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Removal of strontium from aqueous solutions by acrylamide-modified attapulgite

  • Rui Zuo
  • Li MengEmail author
  • Xin Guan
  • Jinsheng Wang
  • Jie Yang
  • Yuanhui Lin
Article
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Abstract

Removal of Sr(II) with acrylamide modified attapulgite (AMATP) from aqueous solutions was investigated. The AMATP was characterized by XRD, SEM and FTIR and the pH with Sr(II) initial concentration were controlling factors for Sr(II) sorption process. The inhibitory effects of coexisting ions have the order as Ca2+ > Mg2+ > Na+. The sorption process of Sr(II) on AMATP was spontaneous and endothermic and followed the pseudo second-order sorption model and fit well with the Langmuir isotherm. Owing to its high sorption capacity and low cost, AMATP can be a promising candidate for Sr(II) sorption removal.

Keywords

Acrylamide modified attapulgite Sr(II) sorption pH Ionic strength Sorption thermodynamic 

Notes

Acknowledgement

This work was supported by the National Natural Science Foundation of China (No. 41672228) and the Major Science and Technology Program for Water Pollution Control and Treatment (2014ZX07201-010).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

References

  1. 1.
    Ahmadpour A, Zabihi M, Tahmasbi M, Rohani Bastami T (2010) Effect of sorbents and chemical treatments on the removal of strontium from aqueous solutions. J Hazard Mater 182:552–556CrossRefGoogle Scholar
  2. 2.
    Wang H, Wang XJ, Ma JX, Xia P, Zhao JF (2017) Removal of cadmium(II) from aqueous solution: a comparative study of raw attapulgite clay and a reusable waste-struvite/attapulgite obtained from nutrient-rich wastewater. J Hazard Mater 329:66–76CrossRefGoogle Scholar
  3. 3.
    Chegrouche S, Mellah A, Barkat M (2009) Removal of strontium from aqueous solutions by adsorption onto activated carbon: kinetic and thermodynamic studies. Desalination 235:306–318CrossRefGoogle Scholar
  4. 4.
    Rahman ROA, Ibrahim HA, Hanafy M, Monem NMA (2010) Assessment of synthetic zeolite Na A-X as sorbing barrier for strontium in a radioactive disposal facility. Chem Eng J 157:100–112CrossRefGoogle Scholar
  5. 5.
    Kaçan E, Kütahyalı C (2012) Adsorption of strontium from aqueous solution using activated carbon produced from textile sewage sludges. J Anal Appl Pyrolysis 97:149–157CrossRefGoogle Scholar
  6. 6.
    Shirvani M, Kalbasi M, Shariatmadari H, Nourbakhsh F, Najafi B (2006) Sorption–desorption of cadmium in aqueous palygorskite, sepiolite, and calcite suspensions: isotherm hysteresis. Chemosphere 65:2178–2184CrossRefGoogle Scholar
  7. 7.
    Zhao Y, Shao ZY, Chen CL, Hu J, Chen HL (2014) Effect of environmental conditions on the adsorption behavior of Sr(II) by Na-rectorite. Appl Clay Sci 87:1–6CrossRefGoogle Scholar
  8. 8.
    Berhane T, Levy J, Krekeler MPS, Danielson ND (2017) Kinetic sorption of contaminants of emerging concern by a palygorskite-montmorillonite filter medium. Chemosphere 176:231–242CrossRefGoogle Scholar
  9. 9.
    El-Kamash AM (2008) Evaluation of zeolite A for the sorptive removal of Cs+ and Sr2+ ions from aqueous solutions using batch and fixed bed column operations. J Hazard Mater 151:432–445CrossRefGoogle Scholar
  10. 10.
    Dyer A, Chimedtsogzol A, Campbell L, Williams C (2006) Uptake of cesium and strontium radioisotopes by natural zeolites from mongolia. Microporous Mesoporous Mater 95:172–175CrossRefGoogle Scholar
  11. 11.
    Li Q, Liu HN, Liu TY, Guo M, Qing BJ, Ye XS, Wu ZJ (2010) Strontium and calcium ion adsorption by molecularly imprinted hybrid gel. J Hazard Mater 157:401–407Google Scholar
  12. 12.
    Nilchi A, Hadjmohammadi MR, Rasouli GS, Saberi R (2009) Studies on the adsorption behavior of trace amounts of 90Sr2+, 140La3+, 60Co2+, Ni2+ and Zr4+ cations on synthesized inorganic ion exchangers. J Hazard Mater 167:531–535CrossRefGoogle Scholar
  13. 13.
    Guan W, Pan JM, Ou HX, Wang X, Zou XH, Hu W, Li CX (2011) Removal of strontium(II) ions by potassium tetratitanate whisker and sodium trititanate whisker from aqueous solution: equilibrium, kinetics and thermodynamics. Chem Eng J 167:215–222CrossRefGoogle Scholar
  14. 14.
    Zhang L, Wei JY, Zhao X, Li FZ, Jiang F (2015) Adsorption characteristics of strontium on synthesized antimony silicate. Chem Eng J 277:378–387CrossRefGoogle Scholar
  15. 15.
    Ackermann M, Ajello M, Allafort A, Schady P, Baldini L, Ballet J (2012) The sorption behaviour of synthetic sodium nonatitanate and zeolite a for removing radioactive strontium from aqueous wastes. Sep Purif Technol 96:81–88CrossRefGoogle Scholar
  16. 16.
    Smičiklas I, Dimović S, Plećaš I (2007) Removal of Cs1+, Sr2+, and Co2+, from aqueous solutions by adsorption on natural clinoptilolite. Appl Clay Sci 35:139–144CrossRefGoogle Scholar
  17. 17.
    Chang Y, Liu H, Zha F, Chen H, Ren X, Lei Z (2011) Adsorption of Pb(II) by n-methylimidazole modified palygorskite. Chem Eng J 167:183–189CrossRefGoogle Scholar
  18. 18.
    Galamboš M, Kufčáková J, Rajec P (2009) Sorption of strontium on Slovak bentonites. J Radioanal Nucl Chem 281:347–357CrossRefGoogle Scholar
  19. 19.
    Sheikhhosseini A, Shirvani M, Shariatmadari H (2013) Competitive sorption of nickel, cadmium, zinc and copper on palygorskite and sepiolite silicate clay minerals. Geoderma 192:249–253CrossRefGoogle Scholar
  20. 20.
    Deng YH, Wu F, Liu BZ, Hu XB, Sun C (2011) Sorptive removal of β-blocker propranolol from aqueous solution by modified attapulgite: effect factors and sorption mechanisms. Chem Eng J 174:571–578CrossRefGoogle Scholar
  21. 21.
    Zou XH, Pan JM, Ou HX, Wang X, Guan W, Li CX, Yan YS (2011) Adsorptive removal of Cr(III) and Fe(III) from aqueous solution by chitosan/attapulgite composites: equilibrium, thermodynamics and kinetics. Chem Eng J 167:112–121CrossRefGoogle Scholar
  22. 22.
    Deng YH, Gao ZQ, Liu BZ, Wei ZB, Sun C (2013) Selective removal of lead from aqueous solutions by ethylenediamine-modified attapulgite. Chem Eng J 223:91–98CrossRefGoogle Scholar
  23. 23.
    Fan QH, Shao DD, Lu Y, Wu WS, Wang XK (2009) Effect of pH, ionic strength, temperature and humic substances on the sorption of Ni(II) to Na–attapulgite. Chem Eng J 150:188–195CrossRefGoogle Scholar
  24. 24.
    Cui H, Qian Y, Li Q, Wei ZB, Zhai JP (2013) Fast removal of Hg(II) ions from aqueous solution by amine-modified attapulgite. Appl Clay Sci 72:84–90CrossRefGoogle Scholar
  25. 25.
    Cao JS, Wang C, Fang F, Lin JX (2016) Removal of heavy metal Cu(II) in simulated aquaculture wastewater by modified palygorskite. Environ Pollut 219:924–931CrossRefGoogle Scholar
  26. 26.
    Tan LQ, Wang X, Tan X et al (2017) Bonding properties of humic acid with attapulgite and its influence on U(VI) sorption. Chem Geol 464:91–100CrossRefGoogle Scholar
  27. 27.
    Metwally SS, Ahmed IM, Rizk HE (2017) Modification of hydroxyapatite for removal of cesium and strontium ions from aqueous solution. J Alloys Compd 709:438–444CrossRefGoogle Scholar
  28. 28.
    Zhang L, Wei JY, Zhao X, Li FZ, Jiang F, Zhang M, Chen XZ (2016) Removal of strontium(II) and cobalt(II) from acidic solution by manganese antimonite. Chem Eng J 302:733–743CrossRefGoogle Scholar
  29. 29.
    Lei C, Tian X, Ma B (2013) Effect of ph, ionic strength, foreign ions and temperatures on the sorption of Eu(III) on attapulgite-iron oxide magnetic composites. J Radioanal Nucl Chem 298(2):1127–1135CrossRefGoogle Scholar
  30. 30.
    Wang YQ, Feng Y, Zhang XF, Zhang X, Jiang J, Yao J (2018) Alginate-based attapulgite foams as efficient and recyclable adsorbents for the removal of heavy metals. J Colloid Interface Sci 514:190–198CrossRefGoogle Scholar
  31. 31.
    Ekholm P, Kallio K, Turtola E, Rekolainen S, Puustinen M (2009) Adsorption of Cu2+ and Pb2+ ion on dolomite powder. J Hazard Mater 167:271–283Google Scholar
  32. 32.
    Hmh G, Youssef MA (2017) Sorption behavior of Eu(III) from an aqueous solution onto modified hydroxyapatite: kinetics, modeling and thermodynamics. Environ Technol 39:2583–2596Google Scholar
  33. 33.
    Abdel-Karim AAM, Zaki AA, Elwan W, El-Naggar MR, Gouda MM (2016) Experimental and modeling investigations of cesium and strontium adsorption onto clay of radioactive waste disposal. Appl Clay Sci 132–133:391–401CrossRefGoogle Scholar
  34. 34.
    Liu D, Zheng H (2017) Enhanced adsorption of radioactive strontium ions from aqueous solution by H2O2 -modified attapulgite. J Radioanal Nucl Chem 311(3):1883–1890CrossRefGoogle Scholar
  35. 35.
    Klika Z, Seidlerová J, Valášková M, Kliková C, Kolomazník I (2016) Uptake of Ce(III) and Ce(IV) on montmorillonite. Appl Clay Sci 132–134:41–49CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.College of Water SciencesBeijing Normal UniversityBeijingChina
  2. 2.Engineering Research Center of Groundwater Pollution Control and RemediationMinistry of EducationBeijingChina

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