CuO photoelectrodes synthesized by the sol–gel method for water splitting
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CuO is an attractive photocatalytic material for water splitting due to its high earth abundance and low cost. In this paper, we report the deposition of CuO thin films by sol–gel dip-coating process. Sol deposition has attractive advantages including low-cost solution processing and uniform film formation over large areas with a fairly good control of the film stoichiometry and thickness. Pure CuO phase was obtained for calcination temperatures higher than 360 °C in air. The CuO photocurrents for hydrogen evolution depend on the crystallinity and the microstructure of the film. Values of −0.94 mA cm−2 at pH = 8 and 0 V vs. RHE were achieved for CuO photoelectrodes annealed at 400 °C under air. More interestingly, the stability of the photoelectrode was enhanced upon the sol–gel deposition of a TiO2 protective layer. In this all sol–gel CuO/TiO2 photocathode, a photocurrent of −0.5 mA cm−2 is achieved at pH = 7 and 0 V vs. RHE with a stability of ~100% over 600 s.
Sol–gel-based CuO photoelectrode has values of −0.94 mA cm−2 at pH = 8 and 0 V vs. RHE.
CuO/TiO2 photoelectrodes have been synthesized by the sol–gel chemistry coupled with dip-coating.
These photoelectrodes exhibit −0.5 mA cm−2 at pH = 7 and 0 V vs. RHE.
These photoelectrodes are 100% stable over 600 s.
KeywordsCuO photoelectrode Sol–gel TiO2 protecting layer for CuO photoelectrode Water splitting
This work was supported by the ANRT, the Agence Nationale de la Recherche through the LabEx ARCANE programme (ANR-11-LABX-0003-01), and Total-Energie Nouvelle.
Compliance with ethical standards
Conflict of interest
The authors declare that they have no conflict of interest.
- 1.Dudley B (2014) BP Energy Outlook 2035. BP’s Energy Outlook 94:1-7.Google Scholar
- 28.Morales-Guio CG, Tilley SD, Vrubel H, Gratzel M, Hu XL (2014) Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst. Nat Commun 5:1-96.Google Scholar
- 34.Koshy J, Goerge KC (2015) Annealing effects on crystallite size and band gap of CuO nanoparticles. Int J Nanosci Nanotechnol 6(1):1–8Google Scholar
- 37.Kidowaki HO, Akiyama T, Suzuki A, Jeyadevan B, Cuya J (2012) Fabrication and Characterization of CuO-based solar cells. J Mater Sci Res 1(1):138–143Google Scholar
- 38.Johan MR, Suan MSM, Hawari NL, Ching HA (2011) Annealing effects on the properties of copper oxide thin films prepared by chemical deposition. Int J Electrochem Sci 6:6094–6104Google Scholar
- 39.Choudhary S, Solanki A, Upadhyay S, Singh N, Satsangi VR, Shrivastav R, Dass S (2013) Nanostructured CuO/SrTiO3bilayered thin films for photoelectrochemical water splitting. J Solid State Electrochem 17(9):2531–2538Google Scholar
- 46.Toupin J, Strub HP, Kressmann S, Boudot M, Artero V, Laberty C (2017) Engineering n-p junction for photo-electrochemical hydrogen production. Phys Chem Chem Phys.Google Scholar