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Journal of Porous Materials

, Volume 26, Issue 6, pp 1657–1665 | Cite as

Characterization and catalytic performance evaluation of a novel heterogeneous mesoporous catalyst for methanol–acetic acid esterification

  • Veli ŞimşekEmail author
  • Samet ŞahinEmail author
Article
  • 95 Downloads

Abstract

In this study, a novel heterogeneous catalyst based on silicotungstic acid (STA) has been synthesised using hydrothermal and wet-impregnation methods for methanol–acetic acid esterification. Active compound STA was loaded on MCM-48 support material to compose proposed catalysis. Tungsten (W) to silica (Si) molar ratios were set as 5%, 10%, 20% and 40%. Characterizations of MCM-48 and STA/MCM-48 catalysts were performed using BET, XRD, FT-IR, DRIFT, TGA/DTA, SEM, and EDX mapping analysis. Results showed successful synthesis of the novel catalyst with good thermal stability and formation of both Brønsted acid and Lewis acid sites. The catalytic activity was also investigated in methyl acetate esterification reaction and it was shown that temperature, reaction time and the molar ratio of the reactants had significant effect on conversion rate. The highest catalytic activity was obtained as 84% with 20% catalyst at feed ratio of 1:3 (metanol:acetic acid, 353 K, 27 h).

Keywords

STA MCM-48 Esterification Catalytic activity Wet-impregnation Hydrothermal method 

Notes

Supplementary material

10934_2019_764_MOESM1_ESM.docx (645 kb)
Supplementary material 1 (DOCX 645 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of Chemical Engineering, Faculty of EngineeringBilecik Şeyh Edebali UniversityBilecikTurkey
  2. 2.Department of Bioengineering, Faculty of EngineeringBilecik Şeyh Edebali UniversityBilecikTurkey
  3. 3.Biotechnology Application and Research CentreBilecik Şeyh Edebali UniversityBilecikTurkey

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