Novel Experimental Approach to Obtain the Oxygen-Deficient LaBaCaCu3Oy Superconductor Compound
Original Articles
First Online:
- 31 Downloads
Abstract
This work presents a novel approach based on the nitrate decomposition method for the preparation the oxygen-deficient LaBaCaCu3Oy (La1113) compound. The XRD results reveal the presence of the triple perovskite structure LaBaCaCu3Oy as a dominant phase crystallizing in the tetragonal system with the space group P4/mmm. The SEM observation shows a low porosity and EDAX data indicates the presence of the basic elements of the phase. The superconducting character of the compound is confirmed by AC susceptibility measurements with Tc = 63 K even if the samples are not treated under oxygen atmosphere.
Keywords
Nitrate decomposition method X-ray diffraction (XRD) Energy-dispersive analysis with X-rays (EDAX) SuperconductorsNotes
References
- 1.Awana, V.P.S., de Lima, O.F., Malik, S.K., Yelon, W.B., Narlikar, A.V.: Structural and superconducting properties of LaBaCaCu3O7+δ system: a neutron diffraction study. Physica C. 314, 93–97 (1999)ADSCrossRefGoogle Scholar
- 2.Valladares, L.D.L.S., Angel Bustamante, D., Gonzalez, J.C., Juan Feijoo, L., Ana Osorio, A., Mitrelias, T., Majima, Y., Barnes, C.H.W.: Magnetic properties of the superconductor LaCaBaCu3O7. The Open Superconductors Journal. 2, 19–27 (2010)ADSCrossRefGoogle Scholar
- 3.Cava, R.J., Hewat, A.W., Hewat, E.A., Batlogg, B., Marezio, M., Rabe, K.M., Karajewski, J.J., Peck Jr., W.F., Rupp Jr., L.W.: Structural anomalies, oxygen ordering and superconductivity in oxygen deficient Ba2YCu3Ox. Physica C. 165, 419–433 (1990)ADSCrossRefGoogle Scholar
- 4.Shi, D.: Isothermal shear transformation in YBa2Cu3O7−δ Physica C. 156, 359–362 (1988)Google Scholar
- 5.Smith, J.F., Wohlleben, Z.D.: Twin refinement below room temperature in the 1-2-3 high T c superconductors. Physica B. 72, 323–334 (1988)Google Scholar
- 6.Kini, N.S., Umarji, A.M.: Influence of synthesis route on structural phase transition in YBa2-xLa xCu3Oy (0< x<0.20). Physica C. 349, 257–264 (2001)ADSCrossRefGoogle Scholar
- 7.Baškys, E., Bondarenka, V., Grebinskij, S.I., Sereika, R.: XPS study of sol–gel produced lanthanum oxide thin films. Lith. J. Phys. 54, 120–124 (2014)CrossRefGoogle Scholar
- 8.Misra, D., Iwai, H.: Dielectrics for nanosystems II: materials science, processing, reliability, and manufacturing. The Electrochemical Society, New Jersey (2006)Google Scholar
- 9.Chen, C., Wondre, F., Wanklyn, B.M., Wanklyn, J.W., Ryan, J.F.: Phase diagram, crystal growth and superconductivity of CaLaBaCu3O7−Y crystal. J. Mater. Sci. 10, 581–584 (1999)Google Scholar
- 10.Corredor, L.T., Landinez Téllez, D.A., RoaRojas, J., Albino Aguiar, J.: Structural properties of CaLaBaCu3O7−δ single crystals grown by self-flux method. Braz. J. Phys. 33, 733–736 (2003)ADSCrossRefGoogle Scholar
- 11.Vaclave, P., Dusek, M., Palatinus, L.: The crystallographic computing system for standing and modulate structures. Institute of Physics, Prague (2006)Google Scholar
- 12.Leu, Y.D., Huang, W.N., Wang, C.M., Kao, H.-C.I.: Superconductivity and hole concentration of La3−xCa2xBa3−xCu6Oy compounds. Physica C. 261, 284–288 (1996)ADSCrossRefGoogle Scholar
- 13.Ettarh, C., Glawey, A.K.: A kinetic and mechanistic study of the thermal decomposition of calcium nitrate. Theor. Chim. Acta. 288, 203–219 (1996)CrossRefGoogle Scholar
- 14.Mentus, S., Jelić, D., Gudić, V.: Lanthanum nitrate decomposition by both temperature programmed heating and citrate gel combustion. J. Therm. Anal. Calorim. 90, 393–397 (2007)CrossRefGoogle Scholar
- 15.Engelsberg, S.: Superconductivity in the series La3Ba3CaxCu6+xOy, 0≤x≤3, an oxygen deficient tetragonal triple perovskite structure. Physica C. 176, 451–456 (1991)ADSCrossRefGoogle Scholar
- 16.Raveau, B., Michel, C., Hervieu, M., Groult, D.: Crystal chemistry of high Tc superconducting copper oxides, pp. 85–86. Springer, Heidelberg (1991)CrossRefGoogle Scholar
- 17.Martínez, B.D., Parra Vargas, C.A., David, A., Landinez Téllez, D.A., Roa Rojas, J.: Produccion y Caracterizacion del Material Superconductor Yb0.6Sm0.4Ba2Cu3O7-δ. Revista Colombiana de Física. 40, 104–106 (2008)Google Scholar
Copyright information
© Springer Science+Business Media, LLC, part of Springer Nature 2019