Structural and thermal investigation of Ta–25 mass% Cu alloy prepared by mechanosynthesis route
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A mixture of Ta and 25 mass% Cu elemental powders was subjected to mechanical alloying in a high-energy ball mill up to 60 h. The results are composite particles formed by nanocrystalline Cu and amorphous Ta phases. Thermal stability of amorphous was investigated by DSC. The XRD, FTIR and EDX analyses of Ta–25 mass% Cu powder milled for 60 h performed after DSC at 800 and 900 °C have revealed large amounts of Ta nitride and Ta oxides even though the milling process was done in Ar atmosphere. This is due to high reactivity of Ta fine particles with oxygen and nitrogen from air. During manipulations of the powder (taking samples from vials and its investigation), the adsorption phenomena on its surface occur, and both surface-adsorbed N2 and O2 are processed with powder and embedded in it. While heating of Ta–25% Cu milled powder in DSC, nitrogen and oxygen diffusion into tantalum is activated, and Ta2N and TaO2/Ta2O5 compound forms.
KeywordsTa–Cu amorphous phase DSC Mechanical alloying Ta oxides Ta nitrides
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The authors declare that they have no conflict of interest.
- 1.Predel B. Cu–Ta, thermodynamic properties—phase equilibria, crystallographic and thermodynamic data of binary alloys. Berlin: Springer; 1994.Google Scholar
- 24.Colthup N. Introduction to infrared and Raman spectroscopy. Amsterdam: Elsevier; 2012.Google Scholar
- 27.Epifani M, Zamani R, Arbiol J, Fabrega C, Andreu T, Pace GB, Morante JR. Soft chemistry routes to transparent metal oxide thin films. The case of sol–gel synthesis and structural characterization of Ta2O5 thin films from tantalum chloromethoxide. Thin Solid Films. 2014;555:39–41.CrossRefGoogle Scholar