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Nickel selenate: a deep and efficient characterization

  • Caroline Gaglieri
  • Rafael T. Alarcon
  • Aniele de Moura
  • Flávio J. CairesEmail author
Article
  • 53 Downloads

Abstract

This work aims to determine the nickel selenate hexahydrate thermal behavior by simultaneous thermogravimetry–differential thermal analysis and differential scanning calorimetry and characterize its thermal intermediates decomposition. Moreover, at 25 °C, this material is a green-colored compound; however, with the temperature increase (until 420 °C), a color change from yellowish green to yellowish orange and finally to yellow was observed. This characteristic is due to the water molecules release, changing the ultraviolet–visible/near-infrared spectroscopy analysis absorption spectra and consequently modifying the crystal structure, as confirmed by X-ray powder diffraction, and resulting in visual changes in photo-DSC. The new data are essential to determine the better conditions to use this material as a precursor in synthesis and also to use it in future applications.

Keywords

Characterization Thermal properties Color change Nickel selenate hexahydrate 

Notes

Acknowledgements

The authors wish to thank CAPES (grant 024/2012 Pro-equipment), CNPq (grant No. 421469/2016-1) and FAPESP (grants No. 2017/14936-9, No. 2018/03460-6, No. 2018/12463-9 and No. 2018/24378-6) for financial support.

Supplementary material

Photo-DSC video of nickel selenate hexahydrate (MP4 1827 kb)

10973_2019_8623_MOESM2_ESM.tif (84 kb)
MIR spectra of H2SeO4 (a), NiSeO4·6H2O (b), and NiSeO4·0.5H2O (c) (TIFF 83 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.UNESP-São Paulo State UniversityChemistry Department, School of SciencesBauruBrazil
  2. 2.UNESP-São Paulo State UniversityInstitute of ChemistryAraraquaraBrazil

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