Advertisement

Journal of Polymers and the Environment

, Volume 26, Issue 8, pp 3470–3483 | Cite as

Reactive Dye Adsorption from Aqueous Solution on HPEI-Modified Fe3O4 Nanoparticle as a Superadsorbent: Characterization, Modeling, and Optimization

  • Arash Dalvand
  • Mehdi Khoobi
  • Ramin Nabizadeh
  • Mohammad Reza Ganjali
  • Elham Gholibegloo
  • Amir Hossein Mahvi
Original Paper
First Online:

Abstract

In this work, the optimum condition for the adsorption of Reactive Blue 19 dye onto Fe3O4 functionalized with hyperbranched polyethylenimine (Fe@HPEI) was determined using response surface methodology. The properties of synthesized magnetic Fe@HPEI nanoparticles were ascertained using FTIR, SEM, TEM, VSM and zeta potential measurement. The experimental adsorption data indicating the positive effect of adsorbent dose and contact time, and the negative effect of pH, initial dye concentration and ionic strength on dye adsorption. At optimal condition; pH 3.4, contact time 25 min, adsorbent dose 0.4 g/L and initial dye concentration 113 mg/L, Fe@HPEI nanoparticles removed dye up to 99.27%. The maximum experimental dye adsorption was near to the predicted value of 100%, which confirmed the reliability of the selected statistical model. The dye adsorption data were fitted well to Langmuir isotherm and pseudo-second-order kinetic, and the maximum adsorption capacity was 500 mg/g. Totally, Fe@HPEI as an effective superadsorbent can be repeatedly utilized for the adsorption of dye from the aqueous environment.

Keywords

Dye adsorption Fe@HPEI Central composite design Modeling Optimization 
This is a preview of subscription content, log in to check access.

Notes

Acknowledgements

The authors are grateful to Center for Water Quality Research, Tehran University of Medical Sciences for financial support of this study (Grant Number: 94-01-46-28904). The first author would like to thank, Shahid Sadoughi University of Medical Sciences for supporting current work.

Compliance with Ethical Standards

Conflict of interest

The authors declare that they have no conflict of interest.

References

  1. 1.
    Gholami-Borujeni F, Mahvi AH, Nasseri S, Faramarzi MA, Nabizadeh R, Alimohammadi M (2011) Appl Biochem Biotechnol 165:1274–1284CrossRefGoogle Scholar
  2. 2.
    Wang T, Kailasam K, Xiao P, Chen G, Chen L, Wang L, Li J, Zhu J (2014) Microporous Mesoporous Mater 187:63–70CrossRefGoogle Scholar
  3. 3.
    Mahmoodi NM, Dalvand A (2013) Desalin Water Treat 51:5959–5964CrossRefGoogle Scholar
  4. 4.
    Maleki A, Mahvi AH, Ebrahimi R, Zandsalimi Y (2010) Korean J Chem Eng 27:1805–1810CrossRefGoogle Scholar
  5. 5.
    Yousefi N, Nabizadeh R, Nasseri S, Khoobi M, Nazmara S, Mahvi AH (2017) Korean J Chem Eng 34:2342–2353CrossRefGoogle Scholar
  6. 6.
    Nematollahzadeh A, Shojaei A, Karimi M (2015) React Funct Polym 86:7–15CrossRefGoogle Scholar
  7. 7.
    Natarajan S, Bajaj HC, Tayade RJ (2018) J Environ Sci 65:201–222CrossRefGoogle Scholar
  8. 8.
    Tsang DC, Hu J, Liu MY, Zhang W, Lai KC, Lo IM (2007) Water Air Soil Pollut 184:141–155CrossRefGoogle Scholar
  9. 9.
    Khatri A, Peerzada MH, Mohsin M, White M (2015) J Clean Prod 87:50–57CrossRefGoogle Scholar
  10. 10.
    Klemola K, Honkalampi-Hämäläinen U, Liesivuori J, Pearson J, Lindström-Seppä P (2006) Autex Res J 6:182–190Google Scholar
  11. 11.
    Dalvand A, Gholami M, Joneidi A, Mahmoodi NM (2011) Clean-Soil Air Water 39:665–672CrossRefGoogle Scholar
  12. 12.
    Dalvand A, Gholibegloo E, Ganjali MR, Golchinpoor N, Khazaei M, Kamani H, Hosseini SS, Mahvi AH (2016) Environ Sci Pollut Res 23:16396–16405CrossRefGoogle Scholar
  13. 13.
    Fathy NA, El-Shafey SE, El-Shafey OI, Mohamed WS (2013) J Environ Chem Eng 1:858–864CrossRefGoogle Scholar
  14. 14.
    Ergene A, Ada K, Tan S, Katırcıoğlu H (2009) Desalination 249:1308–1314CrossRefGoogle Scholar
  15. 15.
    Shirmardi M, Mahvi AH, Hashemzadeh B, Naeimabadi A, Hassani G, Niri MV (2013) Korean J Chem Eng 30:1603–1608CrossRefGoogle Scholar
  16. 16.
    Mohammadi N, Khani H, Gupta VK, Amereh E, Agarwal S (2011) J Colloid Interface Sci 362:457–462CrossRefGoogle Scholar
  17. 17.
    Cao D, Jin X, Gan L, Wang T, Chen Z (2016) Chemosphere 159:23–31CrossRefGoogle Scholar
  18. 18.
    Yoon SU, Mahanty B, Ha HM, Kim CG (2016) J Nanopart Res 18:1–10CrossRefGoogle Scholar
  19. 19.
    Li DP, Zhang YR, Zhao XX, Zhao BX (2013) Chem Eng J 232:425–433CrossRefGoogle Scholar
  20. 20.
    Dalvand A, Nabizadeh R, Ganjali MR, Khoobi M, Nazmara S, Mahvi AH (2016) J Magn Magn Mater 404:179–189CrossRefGoogle Scholar
  21. 21.
    Zhang YR, Shen SL, Wang SQ, Huang J, Su P, Wang QR, Zhao BX (2014) Chem Eng J 239:250–256CrossRefGoogle Scholar
  22. 22.
    Xia T, Guan Y, Yang M, Xiong W, Wang N, Zhao S, Guo C (2014) Colloids Surf A 443:552–559CrossRefGoogle Scholar
  23. 23.
    Chen CT, Wang LY, Ho YP (2011) Anal Bioanal Chem 399:2795–2806CrossRefGoogle Scholar
  24. 24.
    Sajab MS, Chia CH, Zakaria PS, Khiew SC (2013) Bioresour Technol 128:571–577CrossRefGoogle Scholar
  25. 25.
    Sun XF, Wang SG, Cheng W, Fan M, Tian BH, Gao BY, Li XM (2011) J Hazard Mater 189:27–33CrossRefGoogle Scholar
  26. 26.
    Kim MH, Hwang CH, Kang SB, Kim S, Park SW, Yun YS, Won SW (2015) Chem Eng J 280:18–25CrossRefGoogle Scholar
  27. 27.
    Liu J, Ma S, Zang L (2013) Appl Surf Sci 265:393–398CrossRefGoogle Scholar
  28. 28.
    Khoobi M, Delshad TM, Vosooghi M, Alipour M, Hamadi H, Alipour E, Hamedani MP, Safaei Z, Foroumadi A, Shafiee A (2015) J Magn Magn Mater 375:217–226CrossRefGoogle Scholar
  29. 29.
    Pang Y, Zeng G, Tang L, Zhang Y, Liu Y, Lei X, Li Z, Zhang J, Xie G (2011) Desalination 281:278–284CrossRefGoogle Scholar
  30. 30.
    Ashrafi S, Nasseri S, Alimohammadi M, Mahvi A, Faramarzi M (2016) Desalin Water Treat 57:1–10Google Scholar
  31. 31.
    Ye J, Cong X, Zhang P, Zeng G, Hoffmann E, Liu Y, Wu Y, Zhang H, Fang W, Hahn HH (2016) J Environ Manag 167:1–7CrossRefGoogle Scholar
  32. 32.
    Sahu MK, Sahu UK, Patel RK (2015) RSC Adv 5:42294–42304CrossRefGoogle Scholar
  33. 33.
    Zarei H, Nasseri S, Nabizadeh R, Shemirani F, Dalvand A, Mahvi AH (2017) Desalin Water Treat 67:196–205CrossRefGoogle Scholar
  34. 34.
    Kütahyalı C, Çetinkaya B, Acar MB, Işık NO, Cireli I (2012) J Hazard Mater 201:115–124CrossRefGoogle Scholar
  35. 35.
    Fakhri A, Rashidi S, Tyagi I, Agarwal S, Gupta VK (2016) J Mol Liq 214:378–383CrossRefGoogle Scholar
  36. 36.
    Zhu HY, Fu YQ, Jiang R, Jiang JH, Xiao L, Zeng GM, Zhao SL, Wang Y (2011) Chem Eng J 173:494–502CrossRefGoogle Scholar
  37. 37.
    Cao JS, Lin JX, Fang F, Zhang MT, Hu ZR (2014) Bioresour Technol 163:199–205CrossRefGoogle Scholar
  38. 38.
    Chang YP, Ren CL, Yang Q, Zhang ZY, Dong LJ, Chen XG, Xue DS (2011) Appl Surf Sci 257:8610–8616CrossRefGoogle Scholar
  39. 39.
    Xia C, Jing Y, Jia Y, Yue D, Ma J, Yin X (2011) Desalination 265:81–87CrossRefGoogle Scholar
  40. 40.
    Saleh TA, Agarwal S, Gupta VK (2011) Appl Catal B 106:46–53Google Scholar
  41. 41.
    Liu S, Ding Y, Li P, Diao K, Tan X, Lei F, Zhan Y, Li Q, Huang B, Huang Z (2014) Chem Eng J 248:135–144CrossRefGoogle Scholar
  42. 42.
    Khosravi M, Azizian S (2014) J Ind Eng Chem 20:2561–2567CrossRefGoogle Scholar
  43. 43.
    Xu C, Wang H, Yang W, Ma L, Lin A (2018) J Polym Environ 26:1206–1217CrossRefGoogle Scholar
  44. 44.
    Zazouli MA, Mahvi AH, Dobaradaran S, Barafrashtehpour M, Mahdavi Y, Balarak D (2014) Fluoride 47:349–358Google Scholar
  45. 45.
    Yue L, Ge C, Feng D, Yu H, Deng H, Fu B (2017) J Environ Sci 57:180–189CrossRefGoogle Scholar
  46. 46.
    Laabd M, El Jaouhari A, Bazzaoui M, Albourine A, El Jazouli H (2017) J Polym Environ 25:359–369CrossRefGoogle Scholar
  47. 47.
    Ghaedi M, Hajjati S, Mahmudi Z, Tyagi I, Agarwal S, Maity A, Gupta V (2015) Chem Eng J 268:28–37CrossRefGoogle Scholar
  48. 48.
    Sun L, Chen D, Wan S, Yu Z (2018) J Polym Environ 26:765–777CrossRefGoogle Scholar
  49. 49.
    Rotte NK, Yerramala S, Boniface J, Srikanth VV (2014) Chem Eng J 258:412–419CrossRefGoogle Scholar
  50. 50.
    Li H, An N, Liu G, Li J, Liu N, Jia M, Zhang W, Yuan X (2016) J Colloid Interface Sci 466:343–351CrossRefGoogle Scholar
  51. 51.
    Saleh TA, Gupta VK (2014) Adv Colloid Interface Sci 211:93–101CrossRefGoogle Scholar
  52. 52.
    Isah U, Abdulraheem G, Bala S, Muhammad S, Abdullahi M (2015) Int Biodeter Biodegr 102:265–273CrossRefGoogle Scholar
  53. 53.
    Elsherbiny AS, El-Hefnawy ME, Gemeay AH (2018) J Polym Environ 26:411–422CrossRefGoogle Scholar
  54. 54.
    Shekarriz M, Ramezani Z, Elhami F (2017) Int J Environ Sci Technol 14:1081–1090CrossRefGoogle Scholar
  55. 55.
    Torkshavand Z, Gholami M, Farzadkia M, Esrafili A (2014) Iran J Health Saf Environ 1:101–110Google Scholar
  56. 56.
    Wang L, Zhao X, Zhang J, Xiong Z (2017) Environ Sci Pollut Res 24:14198–14206CrossRefGoogle Scholar
  57. 57.
    Cui L, Wang Y, Gao L, Hu L, Yan L, Wei Q, Du B (2015) Chem Eng J 281:1–10CrossRefGoogle Scholar
  58. 58.
    Gupta VK, Atar N, Yola ML, Üstündağ Z, Uzun L (2014) Water Res 48:210–217CrossRefGoogle Scholar
  59. 59.
    Hassanpour S, Taghizadeh M, Yamini Y (2018) J Polym Environ 26:101–115CrossRefGoogle Scholar
  60. 60.
    Karthikeyan S, Gupta V, Boopathy R, Titus A, Sekaran G (2012) J Mol Liq 173:153–163CrossRefGoogle Scholar
  61. 61.
    Khademi Z, Ramavandi B, Ghaneian MT (2015) J Environ Chem Eng 3:2057–2067CrossRefGoogle Scholar
  62. 62.
    Xue Y, Hou H, Zhu S (2009) Chem Eng J 147:272–279CrossRefGoogle Scholar
  63. 63.
    Çiçek F, Özer D, Özer A, Özer A (2007) J Hazard Mater 146:408–416CrossRefGoogle Scholar
  64. 64.
    Özcan A, Ömeroğlu Ç, Erdoğan Y, Özcan AS (2007) J Hazard Mater 140:173–179CrossRefGoogle Scholar
  65. 65.
    De Souza KC, Antunes MLP, Couperthwaite SJ, Da Conceição FT, De Barros TR, Frost R (2013) J Colloid Interface Sci 396:210–214CrossRefGoogle Scholar
  66. 66.
    Elwakeel K, El-Bindary A, Ismail A, Morshidy A (2016) RSC Adv 6:22395–22410CrossRefGoogle Scholar
  67. 67.
    Shanehsaz M, Seidi S, Ghorbani Y, Shoja SMR, Rouhani S (2015) Spectrochim Acta Part A 149:481–486CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Arash Dalvand
    • 1
    • 2
  • Mehdi Khoobi
    • 3
    • 4
  • Ramin Nabizadeh
    • 2
  • Mohammad Reza Ganjali
    • 5
    • 6
  • Elham Gholibegloo
    • 7
  • Amir Hossein Mahvi
    • 8
    • 9
    • 10
  1. 1.Environmental Science and Technology Research Center, Department of Environmental Health Engineering, School of Public HealthShahid Sadoughi University of Medical SciencesYazdIran
  2. 2.Department of Environmental Health Engineering, School of Public HealthTehran University of Medical SciencesTehranIran
  3. 3.Medical Biomaterials Research CenterTehran University of Medical SciencesTehranIran
  4. 4.Department of Medicinal Chemistry, Faculty of Pharmacy and Pharmaceutical Sciences Research CenterTehran University of Medical SciencesTehranIran
  5. 5.Center of Excellence in Electrochemistry, Faculty of ChemistryUniversity of TehranTehranIran
  6. 6.Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences InstituteTehran University of Medical SciencesTehranIran
  7. 7.Depatment of Organic ChemistryUniversity of ZanjanZanjanIran
  8. 8.Center for Water Quality Research, Institute for Environmental ResearchTehran University of Medical SciencesTehranIran
  9. 9.Center for Solid Waste Research, Institute for Environmental ResearchTehran University of Medical SciencesTehranIran
  10. 10.National Institute of Health ResearchTehran University of Medical SciencesTehranIran

Personalised recommendations