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Poly[1,3,6,8-tetra(2-thiophenyl)pyrene] and poly[1,3,6,8-tetra(3-thiophenyl)pyrene] conjugated microporous polymers for reversible adsorbing and fluorescent sensing iodine

  • Tongmou GengEmail author
  • Lanzhen Ma
  • Guofeng Chen
  • Can Zhang
  • Weiyong Zhang
  • Hongyu Xia
  • Hai Zhu
ORIGINAL PAPER
  • 26 Downloads

Abstract

Two thiophene- and pyrene-based conjugated microporous polymers poly[1,3,6,8-tetra(2-thiophenyl)pyrene] and poly[1,3,6,8-tetra(3-thiophenyl)pyrene] (PTThP-2 and PTThP-3) were designed and prepared through a FeCl3 oxidative coupling polymerization. The PTThP-2 and PTThP-3 possess considerable BET surface area of over 370.8 m2 g−1 and 748.2 m2 g−1, large pore volume of 0.544 cm3 g−1 and 0.573 cm3 g−1, good stability, and display excellent guest uptake of 1.62 and 2.00 g g−1 in iodine vapour. Furthermore, incorporation of pyrene and thiophene moieties into these polymers can induce high fluorescence in the dispersions of tetrahydrofuran (THF), which make them sensing electron-deficient iodine via fluorescence quenching with the Ksv of 1.99 × 103 and 5.09 × 103 L mol−1, and the limit of detection of 7.54 × 10−8 and 2.95 × 10−8 mol L−1, respectively.

Keywords

Conjugated microporous polymer Iodine adsorption Fluorescence sensor Pyrene Thiophene 

Notes

Acknowledgements

This work was supported by Natural Science Foundation of Anhui Education Department (under Grant No. KJ2018A0319) and the open fund of AnHui Province Key Laboratory of Optoelectronic and Magnetism Functional Materials (under Grant No. ZD2017007).

Supplementary material

10965_2019_1766_MOESM1_ESM.doc (6.5 mb)
ESM 1 (DOC 6636 kb)

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Copyright information

© The Polymer Society, Taipei 2019

Authors and Affiliations

  • Tongmou Geng
    • 1
    Email author
  • Lanzhen Ma
    • 1
  • Guofeng Chen
    • 1
  • Can Zhang
    • 1
  • Weiyong Zhang
    • 1
  • Hongyu Xia
    • 1
  • Hai Zhu
    • 1
  1. 1.AnHui Province Key Laboratory of Optoelectronic and Magnetism Functional Materials, Key Laboratory of Functional Coordination Compounds of Anhui Higher Education InstitutesAnqing Normal UniversityAnqingChina

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