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Characterization of Simarouba glauca seed oil biodiesel

A comprehensive study
  • P. JeyalakshmiEmail author
Article
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Abstract

Simarouba glauca seed oil was identified as a possible feedstock to produce biodiesel. The oil was produced through two-stage esterification process using concentrated sulphuric acid and sodium hydroxide as catalysts. Simarouba glauca seed oil biodiesel was blended with diesel in various proportions, and its thermo-physical properties were characterized by chromatographic and spectroscopic techniques. Moreover, the performance and emission characteristics were evaluated in a single-cylinder direct injection diesel engine. The free fatty acid content of the oil was reduced from 3.5 to 0.2%. The results showed that the Simarouba glauca seed oil (SGO) is having good potential of replacing diesel in near future. The performance and emission characteristics of Simarouba seed oil were observed to be good when compared to diesel and satisfied with the limits prescribed in the ASTM D6751, BIS and European standards.

Keywords

Biodiesel Simarouba glauca seed oil Characterization Free fatty acid Esterification 

Notes

References

  1. 1.
    Largest consumer of crude and petroleum products. http://oilprice.com. Accessed 09 Dec 15.
  2. 2.
    Sathiyamoorthi R, Sankaranarayanan G. Effect of antioxidant additives on the performance and emission characteristics of a DICI engine using neat lemongrass oil–diesel blend. Fuel. 2016;174:89–96. http://articles.energy.economictimes.indiaimes.com.
  3. 3.
    Freire LMS, Bicudo TC, Rosenhaim R, Sinfrônio FSM, Botelho JR, Carvalho Filho JR, Santos IMG, Fernandes VJ, Antoniosi Filho NR, Souza AG. Thermal investigation of oil and biodiesel from Jatropha curcas L. J Therm Anal Calorim. 2009;96:1029–33.CrossRefGoogle Scholar
  4. 4.
    Lujaji F, Bereczky A, Janosi I, Novak CS, Mbarawa M. Cetane number and thermal properties of vegetable oil, biodiesel, 1-butanol and diesel blends. J Therm Anal Calorim. 2010;102:1175–81.CrossRefGoogle Scholar
  5. 5.
    Kumar A, Sharma S. Potential non-edible oil resources as biodiesel feedstock: an Indian perspective. Renew Sustain Energy Rev. 2011;15:1791–800.CrossRefGoogle Scholar
  6. 6.
    Atabani AE, Silitonga AS, Ong HC, Mahlia TMI, Masjuki HH, IrfanAnjumBadruddin, Fayaz H. Non-edible vegetable oils: a critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production. Renew Sustain Energy Rev. 2013;18:211–45.CrossRefGoogle Scholar
  7. 7.
    James P, Khizer S. An overview of biodiesel oxidation stability. Renew Sustain Energy Rev. 2012;16:5924–50.CrossRefGoogle Scholar
  8. 8.
    Du Plessis LM, De Villiers JBM, Van Der Walt WH. Stability studies on methyl and ethyl fatty acid esters of sunflower seed oil. J Am Oil Chem Soc. 1985;62(4):748–52.CrossRefGoogle Scholar
  9. 9.
    Bondioli P, Gasparoli A, Lanzani A, Fedeli E, Veronese S, Sala M. Storage stability of biodiesel. J Am Oil Chem Soc. 1995;72(6):699–702.CrossRefGoogle Scholar
  10. 10.
    Obadiah A, Kannan R, Ramasubbu A, Kumar SV. Studies on the effect of antioxidants on the long-term storage and oxidation stability of Pongamia pinnata (L.) biodiesel. Fuel Process. Technol. 2012;99:56–63.CrossRefGoogle Scholar
  11. 11.
    Joshi S, Shantha H. Simarouba a potential oilseed tree. Curr Sci. 2000;78:694–7.Google Scholar
  12. 12.
    Devan PK, Mahalakshmi NV. Utilization of unattended methyl ester of paradise oil as fuel in diesel engine. Fuel. 2009;88(10):1828–33.CrossRefGoogle Scholar
  13. 13.
    Devan PK, Mahalakshmi NV. A study of the performance, emission and combustion characteristics of a compression ignition engine using methyl ester of paradise oil–eucalyptus oil blends. Appl Energy. 2009;86(5):675–80.CrossRefGoogle Scholar
  14. 14.
    Jeyalakshmi P, Subramanian R. The application of response surface methodology for the optimization of pretreatment of process parameters of paradise seed (Simarouba glauca) oil. Energy Source Part A. 2013;35:2087–95.CrossRefGoogle Scholar
  15. 15.
    Jena PC, Raheman H, Prasanna Kumar GV, Machavaram R. Biodiesel production from mixture of Mahua and Simarouba oils with high free fatty acids. Biomass Bioenergy. 2010;34:1108–16.CrossRefGoogle Scholar
  16. 16.
    Jeyalakshmi P, Subramanian R, Nedunchezhian N. Biodiesel production from two stage esterification of Simarouba glauca seed oil and its characterization. Energy Source Part A. 2016;38:1163–8.CrossRefGoogle Scholar
  17. 17.
    Peterson C, Auid L. Proceedings of solid fuel conversion for the transportation sector. ASME. 1991;12:45–54.Google Scholar
  18. 18.
    Ramadhas AS, Jayaraj S, Muraleedharan C. Use of vegetable oils as IC engine fuels—a review. Renew Energy. 2004;29(5):727–42.CrossRefGoogle Scholar
  19. 19.
    Noureddini H, Teoh BC, Clements DL. Viscosities of vegetable oils and fatty acids. JAOCS. 1992;69:1189–91.CrossRefGoogle Scholar
  20. 20.
    Rodrigues JA, Cardoso FP, Lachter ER, Estevao LRM, Lima E, Nascimento RS. Correlating chemical structure and physical properties of vegetable oil esters. JAOCS. 2006;83:353–7.CrossRefGoogle Scholar
  21. 21.
    Freedman B, Bagby MO. Heat of combustion of fatty esters and triglycerides. JAOCS. 1989;66:1601–5.CrossRefGoogle Scholar
  22. 22.
    AOCS Official Method CA 5a-40. In: Firestone D (ed) Official methods and recommended practices of the American Oil Chemists Society, 4th edn. AOCS, Champaign.Google Scholar
  23. 23.
    Issariyakul T, Kulkarni MG, Dalai AK, Bakhshi NN. Production of biodiesel from waste fryer grease using mixed methanol/ethanol system. Fuel Process Technol. 2007;88:429–36.CrossRefGoogle Scholar
  24. 24.
    Rizwanul Fattah IM, Masjuki HH, Kalam MA, et al. Experimental investigation of performance and regulated emissions of a diesel engine with Calophyllum inophyllum biodiesel blends accompanied by oxidation inhibitors. Energy Convers Manag. 2014;83:232–40.CrossRefGoogle Scholar
  25. 25.
    Gelbard G, Bres O, Vargas RM, Vielfaure F, Schuchardt UF. 1H nuclear magnetic resonance determination of the yield of the transesterification of rapeseed oil with methanol. J Am Oil Chem Soc. 1995;72:1239–41.CrossRefGoogle Scholar
  26. 26.
    Tariq M, Ali S, Ahmad S, Ahmad F, Zafar M, Khalid N, Khan MA. Identification, FT-IR, NMR (1H and 13C) and GC/MS studies of fatty acid methyl esters in biodiesel from rocket seed oil. Fuel Process Technol. 2010;92:336–41.CrossRefGoogle Scholar
  27. 27.
    Vlahov G. Application of NMR to the study of olive oils. Prog Nucl Magn Reson Spectrosc. 1999;35:341–57.CrossRefGoogle Scholar
  28. 28.
    Oromi-Farrus M, Villorbina G, Eras J, Gatius F, Torres M, Canela R. Determination of the iodine value of biodiesel using 1H NMR with 1,4-dioxane as an internal standard. Fuel. 2010;89:3489–92.CrossRefGoogle Scholar
  29. 29.
    Miyake Y, Yokomizo K, Matsuzaki N. Determination of unsaturated fatty acid composition by high-resolution nuclear magnetic resonance spectroscopy. J Am Oil Chem Soc. 1988;75:1091–4.CrossRefGoogle Scholar
  30. 30.
    Rani B, Bhagat SP, Taware A, Chavan M, Kulkarni DK. Physio-chemical analysis, NMR spectroscopy and gas chromatographic studies of Jatropha curcas L. germplasm. J Am Oil Chem Soc. 2011;88:337–40.CrossRefGoogle Scholar
  31. 31.
    Shiao T, Shiao MS. Determination of fatty acid compositions of triacylglycerols by high resolution NMR spectroscopy. Bot Bull Acad Sin. 1989;30:191–9.Google Scholar
  32. 32.
    Monteiro MR, Ambrozin ARP, Liao LM, Ferreira AG. Determination of biodiesel blend levels in different diesel samples by H NMR. Fuel. 2009;88:691–6.CrossRefGoogle Scholar
  33. 33.
    Ramadhas AS, Jayaraj S, Muraleedharan C. Biodiesel production from high FFA rubber seed oil. Fuel. 2005;84(4):335–40.CrossRefGoogle Scholar
  34. 34.
    Rakopoulos CD, Antonopoulos KA, Rakopoulos DC, Kakaras EC, Pariotis EG. Characteristics of the performance and emissions of a HSDI diesel engine running with cottonseed oil or its methyl ester and their blends with diesel fuel. Int J Veh Des. 2007;45(1–2):200–21.CrossRefGoogle Scholar
  35. 35.
    Nwafor OMI. The effect of elevated fuel inlet temperature on performance of diesel engine running on neat vegetable oil at constant speed conditions. Renew Energy. 2003;28:171–81.CrossRefGoogle Scholar
  36. 36.
    Ramadhas AS, Muraleedharan C, Jayaraj S. Performance and emission evaluation of a diesel engine fuelled with methyl esters of rubber seed oil. Renew Energy. 2005;30:1789–800.CrossRefGoogle Scholar
  37. 37.
    Huzayyin AS, et al. Experimental evaluation of diesel engine performance and emission using blends of jojoba oil and diesel fuel. Energy Convers Manag. 2004;45:2093–112.CrossRefGoogle Scholar
  38. 38.
    Nwafor OMI, Rice G. Performance of rapeseed methyl ester in diesel engine. Renew Energy. 1995;6:335–42.CrossRefGoogle Scholar
  39. 39.
    Monyem A, Van Gerpen JH. The effect of biodiesel oxidation on engine performance and emissions. Biomass Bioenergy. 2001;20(4):317–25.CrossRefGoogle Scholar
  40. 40.
    Kawano D, Ishii H, Goto Y, Noda A, Aoyagi Y. Application of biodiesel fuel to modern diesel engine. SAE Paper No. 2006-01-0233 2006.Google Scholar
  41. 41.
    Gebremariam SN, Marchetti JM. Economics of biodiesel production: review. Energy Convers Manag. 2018;168(74):84.Google Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.Department of Mechanical EngineeringHindusthan College of Engineering and TechnologyCoimbatoreIndia

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