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Iron(III) porphyrin catalyzed polymerization of acrylamide in ionic liquids

  • Anchal Singhal
  • S. M. S. Chauhan
ORIGINAL PAPER
  • 16 Downloads

Abstract

Iron(III) porphyrin is advocated as catalyst for polymerization of acrylamide with hydrogen peroxide in ionic liquid medium. Reaction conditions were optimized using different porphyrins, solvents, oxidants and initiators. The polymer products were characterized by using 1H NMR, FT-IR, GPC and Mass spectrometric techniques. The recyclability of catalyst and ionic liquids, high yields, high molecular weights and simple work-up procedure are the important attributes of this protocol and contribute as an attractive addition to polymer chemistry.

Keywords

Polyacrylamide Porphyrin Ionic liquids Catalysis Hydrogen peroxide 

Notes

Acknowledgements

We are grateful for financial assistance to the Council of Scientific and Industrial Research (CSIR), New Delhi, India. We also thank Indian Institute of Technology, Delhi for facilitating GPC analysis and Central Instrumentation Facility (CIF), University of Delhi for characterization of polymer products.

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Copyright information

© The Polymer Society, Taipei 2018

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of DelhiDelhiIndia

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