Advertisement

A novel ex-situ charge interaction strategy for the fabrication of graphene oxide/organic functionalized silica nanoparticles composites and application in Cd (II) adsorption

  • Pengpeng Wang
  • Jie Li
  • Lianxi ChenEmail author
  • Jinjin Fang
Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)
First Online:
  • 23 Downloads

Abstract

In this study, a new-style “ex-situ charge interaction” strategy has been developed to prepare graphene oxide/organic functionalized silica nanoparticles (GO/OSNs) composites. The crucial point of the strategy is that the OSNs have positive charge by adding Hydrochloric acid (HCl). Four types of OSNs were prepared via one-pot sol–gel reaction of four different kinds of organosilane. Then the positively charge OSNs and negatively charge GO could effectively composite via charge interaction. The GO/OSNs were characterized by Scanning electron microscope (SEM), Transmission electronic microscope (TEM), Fourier transform infrared (FT-IR), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results showed that “ex-situ charge interaction” strategy might be a general method for the fabrication of GO/OSNs. This research provides a new approach for the fabrication of GO/OSNs composites with other OSNs structures. In addition, the application of GO/OSNs in the adsorption of Cd(II) has also been investigated, which included adsorption properties of four GO/OSNs, parameters of adsorption isotherm and adsorption kinetics.

Open image in new window

GO/OSNs composites were fabricated based on a new-style “ex-situ charge interaction” strategy. OSNs were first prepared via one-pot sol–gel reaction. Furthermore, they were given positive charge by adding HCl. Finally, GO/OSNs were fabricated by charge interaction of between GO and OSNs.

Highlights

  • OSNs treated with acid is first used to fabricate GO/OSNs composites.

  • Various organic functional groups are introduced into the composites.

  • The strategy can be used for fabrication of composites with other morphology of OSNs.

  • Toxic reagents, high-temperature and time-consuming process are not utilized.

Keywords

Ex-situ charge interaction Graphene oxide Organic silica Composites Adsorption 
This is a preview of subscription content, log in to check access.

Notes

Acknowledgements

This work is financially supported by the Fundamental Research Funds for the Central Universities (WUT:2017IB002), the Fundamental Research Funds for the Central Universities (WUT:2018IB022) and the Nature Science Foundation of Hubei Province (No.2017CFB296). We would also like to thank Shanbin Mu for their SEM analysis and Tingting Luo for their TEM analysis in the Materials Research and Test Center of WUT.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

References

  1. 1.
    Wang W, Ma R, Wu Q, Wang C, Wang Z (2013) Magnetic microsphere-confined graphene for the extraction of polycyclic aromatic hydrocarbons from environmental water samples coupled with high performance liquid chromatography-fluorescence analysis. J Chromatogr A 1293:20–27CrossRefGoogle Scholar
  2. 2.
    Jalilian N, Ebrahimzadeh H, Asgharinezhad AA, Molaei K (2017) Extraction and determination of trace amounts of gold(III), palladium(II), platinum(II) and silver(I) with the aid of a magnetic nanosorbent made from Fe3O4-decorated and silica-coated graphene oxide modified with a polypyrrole-polythiophene copolymer. Microchim Acta 184:2191–2200CrossRefGoogle Scholar
  3. 3.
    Hermanov S, ZareCk M, Bou D, Pumera AM, Sofer Z (2015) Graphene oxide immobilized enzymes show high thermal and solvent stability. Nanoscale 7:5852–5858CrossRefGoogle Scholar
  4. 4.
    Jiang T, Kuila T, Kim NH, Ku BC, Lee JH (2013) Enhanced mechanical properties of silanized silica nanoparticle attached graphene oxide/epoxy composites. Compos Sci Technol 79:115–125CrossRefGoogle Scholar
  5. 5.
    Jiao FL, Gao FY, Wang HP, Deng YL, Zhang YJ, Qian XH, Zhang YK (2017) Ultrathin Au nanowires assisted magnetic graphene-silica ZIC-HILIC composites for highly specific enrichment of N-linked glycopeptides. Anal Chim Acta 970:47–56CrossRefGoogle Scholar
  6. 6.
    Han L, Ruan JF, Li YS, Terasaki AO, Che SN (2007) Synthesis and characterization of the amphoteric amino acid bifunctional mesoporous silica. Chem Mater 19:2860–2867CrossRefGoogle Scholar
  7. 7.
    Teng MM, Wang HT, Li FT, Zhang BR (2011) Thioether-functionalized mesoporous fiber membranes: sol-gel combined electrospun fabrication and their applications for Hg2+ removal. J Colloid Interface Sci 355:23–28CrossRefGoogle Scholar
  8. 8.
    Xu WJ, Gao Q, Xu Y, Wu D, Sun YH, Shen WL, Deng F (2008) Controlled drug release from bifunctionalized mesoporous silica. J Solid State Chem 181:2837–2844CrossRefGoogle Scholar
  9. 9.
    Yang Y, Liu J, Li XB, Liu X, Yang QH (2011) Organosilane-assisted transformation from core–shell to yolk–shell nanocomposites. Chem Mater 23:3676–3684CrossRefGoogle Scholar
  10. 10.
    Zhu YF, Fang Y, Borchardt L, Kaskel S (2011) PEGylated hollow mesoporous silica nanoparticles as potential drug delivery vehicles. Micro Mesopor Mat 141:199–206CrossRefGoogle Scholar
  11. 11.
    Sasidharan M, Nakashima K, Gunawardhana N, Yokoi T, Ito M, Inoue M, Yusa S, Yoshio M, Tatsumi T (2011) Periodic organosilica hollow nanospheres as anode materials for lithium ion rechargeable batteries. Nanoscale 3:4768–4773CrossRefGoogle Scholar
  12. 12.
    Li YS, Shi JL, Hua Z, Chen HR, Ruan ML, Yan DS (2003) Hollow Spheres of Mesoporous Aluminosilicate with a Three-Dimensional Pore Network and Extraordinarily High Hydrothermal Stability. Nano Lett 3:609–612CrossRefGoogle Scholar
  13. 13.
    Cao SS, Zhao ZY, Jin X, Sheng WC, Li SJ, Ge Y, Dong MD, Wu WW, Fang L (2011) Unique double-shelled hollow silica microspheres: template-guided self-assembly, tunable pore size, high thermal stability, and their application in removal of neutral red. J Mater Chem 21:19124–19131CrossRefGoogle Scholar
  14. 14.
    Chen Z, Cui ZM, Niu F, Jiang L, Song WG (2010) Pd nanoparticles in silica hollow spheres with mesoporous walls: a nanoreactor with extremely high activity. Chem Commun 46:6524–6526CrossRefGoogle Scholar
  15. 15.
    Yang XL, Zhao N, Zhou QZ, Wang Z, Duan C, Cai CT, Zhang X, Xu JL (2012) Facile preparation of hollow amino-functionalized organosilica microspheres by a template-free method. J Mater Chem 22:18010–18017CrossRefGoogle Scholar
  16. 16.
    Yang SB, Feng XL, Wang L, Tang K, Maier J, Mullen K (2010) Graphene-based nanosheets with a sandwich structure. Angew Chem Int Ed 49:4795–4799CrossRefGoogle Scholar
  17. 17.
    Zhang WL, Choi HJ (2012) Silica-graphene oxide hybrid composite particles and their electroresponsive characteristics. Langmuir 28:7055–7062CrossRefGoogle Scholar
  18. 18.
    Maio A, Giallombardo D, Scaffaro R, Palumbo Piccionello A, Pibiri I (2016) Synthesis of a fluorinated graphene oxide–silica nanohybrid: improving oxygen affinity. RSC Adv 6:46037–46047CrossRefGoogle Scholar
  19. 19.
    Liu JW, Zhang Q, Chen XW, Wang JH (2011) Surface assembly of graphene oxide nanosheets on SiO2 particles for the selective isolation of hemoglobin. Chem Eur J 17:4864–4870CrossRefGoogle Scholar
  20. 20.
    Li XZ, Li X, Zhou J, Dong YL, Xie ZZ, Cai WQ, Zhang CC (2017) Facile synthesis of hierarchical porous carbon derived from carboxyl graphene oxide/phenolic foam for high performance supercapacitors. RSC Adv 7:43965–43977CrossRefGoogle Scholar
  21. 21.
    Liu ZH, Chen LX, Ye XS, Yu HG, Li J, Zeng FL (2016) Selective basic etching of bifunctional core–shell composite particles for the fabrication of organic functionalized hollow mesoporous silica nanospheres. NJC 40:825–831CrossRefGoogle Scholar
  22. 22.
    Lee CY, Bae J, Kim TY, Chang SH, Kim SY (2015) Using silane-functionalized graphene oxides for enhancing the interfacial bonding strength of carbon/epoxy composites. Compos Part A: Appl Sci 75:11–17CrossRefGoogle Scholar
  23. 23.
    Music S, Filipovi Vincekovi N, Sekovani L (2011) Precipitation of amorphous SiO2 particles and their properties. Braz J Chem Eng 28:89–94CrossRefGoogle Scholar
  24. 24.
    Yu Y, Addai-Mensah J, Losic D (2012) Functionalized diatom silica microparticles for removal of mercury ions. Sci Technol Adv Mater 13:015008–015018CrossRefGoogle Scholar
  25. 25.
    Smith AL (1960) Infrared spectra-structure correlations for organosilicon compounds. Spectrochim Acta 16:87–105CrossRefGoogle Scholar
  26. 26.
    Lesaint C, Lebeau B, Marichal C, Patarin J (2005) Synthesis of mesoporous silica materials functionalized with n-propyl groups. Microporous & mesoporous. Materials 83:76–84Google Scholar
  27. 27.
    Hayashi K, Nakamura M, Ishimura K (2011) In situ synthesis and photoresponsive rupture of organosilica nanocapsules. Chem Commun 47:1518–1520CrossRefGoogle Scholar
  28. 28.
    Teng ZG, Wang SJ, Su XD, Chen GT, Liu Y, Luo ZM, Luo W, Tang YX, Ju HX, Zhao DY, Lu GM (2014) Facile synthesis of yolk-shell structured inorganic-organic hybrid spheres with ordered radial mesochannels. Adv Mater 26:3741–3747CrossRefGoogle Scholar
  29. 29.
    Shao L, Quan S, Liu Y, Guo ZH, Wang ZX (2013) A novel “gel–sol” strategy to synthesize TiO2 nanorod combining reduced graphene oxide composites. Mater Lett 107:307–310CrossRefGoogle Scholar
  30. 30.
    Kou L, Gao C (2011) Making silica nanoparticle-covered graphene oxide nanohybrids as general building blocks for large-area superhydrophilic coatings. Nanoscale 3:519–528CrossRefGoogle Scholar
  31. 31.
    Layek RK, Das AK, Park MU, Kim NH, Lee JH (2014) Layer-structured graphene oxide/polyvinyl alcohol nanocomposites: dramatic enhancement of hydrogen gas barrier properties. J Mater Chem A 2:12158–12161CrossRefGoogle Scholar
  32. 32.
    Yan J, Wei T, Shao B, Ma FQ, Fan ZJ, Zhang ML, Zheng C, Shang YC, Qian WZ, Wei F (2010) Electrochemical properties of graphene nanosheet/carbon black composites as electrodes for supercapacitors. Carbon 48:1731–1737CrossRefGoogle Scholar
  33. 33.
    Saikia BK, Boruah RK, Gogoi PK (2009) A X-ray diffraction analysis on graphene layers of Assam coal. J Chem Sci 121:103–106CrossRefGoogle Scholar
  34. 34.
    Xu XL, Wang XF, Li JL, Yang JH, Wang Y, Zhou ZW (2017) Preparation of hybrid graphene oxide/nano-silica nanofillers and their application in poly(vinyl alcohol) composites. Polym Compos 38:E89–E97CrossRefGoogle Scholar
  35. 35.
    Xu C, Wu X, Zhu J, Wang X (2008) Synthesis of amphiphilic graphite oxide. Carbon 46:386–389CrossRefGoogle Scholar
  36. 36.
    Wang LZ, Tomura S, Ohashi F, Maeda M, Suzuki M, Inukai K (2001) Synthesis of single silica nanotubes in the presence of citric acid. J Mater Chem 11:1465–1468CrossRefGoogle Scholar
  37. 37.
    Haeri Z, Ramezanzadeh B, Asghari M (2017) A novel fabrication of a high performance SiO2-graphene oxide (GO) nanohybrids: Characterization of thermal properties of epoxy nanocomposites filled with SiO2-GO nanohybrids. J Colloid Interface Sci 493:111–122CrossRefGoogle Scholar
  38. 38.
    Jiang TW, Kuila T, Kim NH, Lee JH (2014) Effects of surface-modified silica nanoparticles attached graphene oxide using isocyanate-terminated flexible polymer chains on the mechanical properties of epoxy composites. J Mater Chem A 2:10557–10567CrossRefGoogle Scholar
  39. 39.
    Deng L, Chen C, Zhu C, Dong S, Lu H (2014) Multiplexed bioactive paper based on GO@SiO2@CeO2 nanosheets for a low-cost diagnostics platform. Biosens & Bioelectron 52:324–329CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Pengpeng Wang
    • 1
  • Jie Li
    • 2
  • Lianxi Chen
    • 1
    Email author
  • Jinjin Fang
    • 1
  1. 1.School of Chemistry, Chemical Engineer and Life ScienceWuhan University of TechnologyWuhanP. R. China
  2. 2.School of Food EngineeringWuchang Institute of TechnologyWuhanP. R. China

Personalised recommendations

Cite article

Buy options