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Journal of Superconductivity and Novel Magnetism

, Volume 32, Issue 2, pp 167–173 | Cite as

Superconductivity in Perovskite Ba0.85−xLaxPr0.15(Bi0.20Pb0.80)O3−δ

  • Attia Firdous
  • Xiaoge Wang
  • Muhammad Asim Farid
  • Meng Zhang
  • Yan Wang
  • Jinling Geng
  • Junliang Sun
  • Guobao LiEmail author
  • Fuhui Liao
  • Jianhua LinEmail author
Original Paper
  • 159 Downloads

Abstract

The perovskites Ba0.85−xLaxPr0.15(Bi0.20Pb0.80)O3−δ (0.0 ≤ x ≤ 0.07) have been synthesized by traditional solid-state method. They crystallize in P1 space group confirmed by x-ray and rotational electron diffraction data. X-ray photoelectron spectroscopy data indicate that the valences of bismuth are + 3 and + 5, while the valences of lead are + 2 and + 4 in this solid solution. They all show superconductivity. The \(T_{c}^{\text {zero}}\) (the highest temperature at which the sample shows zero electrical resistivity) decreases with an increase of La in the sample.

Keywords

Solid-state reaction Perovskite Ba0.85−xLaxPr0.15(Bi0.20Pb0.80)O3−δ Superconductivity 

Notes

Acknowledgments

This work is supported by the National Natural Science Foundation of China (Grant 21771007).

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular EngineeringPeking UniversityBeijingPeople’s Republic of China
  2. 2.Department of Chemistry, School of ScienceBeijing Jiaotong UniversityBeijingPeople’s Republic of China

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