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Journal of Radioanalytical and Nuclear Chemistry

, Volume 322, Issue 2, pp 827–838 | Cite as

Removal of Co(II) from aqueous solution with functionalized metal–organic frameworks (MOFs) composite

  • Guoyuan Yuan
  • Yin TianEmail author
  • Min Li
  • Yang Zeng
  • Hong Tu
  • Jiali Liao
  • Jijun Yang
  • Yuanyou Yang
  • Ning LiuEmail author
Article
  • 43 Downloads

Abstract

In this study, four functionalized metal–organic frameworks (MOFs) composite (UiO-66-COOCH3, UiO-66-CONH2, UiO-66-CN and UiO-66-SO3H) were successfully prepared by post-synthesis modification for the removal of Co(II) from simulated 60Co radioactive wastewater. Benefiting from the strong uptake ability of these functional MOFs, the as-synthesized MOFs adsorbents exhibit an extraordinary adsorption performance towards Co(II), and their saturated adsorption capacity reached 334.4 mg g−1 (UiO-66-COOCH3), 339.7 mg g−1 (UiO-66-CONH2), 274.6 mg g−1 (UiO-66-CN) and 293.7 mg g−1 (UiO-66-SO3H), respectively. In addition, density functional theory (DFT) was used to study the adsorption mechanism of Co(II) by MOFs. The results of theoretical calculation revealed that the functional groups of MOFs have strong chelating ability to Co(II), which gradually increase with the order of nitrile group, sulfonic acid group, ester group and amide group, and the order is also consistent with the adsorption amount of Co(II) in the experiment. All these works suggest that the synthesized MOFs are potential candidate for 60Co seperation.

Keywords

Removal Co(II) MOFs Experimental DFT 

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 21876122).

Supplementary material

10967_2019_6764_MOESM1_ESM.docx (260 kb)
Supplementary material 1 (DOCX 259 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.Key Laboratory of Radiation Physics and Technology (Sichuan University), Ministry of Education, Institute of Nuclear Science and TechnologySichuan UniversityChengduPeople’s Republic of China
  2. 2.College of Chemistry and Chemical EngineeringChongqing University of Science and TechnologyChongqingPeople’s Republic of China
  3. 3.School of PharmacyChengdu University of Traditional Chinese MedicineChengduPeople’s Republic of China

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