Three different dimensional zinc phosphites and zinc phosphates, [C7H18N]2[Zn(HPO3)2] (1), [C6H9N2][Zn2(PO4)(HPO3)] (2), and [C6H14N2][Zn2(PO4)2] (3) were hydro(solvo)thermally synthesized from organic amines with the same number of nonhydrogen atoms and different dimensionalities and sizes. Structural analysis indicates that compound 1 shows a one-dimensional (1D) chain structure; compound 2 is an inorganic–organic hybrid two-dimensional (2D) material; compound 3 is a three-dimensional (3D) open-framework zinc phosphate EDI zeolite. The mechanisms of 1D chain-like n-heptamine, 2D planar 3-aminomethylpyridine, and 3D triethylenediamine on the synthetic process were analyzed. The n-heptamine has only one function: a protonated template in compound 1, while 3-aminomethylpyridine has two functions: a protonated template and binding ligand in the synthesis of compound 2. The triethylenediamine has three functions in compound 3: a protonated template, space-filling agent, and structure-directing agent. Thus, the three organic amines play different roles in the three compounds. They were analyzed by XRD, SEM, TGA, FT-IR, ICP, and CHN analyses.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
J.Y. Li, A. Corma, J.H. Yu, Chem Soc Rev. 44, 7112 (2015)
D.F. Weng, Z.M. Wang, S. Gao, Chem. Soc. Rev. 40, 3157 (2011)
C.N.R. Rao, S. Natarajan, A. Choudhury, S. Neeraj, A.A. Ayi, Acc. Chem. Res. 34, 80 (2001)
T. Rojo, J.L. Mesa, J. Lago, B. Bazán, J.L. Pizarro, M.I. Arriortua, J. Mater. Chem. 19, 3793 (2009)
S.T. Wilson, B.M. Lok, C.A. Messian, T.R. Cannan, E.M. Flanigen, J. Am. Chem. Soc. 104, 1146 (1982)
R. Murugavel, A. Choudhury, M.G. Walawalkar, R. Pothiraja, C.N.R. Rao, Chem. Rev. 108, 3549 (2008)
J.B. Wu, Y. Yan, B.K. Liu, X.L. Wang, J.Y. Li, J.H. Yu, Chem. Commun. 49, 4995 (2013)
M. Yang, P.F. Yan, F.F. Xu, J.H. Ma, U. Welz-Biermann, Micropor Mesoporo Mater 147, 73 (2012)
Y.T. Chang, S.H. Lo, C.H. Lin, L.I. Hung, S.L. Wang, Chem.-Eur. J. 24, 12474 (2018)
H.Z. Xing, W.T. Yang, T. Su, Y. Li, J. Xu, T. Nakano, J.H. Yu, R.R. Xu, Angew. Chem. Int. Ed. 49, 2328 (2010)
G.M Wang, J.H Li, L Wei, S.D. Han, X.M. Zhao, Z.Z. Bao, CrystEngComm. 17, 8414 (2015)
X.J. Wang, J.H. Zhang, J.L. Song, F. Kong, J.G. Mao, CrystEngComm 15, 2519 (2013)
P. Ramaswamy, N.N. Hegde, R. Prabhu, V.M. Vidya, A. Datta, S. Natarajan, Inorg. Chem. 48, 11697 (2009)
H.Y. Lin, C.Y. Chin, H.L. Huang, W.Y. Huang, M.J. Sie, L.H. Huang, Y.H. Lee, C.H. Lin, K.H. Lii, X.H. Bu, S.L. Wang, Science 339, 811 (2013)
C. Lin, F.J. Pan, J. Li, Y.P. Chen, D.E. Shi, T.Q. Ma, Y.Q. Yang, X. Du, W. Wang, F.H. Liao, J.H. Lin, T. Yang, J.L. Sun, Cryst. Growth Des. 18, 1267 (2018)
X.L. Wang, Y. Yan, J.B. Wu, C.Q. Zhang, J.Y. Li, CrystEngComm 16, 2266 (2014)
X.C. Liu, Y. Xing, X.L. Wang, H.B. Xu, X.Z. Liu, K.Z. Shao, Z.M. Su, Chem. Commun. 46, 2614 (2010)
L.M. Li, K. Cheng, J. Zhang, Inorg. Chem. Commun. 30, 136 (2013)
J.A. Rodgers, W.T.A. Harrison, Chem. Commun. 2000, 2385 (2000)
J.M. Tian, B. Li, X.Y. Zhang, J.P. Zhang, CrystEngComm 16, 1071 (2014)
H.D. Li, L.R. Zhang, Q.S. Huo, Y.L. Liu, J. Solid State Chem. 197, 75 (2013)
A. Sutrisno, L. Liu, J. Xu, Y.N. Huang, Phys. Chem. Chem. Phys. 13, 16606 (2011)
X. Zhang, G.M. Wang, Z.H. Wang, Y.X. Wang, J.H. Lin, J Mol Struct. 1056–1057, 25 (2014)
Y.L. Lai, K.H. Lii, S.L. Wang, J. Am. Chem. Soc. 129, 5350 (2007)
Z.J. Dong, L. Zhao, Z.Q. Liang, P. Chen, Y. Yan, J.Y. Li, J.H. Yu, R.R. Xu, Dalton Trans. 39, 5439 (2010)
Y.L. Yang, N. Li, H.B. Song, H.G. Wang, W.B. Chen, S.H. Xiang, Chem. Mater. 19, 1889 (2007)
J. Přech, P. Pizarro, D.P. Serrano, J. Čejka, Chem Soc Rev 47, 8263 (2018)
M.Y. Emran, M.A. Shenashen, H. Morita, S.A. El-Safty, Advanced healthcare materials 7, 1701459 (2018)
M.Y. Emran, M.A. Shenashen, H. Morita, S.A. El-Saftya, Biosens Bioelectron 109, 237 (2018)
N. Akhtar, M.Y. Emran, M.A. Shenashen, H. Khalifa, T. Osaka, A. Faheem, T. Homma, H. Kawarada, S.A. El-Safty, J Mater Chem B5, 7985 (2017)
M.Y. Emran, M.A. Shenashen, A.A. Abdelwahab, M. Abdelmottaleb, S.A. El-Safty, New J. Chem 42, 5037 (2018)
D. Hassen, M.A. Shenashen, A.R. El-Safty, A. Elmarakbi, S.A. El-Safty, Scientific reports. 8, 3740 (2018)
D. Hassen, S.A. El-Safty, K. Tsuchiya, A. Chatterjee, A. Elmarakbi, M.A. Shenashen, M. Sakai, Scientific reports. 6, 24330 (2016)
M.A. Shenashen, D. Hassen, S.A. El-Safty, M.M. Selim, N. Akhtar, A. Chatterjee, A. Elmarakbi, Advanced Materials Interfaces 3, 1600743 (2016)
M.A. Shenashen, D. Hassen, S.A. El-Safty, H. Isago, A. Elmarakbi, H. Yamaguchi, Chem Eng J 313, 83 (2017)
I. Halime, A. Bezgour, M. Fahim, M. Dusek, K. Fejfarova, M. Lachkar, B.E. Bali, J. Chem. Crystallogr. 41, 223 (2011)
C.M. Wang, C.W. Chiu, H.M. Lin, K.H. Lii, J. Solid State Chem. 204, 16 (2013)
SAINT, Bruker AXS Inc. 5465 East Cheryl Parkway, Madison, WI 53711–5373, USA, 2000.
G.M. Sheldrick, Acta Crystallogr. A. 64, 112 (2008)
Z.G. Zhang, S.J. Yao, J.C. Liao, Z.Y. Dai, J. Fu, Mater. Chem. A. 1, 4945 (2013)
C. Fan, D. Slebodnick, R. Troya, B.E. Angel, Hanson. Inorg. Chem. 44, 2719 (2005)
J.H. Li, L. Wei, Z.Z. Bao, G.M. Wang, Z.H. Wang, Solid State Sci 51, 13 (2016)
A.L.J. Spek, J. Appl. Crystallogr. 36, 7 (2003)
W.T.A. Harrison, Acta Crystallogr. E. 57, 248 (2001)
J. Liang, J.Y. Li, J.H. Yu, Q.H. Pan, Q.R. Fang, R.R. Xu, J. Solid State Chem. 178, 2673 (2005)
This work is supported by the National Natural Science Foundation of China (51774175 and 51805235), the Department of Education of Liaoning Province (LJ2017QL005) and College Students' innovation training program (201810147077).
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
About this article
Cite this article
Wang, X., Zhou, Y., Dong, Z. et al. The effects of different dimensional organic amines on synthetic zinc phosphites/phosphates. J Porous Mater 27, 21–28 (2020). https://doi.org/10.1007/s10934-019-00790-2
- Zinc phosphites/phosphates
- Organic amine
- Templating effect
- Hydro(solvo)thermal synthesis
- Inorganic–organic hybrid