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Adsorptive removal of lead-210 using hydroxyapatite nanopowders prepared from phosphogypsum waste

  • Nazife AslanEmail author
  • Gülten Özçayan
Article

Abstract

Recently, several organic and inorganic adsorbents are used for the separation and purification processes of metal ions and removal of radionuclides from radioactive and industrial wastes. In this study, calcium hydroxyapatite was prepared by phosphogypsum waste and its adsorption behavior towards lead-210 was evaluated. Results showed that the adsorption percentage of hydroxyapatite was found to be 95% on the optimum conditions. Additionally, the adsorption kinetic data were analyzed using pseudo-first order and pseudo-second order kinetic models. The results indicated that hydroxyapatite is an efficient adsorbent for the removal of lead-210 from aqueous media with good performance.

Keywords

Lead-210 removal Waste water Hydroxyapatite Phosphogypsum 

Notes

References

  1. 1.
    World Health Organisation (WHO) (2011) Library Cataloguing-in-publication data. Guidelines for drinking-water quality—4th edGoogle Scholar
  2. 2.
    Jia G, Belle M, Blasi M, Marchetti A, Rosamilia S, Sansone U (2000) 210Pb and 210Po determination in environmental samples. Appl Radiat Isot 53:115–120CrossRefGoogle Scholar
  3. 3.
    UNSCEAR, Report to the Generally Assembly (1998) United Nations Scientific Committee on the Effect of Atomic Radiation. Sources, effects, and risk of ionising radiation, New York, United NationsGoogle Scholar
  4. 4.
    Awual MR, Suzuki S, Taguchi T, Shiwaku H, Okamato Y, Yaita T (2017) Radioactive cesium removal from nuclear waste water by novel inorganic and conjugate adsorbents. Chem Eng J 242:127–135CrossRefGoogle Scholar
  5. 5.
    Awual MR, Yaita T, Taguchi T, Suzuki S, Shiwaku H, Suzuki S, Okamoto Y (2014) Selective cesium removal from radioactive liquid waste water by crown ether immobilized new class conjugate adsorbent. J Hazard Mater 278:227–235CrossRefGoogle Scholar
  6. 6.
    Noli F, Kapnisti M, Buema G, Harja M (2016) Retention of barium and europium radionuclides from aqueous solutions on ash-based sorbents by application of radiochemical techniques. Appl Radiat Isot 116:102–109CrossRefGoogle Scholar
  7. 7.
    Jing C, Li YL, Landsberger S (2016) Review of soluble uranium removal by nanoscale zero valent iron. J Environ Radioact 164:65–72CrossRefGoogle Scholar
  8. 8.
    Xu C, Wang J, Chen J (2012) Solvent extraction of strontium and cesium: a review of recent progress. Solvent Extr Ion Exch 30(6):623–650CrossRefGoogle Scholar
  9. 9.
    Nemr EA (2008) Potential of pomegranate husk carbon for Cr(VI) removal from wastewater: kinetic and isotherm studies. J Hazard Mater 161:132–141CrossRefGoogle Scholar
  10. 10.
    Pangeni B, Paudyal H, Inoue K, Ohto K, Kawakita H, Alam S (2014) Preparation of natural cation exchanger from persimmon waste and its application for the removal of cesium from water. Chem Eng J 242:109–116CrossRefGoogle Scholar
  11. 11.
    Moattar F, Hayeripour S (2004) Application of Chitin and Zeolite adsorbents for treatment of low level radioactive liquid wastes. Int J Environ Sci Technol 1(1):45–50CrossRefGoogle Scholar
  12. 12.
    Enamorado-Horrutiner Y, Villanueva-Tagle ME, Behar M, Rodriguez-Fuentes G, Ferraz Dias J, Pomares-Alfonso MS (2016) Cuban zeolite for lead sorption: application for water decontamination and metal quantification in water using nondestructive techniques. Int J Environ Sci Technol 13:1245–1256CrossRefGoogle Scholar
  13. 13.
    Mousa S, Hanna A (2013) Synthesis of nano-crystalline hydroxyapatite and ammonium sulfate from phosphogypsum waste. Mater Res Bull 48:823–828CrossRefGoogle Scholar
  14. 14.
    Hazardous Waste Management Series: HAZWAMS/(2012–2013) Guidelines for management and handling of phosphogypsum generated from phosphoric acid plants. Central Pollution Control Board (Ministry of Environment & Forests) East Arjun Nagar DELHI -110 032Google Scholar
  15. 15.
    Degirmenci N et al (2007) Application of phosphogypsum in soil stabilization. Build Environ 42(9):3393–3398CrossRefGoogle Scholar
  16. 16.
    FolekBarbara S, Bożena W, Miśkiewiczi W (2011) Use of phosphogypsum in road construction. Pol J Chem Technol 13(2):18–22Google Scholar
  17. 17.
    Altun İA, Sert Y (2004) Utilization of weathered phosphogypsum as set retarder in Portland cement. Cem Concr Res 34:677–680CrossRefGoogle Scholar
  18. 18.
    Singh M, Garg M (2002) Production of beneficiated phosphogypsum for cement manufacture. J Sci Ind Res 61:533–537Google Scholar
  19. 19.
    Singh M, Verma CL, Garg M (2003) Processing of phosphogypsum for value added building materials. Recycling and reuse of waste materials. In: Proceedings of the international symposium, Dundee, UK, 165–172Google Scholar
  20. 20.
    Kumar S (2002) A perspective study on fly ash–lime–gypsum bricks and hollow blocks for low cost housing development. Constr Build Mater 16:519–525CrossRefGoogle Scholar
  21. 21.
    Kumar S (2003) Fly ash–lime–phosphogypsum hollow blocks for walls and partitions. Build Environ 38:291–295CrossRefGoogle Scholar
  22. 22.
    Yang J, Liu W, Zhang L, Xiao B (2009) Preparation of load-bearing building materials from autoclaved phosphogypsum. Constr Build Mater 23:687–693CrossRefGoogle Scholar
  23. 23.
    Satone SR, Akhare RP (2014) An experimental investigation of use of phosphogypsum and marble powder for making green concrete. Int J Eng Res Appl 4(7):32–36Google Scholar
  24. 24.
    Yassine E, Mohammed B (2018) Procedure to convert phosphogypsum waste into valuable products. J Mater Manuf Process 33(16):1727–1733CrossRefGoogle Scholar
  25. 25.
    Chen X, Wright JV, Conca JL, Peurrung LM (1992) Effects of pH on heavy metal sorption on mineral apatite. Environ Sci Technol 31(3):624–631CrossRefGoogle Scholar
  26. 26.
    da Rocha NCC, de Campos RC, Rossi AM, Moreira EL, Barbosa ADF, Moure GT (2002) Cadmium uptake by hydroxyapatite synthesized in different conditions and submitted to thermal treatment. Environ Sci Technol 36:1630–1635CrossRefGoogle Scholar
  27. 27.
    Malonda AG, Garcia-Toraño E, Los Arcos JM (1985) Liquid-scintillation counting efficiency as a function of the figure of merit for pure beta-particle emitters. Int J Appl Radiat Isot 36:157–158CrossRefGoogle Scholar
  28. 28.
    Malonda AG, Garcia-Toraño E (1982) Evaluation of counting efficiency in liquid scintillation counting of pure beta ray emitters. Int J Appl Radiat Isot 33:249–253CrossRefGoogle Scholar
  29. 29.
    Hamidpour M, Kalbasi M, Afyuni M, Shariatmadari H, Furrer G (2011) Sorption of lead on Iranian bentonite and zeolite: kinetics and isotherms. Environ Earth Sci 62:559–568CrossRefGoogle Scholar
  30. 30.
    Mousa SM, Ammar NS, Ibrahim HA (2014) Removal of lead ions using hydroxyapatite nano-material prepared from phosphogypsum waste. J Saudi Chem Soc 20:357–365CrossRefGoogle Scholar
  31. 31.
    Karatas M (2012) Removal of Pb(II) from water by natural zeolitic tuff: kinetics and thermodynamics. J Hazard Mater 199–200:383–389CrossRefGoogle Scholar
  32. 32.
    Suzuki T, Ishigaki K, Miyake M (1984) Synthetic hydroxyapatites as inorganic cation exchangers: Part 3. Exchange characteristics of lead ions (Pb2+). J Chem Soc, Faraday Trans 44:159–166Google Scholar
  33. 33.
    Baillez S, Nzihou A, Benache-Assolant D, Champion E, Sharrock P (2007) Removal of aqueous lead ions by hydroxyapatites: equilibria and kinetic processes. J Hazard Mater A139:443–446Google Scholar
  34. 34.
    Suzuki Y, Takeuchi Y (1994) Uptake of a few divalent heavy metal ionic species by a fixed bed of hydroxyapatite particles. J Chem Eng Jpn 27:571–576CrossRefGoogle Scholar
  35. 35.
    Karaçetin G, Sivrikaya S, İmamoğlu M (2014) Adsorptions of methylene blue from aqueous solutions by activated carbon prepared from hazelnut husk using zinc chloride. J Anal Appl Pyrolysis 110:270–276CrossRefGoogle Scholar
  36. 36.
    Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Processes Biochem 34:451–456CrossRefGoogle Scholar
  37. 37.
    Lin YE, Chen HW, Chien PS, Chiou CS, Liu C (2011) Application of bifunctional magnetic adsorbent to adsorb metal cations and anionic dyes in aqueous solution. J Hazard Mater 85:1124–1130CrossRefGoogle Scholar
  38. 38.
    Ho YS, McKay G, Wase DJ, Foster CF (2000) Study of the sorption of divalent metal ions onto peat. Adsorpt Sci Technol 18:639–650CrossRefGoogle Scholar
  39. 39.
    Abramian L, El-Rassy H (2009) Adsorption kinetics and thermodynamics of azo-dye orange II onto highly porous titania aerogel. Chem Eng J 150:403–404CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.Chemistry Department, Polatlı Science and Literature FacultyHacı Bayram Veli UniversityPolatlıTurkey
  2. 2.Radiation Metrology Division, Sarayköy Nuclear Research and Training CenterTurkish Atomic Energy AuthoritySaray, KazanTurkey

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