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Construction of a double-layered polyelectrolyte-coated mesoporous silica containing residues of biogenic aspartic acid and its utilization for cadmium (II) removal

  • Zakariyah A. JamiuEmail author
  • Shaikh A. Ali
Original Paper: Sol–gel and hybrid materials with surface modification for applications
  • 29 Downloads

Abstract

Highly efficient porous adsorbent has been developed by simple and inexpensive surface modification of mesoporous SBA-15 via an alternate adsorption of cationic poly(diallyldimethylammonium ion) and anionic poly(diallylaspartate). The nature of the charge on the surface after modification was confirmed by Zeta potential measurement. The surface morphology, topography, and its textural properties were examined by atomic force microscopy (AFM) and Nitrogen adsorption/desorption, respectively. TGA has been performed to ascertain the amount of polymer layer on the silica material. Multi-parameter isotherm models were used for the analyses of experimental data. The new protocol is found to be very impressive in the removal of toxic Cd(II) pollutant with an experimental maximum uptake capacity of 160 mg g–1.

Bilayered polyelectrolyte-coated silica for remediation of wastewater with enhanced removal of Cd ions.

Highlights

  • An aspartic acid-based polymer was immobilized on mesoporous silica SBA-15.

  • Modification of the silica surface was achieved via simple layer-by-layer deposition.

  • The biogenic amino acid residues imparted remarkable efficacy to remove Cd(II).

Keywords

Wastewater treatment Cadmium(II) Adsorption SBA-15, aspartic acid Layer-by-Layer Mesoporous adsorption 

Notes

Acknowledgements

This work was supported by King Abdulaziz City for Science and Technology (KACST) [project No. AR-32-99].

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10971_2019_4920_MOESM1_ESM.docx (107 kb)
Supplementary Materials

References

  1. 1.
    Järup L, Åkesson A (2009) Current status of cadmium as an environmental health problem. Toxicol Appl Pharmacol 238:201–208.CrossRefGoogle Scholar
  2. 2.
    Peters JL, Perlstein TS, Perry MJ, McNeely E, Weuve J (2010) Cadmium exposure in association with history of stroke and heart failure. Environ Res 110:199–206.CrossRefGoogle Scholar
  3. 3.
    Biswas B, Sarkar B, Mandal A, Naidu R (2016) Specific adsorption of cadmium on surface-engineered biocompatible organoclay under metal-phenanthrene mixed-contamination. Water Res 104:119–127.CrossRefGoogle Scholar
  4. 4.
    Chen YY, Yu SH, Jiang HF, Yao QZ, Fu SQ, Zhou GT (2018) Performance and mechanism of simultaneous removal of Cd(II) and Congo red from aqueous solution by hierarchical vaterite spherulites. Appl Surf Sci 444:224–234.CrossRefGoogle Scholar
  5. 5.
    Novacek M, Jankovsky O, Luxa J, Sedmidubsky D, Pumera M, Fila V et al. (2017) Tuning of graphene oxide composition by multiple oxidations for carbon dioxide storage and capture of toxic metals J Mater Chem A 5:2739–2748.CrossRefGoogle Scholar
  6. 6.
    Hossein Beyki M, Ghasemi MH, Jamali A, Shemirani F (2017) A novel polylysine–resorcinol base γ-alumina nanotube hybrid material for effective adsorption/preconcentration of cadmium from various matrices. J Ind Eng Chem 46:165–174.CrossRefGoogle Scholar
  7. 7.
    Das SK, Wang X, Ostwal MM, Lai Z (2016) A highly stable microporous covalent imine network adsorbent for natural gas upgrading and flue gas CO2 capture. Sep Purif Technol 170:68–77.CrossRefGoogle Scholar
  8. 8.
    Marczewski AW, Derylo-Marczewska A, Skrzypek I, Pikus S, Kozak M (2009) Study of structure properties of organized silica sorbents synthesized on polymeric templates. Adsorption 15:300–305.CrossRefGoogle Scholar
  9. 9.
    Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD et al. (1992) A new family of mesoporous molecular sieves prepared with liquid crystal templates J Am Chem Soc 114:10834–10843.CrossRefGoogle Scholar
  10. 10.
    Feng X, Fryxell GE, Wang L-Q, Kim AY, Liu J, Kemner KM (1997) Functionalized Monolayers on Ordered Mesoporous Supports. Science (80) 276:923–926.CrossRefGoogle Scholar
  11. 11.
    Walcarius A, Mercier L (2010) Mesoporous organosilica adsorbents: nanoengineered materials for removal of organic and inorganic pollutants. J Mater Chem 20:4478–4511.CrossRefGoogle Scholar
  12. 12.
    Yantasee W, Rutledge RD, Chouyyok W, Sukwarotwat V, Orr G, Warner CL et al. (2010) Functionalized nanoporous silica for the removal of heavy metals from biological systems: adsorption and application ACS Appl Mater Interfaces 2:2749–2758.CrossRefGoogle Scholar
  13. 13.
    Netzer LSJ (1983) ω-Hexadecenyltrichlorosilane has proven to be a useful, modifiable, siloxy-anchored amphiphile. J Am Chem Soc 105:674–676.CrossRefGoogle Scholar
  14. 14.
    Mihai M, Schwarz S, Janke A, Ghiorghiţǎ CA, Drǎgan ES (2013) Silica microparticles surface coating by layer-by-layer or polyelectrolyte complex adsorption. J Polym Res 20: 89.  https://doi.org/10.1007/s10965-013-0089-5.
  15. 15.
    Dragan ES, Schwarz S, Eichhorn K-J (2010) Specific effects of the counterion type and concentration on the construction and morphology of polycation/azo dye multilayers. Colloids Surf A 372:210–216.CrossRefGoogle Scholar
  16. 16.
    Yasmin T, Müller K (2011) Synthesis and characterization of surface modified SBA-15 silica materials and their application in chromatography. J Chromatogr A 1218:6464–6475.CrossRefGoogle Scholar
  17. 17.
    Jamiu ZA, Al-Muallem HA, Ali SA (2015) Aspartic acid in a new role: Synthesis and application of a pH-responsive cyclopolymer containing residues of the amino acid. React Funct Polym 93:120–129.CrossRefGoogle Scholar
  18. 18.
    Zhao D, Huo Q, Feng J, Chmelka BF, Stucky GD (1998) Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J Am Chem Soc 120:6024–6036.CrossRefGoogle Scholar
  19. 19.
    Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF et al. (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 Angstrom pores Science (80) 279:548–552CrossRefGoogle Scholar
  20. 20.
    HP B (1966) Chemical identification of surface groups. In: Eley, DD, Pines Herman WPB (eds) Advances in catalysis. Academic Press Inc., New York, pp. 179–274.Google Scholar
  21. 21.
    Salis A, Parsons DF, Boström M, Medda L, Barse B, Ninham BW et al. (2010) Ion specific surface charge density of SBA-15 mesoporous silica Langmuir 26:2484–2490.CrossRefGoogle Scholar
  22. 22.
    Boehm HP (1994) Some aspects of the surface-chemistry of carbonblacks and other. Carbons Carbon N Y 32:759–69.CrossRefGoogle Scholar
  23. 23.
    Leonardelli S, Facchini L, Fretigny C, Tougne P, Legrand AP (1992) Silicon-29 NMR study of silica. J Am Chem Soc 114:6412–6418.CrossRefGoogle Scholar
  24. 24.
    Sindorf DW, Maciel GE (1981) Silicon-29 CP/MAS NMR studies of methylchlorosilane reactions on silica gel. J Am Chem Soc 103:4263–4265.CrossRefGoogle Scholar
  25. 25.
    Maciel GE, Sindorf DW (1980) Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning. J Am Chem Soc 102:7606–7607.CrossRefGoogle Scholar
  26. 26.
    Sindorf DW, Maciel GE (1983) Silicon-29 NMR study of dehydrated/rehydrated silica gel using cross polarization and magic-angle spinning. J Am Chem Soc 105:1487–1493.CrossRefGoogle Scholar
  27. 27.
    Legrand AP, Hommel H, Taïbi H, Miquel JL, Tougne P (1990) Contribution of solid state NMR spectroscopy to the characterization of materials. Colloids Surf 45:391–411.CrossRefGoogle Scholar
  28. 28.
    Grünberg A, Yeping X, Breitzke H, Buntkowsky G (2010) Solid-state NMR characterization of Wilkinson’s catalyst immobilized in mesoporous SBA-3 silica. Chemistry 16:6993–8.CrossRefGoogle Scholar
  29. 29.
    Groen JC, Peffer LA, Pérez-Ramı́rez J (2003) Pore size determination in modified micro- and mesoporous materials. Pitfalls and limitations in gas adsorption data analysis. Microporous Mesoporous Mater 60:1–17.CrossRefGoogle Scholar
  30. 30.
    Jaroniec C, Gilpin R, Jaroniec M (1997) Adsorption and thermogravimetric studies of silica-based amide bonded phases. J Phys 44242:6861–6866.Google Scholar
  31. 31.
    Iler RK (1979) The chemistry of silica: solubility, polymerization, colloid and surface properties and biochemistry. John Wiley, New York.Google Scholar
  32. 32.
    Erto A, Di Natale F, Musmarra D, Lancia A (2015) Modeling of single and competitive adsorption of cadmium and zinc onto activated carbon. Adsorption 21:611–621.CrossRefGoogle Scholar
  33. 33.
    Huang J, Yuan F, Zeng G, Li X, Gu Y, Shi L et al. (2017) Influence of pH on heavy metal speciation and removal from wastewater using micellar-enhanced ultrafiltration Chemosphere 173:199–206.CrossRefGoogle Scholar
  34. 34.
    Abbas M, Kaddour S, Trari M (2014) Kinetic and equilibrium studies of cobalt adsorption on apricot stone activated carbon. J Ind Eng Chem 20:745–751.CrossRefGoogle Scholar
  35. 35.
    Morris WJW, JC (1963) Intraparticle diffusion during the sorption of surfactants onto activated carbon. Eng Div Am Soc Civ Eng 89:31–60.Google Scholar
  36. 36.
    Kavitha D, Namasivayam C (2007) Experimental and kinetic studies on methylene blue adsorption by coir pith carbon. Bioresour Technol 98:14–21.CrossRefGoogle Scholar
  37. 37.
    Wu F-C, Tseng R-L, Juang R-S (2009) Initial behavior of intraparticle diffusion model used in the description of adsorption kinetics. Chem Eng J 153:1–8.CrossRefGoogle Scholar
  38. 38.
    Ho YS, Porter JF, Mckay G (2002) Divalent metal ions onto peat: copper, nickel and lead single component systems. Water Air Soil Pollut 141:1–33.CrossRefGoogle Scholar
  39. 39.
    Lima EC, Adebayo MA, Machado FM (2015) In: Bergmann CP, Machado FM (eds.) Carbon nanomaterials as adsorbents for environmental and biological applications, Springer International Publishing, Switzerland, pp. 33–69.Google Scholar
  40. 40.
    U.S. Department of Health and Human Services (2016) 14th RoC Review of Cobalt and Cobalt Compounds that Release Cobalt Ions In Vivo, National Toxicology Program, https://ntp.niehs.nih.gov/pubhealth/roc/listings/cobalt/. Accessed 17 Jan 2019.

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Safety Technology Program, Dammam Community CollegeKing Fahd University of Petroleum & MineralsDhahranSaudi Arabia
  2. 2.Chemistry DepartmentKing Fahd University of Petroleum & MineralsDhahranSaudi Arabia

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