. Composition, specifications and conformity criteria for common cements.Google Scholar
  6. 6.
    European norm EN 196-2:2014. Method of testing cement. Part 2: Chemical analysis of cement.Google Scholar
  7. 7.
    Nocuń-Wczelik W. Differential calorimetry as a tool in the studies of cement hydration kinetics with sulfate and nitrate solutions. J Therm Anal Calorim. 2017;130:249–59.  https://doi.org/10.1007/s10973-017-6378-1.CrossRefGoogle Scholar
  8. 8.
    European norm EN 196-5:2011. Methods of testing cement. Part 5: Pozzolanicity test for pozzolanic cement.Google Scholar
  9. 9.
    ASTM C311-13. Standard test methods for sampling and testing fly ash or natural pozzolans for use in portland-cement concrete. Subcommittee: C09.24. Book of standards volume: 04.02.Google Scholar
  10. 10.
    European norm EN 196-1:1996. Methods of testing cement. Part 1: Determination of strength.Google Scholar
  11. 11.
    European norm EN 12390-2:2009. Testing hardened concrete. Part 2: Making and curing specimens for strength tests.Google Scholar
  12. 12.
    Kruger O. Complete survey of German sewage sludge ash. Environ Sci Technol. 2014;48(20):11811–8.  https://doi.org/10.1021/es502766x.CrossRefPubMedGoogle Scholar
  13. 13.
    Stempkowska A, Kępys W, Pietrzyk J. The influence of incinerated sewage sludge ashes physical and chemical properties in possibility of usage in red ceramic. Gospodarka Surowcami Mineralnymi—Mineral Resources Management. 2015;31(2):109–22.  https://doi.org/10.1515/gospo-2015-0014.CrossRefGoogle Scholar
  14. 14.
    Záleská M, Pavlík Z, Pavlíková M, Scheinherrová L, Pokorný J, Trník A, Svora P, Fořt J, Jankovský O, Suchorab Z, Černý R. Biomass ash-based mineral admixture prepared from municipal sewage sludge and its application in cement composites. Clean Technol Environ Policy. 2018;20(1):159–71.  https://doi.org/10.1007/s10098-017-1465-3.CrossRefGoogle Scholar
  15. 15.
    Liu M, Zhao Y, Xiao Y, Yu Z. Performance of cement pastes containing sewage sludge ash at elevated temperatures. Constr Build Mater. 2019;211:785–95.  https://doi.org/10.1016/j.conbuildmat.2019.03.290.CrossRefGoogle Scholar
  16. 16.
    Trusilewicz LN. Quantitative determination of reactive alumina content, natural and artificial, by thermogravimetry and Rietveld method. Ph.D. thesis, Technical University of Madrid, Spain 2014. http://oa.upm.es/22743/.
  17. 17.
    Trusilewicz LN, Nocuń-Wczelik W, Górak P, Woyciechowski P. Optimising the cementitious conglomerates of fluidised-bed incinerated sewage sludge ash streams for specific applications. In: 6th MCAA general assembly and annual conference. Research and innovation beyond the information age. Proceedings Book 2019. Marie Curie Alumni Association (MCAA), February 24th–25th 2019, Vienna (Austria). https://www.mariecuriealumni.eu/mcaa-events/2019-mcaa-general-assembly-annual-conference.
  18. 18.
    Trusilewicz LN, Woyciechowski P, Górak P, Nocuń-Wczelik W. CEM I and III based paste, mortar and concrete products, manufactured with fluidised-bed incinerated sewage sludge ashes. In: 10th International concrete congress (ICCC). Recent advances in concrete technology. Sustainable concrete—urban transformation waste, life cycle analysis, recycled materials. May 2nd–4th 2019, Bursa (Turkey). Proceedings Book 2019; p. 338–47. ISBN 978-605-01-1276-4.Google Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019
corrected publication 2019

Authors and Affiliations

  1. 1.Research and Innovation Centre Pro-AkademiaKonstantynów ŁódzkiPoland
  2. 2.Faculty of Materials Science and CeramicsAGH University of Science and TechnologyKrakówPoland
  3. 3.Technology and Quality Management Group, Concrete Quality and Technology TeamCEMEX Poland Sp. o.o.RudnikiPoland
  4. 4.Faculty of Civil Engineering, Institute of Building EngineeringWarsaw University of TechnologyWarszawaPoland

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