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Journal of Solution Chemistry

, Volume 48, Issue 4, pp 455–488 | Cite as

Density and Excess Volume for Four Systems Involving Eugenol and Furan

  • Christophe CoqueletEmail author
  • Eric Auger
  • Alain Valtz
Article
  • 23 Downloads

Abstract

Density and speed of sound measurements have been performed, at atmospheric pressure, using an Anton Paar digital vibrating tube densitometer for pure ethanol, 1-octanol, n-hexane, furan and eugenol, from 278.15 to 323.15 K and for the binary mixtures of furan + ethanol, furan + 1-octanol, eugenol + 1-octanol and eugenol + n-hexane from 278.15 to 323.15 K. Excess molar volumes were calculated and compared. The Redlich–Kister correlation was used to correlate the data. In order to identify the most important molecular interaction contributing to the excess molar volume, the Prigogine–Flory–Patterson theory was applied to correlate and predict the excess molar volumes of the mixtures.

Keywords

Excess molar volume Partial molar volume Eugenol Furan 

Notes

Acknowledgments

Financial support from the ANR of France through the project Memobiol (ANR-09-CP2D-10-04 MEMOBIOL) is gratefully acknowledged.

Supplementary material

10953_2019_870_MOESM1_ESM.docx (210 kb)
Supplementary material 1 (DOCX 210 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Mines ParisTech PSL University, CTP-Centre of Thermodynamics of ProcessesFontainebleauFrance

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