Journal of Polymers and the Environment

, Volume 26, Issue 11, pp 4303–4310 | Cite as

Synthesis of Ion-Imprinted Alginate Based Beads: Selective Adsorption Behavior of Nickel (II) Ions

  • Bengi ÖzkahramanEmail author
  • Zehra Özbaş
  • Ayça Bal Öztürk
Original Paper


Ni(II) imprinted and non-imprinted bioadsorbent alginate beads were prepared, and utilized in the selective adsorption of Ni(II) ions. The optimum adsorption capacity were 6.00 mmol g−1 at 500 ppm initial metal ion concentration at pH 7 for Ni(II) imprinted alginate beads (IIP). The equilibrium data were applied to Langmuir and Freundlich adsorption isotherms, and it fitted both isotherm models. Thermodynamic parameters showed favorable and endothermic nature of adsorption. Ni(II) imprinted bead showed the strong ability to selective adsorption from Cu(II), Co(II) and Zn(II) ions. In conclusion, Ni(II) ion imprinted alginate beads could be used repeatedly without any significant reduce of adsorption capacity.


Ion imprinted polymer Alginate bead Selectivity Ni(II) ion 


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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Bengi Özkahraman
    • 1
    Email author
  • Zehra Özbaş
    • 2
  • Ayça Bal Öztürk
    • 3
    • 4
  1. 1.Department of Polymer Engineering, Faculty of EngineeringHitit UniversityCorumTurkey
  2. 2.Department of Chemical Engineering, Faculty of EngineeringCankırı Karatekin UniversityCankırıTurkey
  3. 3.Department of Analytical Chemistry, Faculty of PharmacyIstinye UniversityZeytinburnuTurkey
  4. 4.Department of Stem Cell and Tissue Engineering, Institute of Health SciencesIstinye UniversityZeytinburnuTurkey

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