Advertisement

Journal of Polymers and the Environment

, Volume 26, Issue 8, pp 3362–3370 | Cite as

Kinetic, Isotherm and Thermodynamic Studies for Removal of Methylene Blue Using β-Cyclodextrin/Activated Carbon Aerogels

  • Kaixuan Zhou
  • Yanhui Li
  • Qi Li
  • Qiuju Du
  • Dechang Wang
  • Kunyan Sui
  • Cuiping Wang
  • Hongliang Li
  • Yanzhi Xia
Original Paper
First Online:
  • 403 Downloads

Abstract

A novel aerogel (β-CD/AC) was prepared through polymerization reaction of β-cyclodextrin (β-CD) with activated carbon (AC) and vacuum freeze drying method. The structure and morphology of β-CD/AC were characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, Brunauer–Emmett–Teller (BET) method and thermogravimetric analysis (TGA). β-CD/AC is used to deal with wastewater containing methylene blue (MB) dye. The effects of AC content in β-CD/AC, pH value, temperature, contact time and amount of adsorbent on the adsorption of MB were studied in detail. The Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms. The Langmuir monolayer adsorption capacity of MB onto β-CD/AC was estimated as 166.67 mg/g. The kinetics of MB onto β-CD/AC was well described by the pseudo-second order model. The thermodynamic parameters indicated that the adsorption reaction of MB onto β-CD/AC was endothermic and spontaneous.

Keywords

Activated carbon β-Cyclodextrin Adsorption Methylene blue 
This is a preview of subscription content, log in to check access.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (51672140), Natural Science Foundation of Shandong Province (ZR2015EM038), Taishan Scholar Program of Shandong Province (201511029).

References

  1. 1.
    Du Q, Sun J, Li Y, Yang X, Wang X, Wang Z, Xia L (2014) Chem Eng J 245:99CrossRefGoogle Scholar
  2. 2.
    Li Q, Li Y, Ma X, Du Q, Sui K, Wang D, Wang C, Li H, Xia Y (2017) Chem Eng J 316:623CrossRefGoogle Scholar
  3. 3.
    Hassan AF, Abdel-Mohsen AM, Elhadidy H (2014) Int J Biol Macromol 68:125CrossRefPubMedGoogle Scholar
  4. 4.
    Wu C, Zhang Y, Li S, Zheng H, Wang H, Liu J, Li K, Yan H (2011) Chem Eng J 178:468CrossRefGoogle Scholar
  5. 5.
    Ghoreishi SM, Haghighi R (2003) Chem Eng J 95:163CrossRefGoogle Scholar
  6. 6.
    Raghu S, Ahmed Basha C (2007) J Hazard Mater 149:324CrossRefPubMedGoogle Scholar
  7. 7.
    Zhu MX, Lee L, Wang HH, Wang Z (2007) J Hazard Mater 149:735CrossRefPubMedGoogle Scholar
  8. 8.
    Lin J, Ye W, Zeng H, Yang H, Shen J, Darvishmanesh S, Luis P, Sotto A, Van der Bruggen B (2015) J Membr Sci 477:183CrossRefGoogle Scholar
  9. 9.
    Zhao W, Tang Y, Xi J, Kong J (2015) Appl Surf Sci 326:276CrossRefGoogle Scholar
  10. 10.
    Li Y, Sun J, Du Q, Zhang L, Yang X, Wu S, Xia Y, Wang Z, Xia L, Cao A (2014) Carbohydr Polym 102:755CrossRefPubMedGoogle Scholar
  11. 11.
    Ghaedi M, Nasab AG, Khodadoust S, Rajabi M, Azizian S (2014) J Ind Eng Chem 20:2317CrossRefGoogle Scholar
  12. 12.
    Rache ML, García AR, Zea HR, Silva AMT, Madeira LM, Ramírez JH (2014) Appl Catal B 146:192CrossRefGoogle Scholar
  13. 13.
    Parida SK, Dash S, Patel S, Mishra BK (2006) Adv Colloid Interface Sci 121:77CrossRefPubMedGoogle Scholar
  14. 14.
    Yang JY, Jiang XY, Jiao FP, Yu JG (2018) Appl Surf Sci 436:198CrossRefGoogle Scholar
  15. 15.
    Wu ZL, Liu F, Li CK, Chen XQ, Yu JG (2016) Colloids Surf A 509:65CrossRefGoogle Scholar
  16. 16.
    Ferreira GMD, Ferreira GMD, Hespanhol MC, de Paula Rezende J, dos Santos Pires AC, Gurgel LVA, da Silva LHM (2017) Colloids Surf A 529:531CrossRefGoogle Scholar
  17. 17.
    Hameed BH, Din AT, Ahmad AL (2007) J Hazard Mater 141:819CrossRefPubMedGoogle Scholar
  18. 18.
    Thue PS, Adebayo MA, Lima EC, Sieliechi JM, Machado FM, Dotto QL, Vaghetti JCP, Dias SLP (2016) J Mol Liq 223:1067CrossRefGoogle Scholar
  19. 19.
    Islam MA, Ahmed MJ, Khanday WA, Asif M, Hameed BH (2017) J Environ Manag 203:237CrossRefGoogle Scholar
  20. 20.
    Fu KF, Yue QY, Gao BY, Wang Y, Li Q (2017) Colloid Surf A 529:842CrossRefGoogle Scholar
  21. 21.
    Li XK, Zhang QY, Tang LL, Lu P, Sun FQ, Li LS (2009) J Hazard Mater 163:115CrossRefPubMedGoogle Scholar
  22. 22.
    Acevedo B, Barriocanal C, Lupul I, Gryglewicz G (2015) Fuel 151:83CrossRefGoogle Scholar
  23. 23.
    Mu’azu ND, Essa MH, Lukman S (2017) Water Sci Technol 76:2213CrossRefPubMedGoogle Scholar
  24. 24.
    Nam H, Wang S, Jeong HR (2018) Fuel 213:186CrossRefGoogle Scholar
  25. 25.
    Alsbaiee A, Smith BJ, Xiao L, Ling Y, Helbling DE, Dichtel WR (2016) Nature 529:190CrossRefPubMedGoogle Scholar
  26. 26.
    He K, Qiu F, Qin J, Yan J, Yang D (2014) J Ind Eng Chem 20:1293CrossRefGoogle Scholar
  27. 27.
    Yan J, Zhu Y, Qiu F, Zhao H, Yang D, Wang J, Wen W (2016) Chem Eng Res Des 106:168CrossRefGoogle Scholar
  28. 28.
    Morin-Crini N, Crini G (2013) Prog Polym Sci 38:344CrossRefGoogle Scholar
  29. 29.
    Xiao J, Chen YT, Xu JB (2014) J Ind Eng Chem 20:2830CrossRefGoogle Scholar
  30. 30.
    Saha I, Gupta K, Chakraborty S, Chatterjee D, Ghosh UC (2014) J Ind Eng Chem 20:1741CrossRefGoogle Scholar
  31. 31.
    Yu L, Xue WH, Cui L, Xing W, Cao XL, Li HY (2014) Int J Biol Macromol 64:233CrossRefPubMedGoogle Scholar
  32. 32.
    Huang H, Fan YF, Wang JW, Gao HQ, Tao SY (2013) Macromol Res 21:726CrossRefGoogle Scholar
  33. 33.
    Wang D, Liu L, Jiang X, Yu J, Chen X (2015) Colloids Surf A 466:166CrossRefGoogle Scholar
  34. 34.
    Putra EK, Pranowo R, Sunarso J, Indraswati N, Ismadji S (2009) Water Res 43:2419CrossRefPubMedGoogle Scholar
  35. 35.
    Oliveira FS, Freitas TS, Cruz RPD, Costa MDS, Pereira RLS, Quintans-Junior LJ, Andrade TA, Menezes PDP, Sousa BMH, Nunes PS, Serafini MR, Menezes IRA, Araujo AAS, Coutinho HDM (2017) Biomed Pharmacother 92:1111CrossRefPubMedGoogle Scholar
  36. 36.
    Gerçel Ö, Gerçel HF (2007) Che Eng J 132:289CrossRefGoogle Scholar
  37. 37.
    Song N, Wu XL, Zhong S, Lin H, Chen JR (2015) J Mol Liq 212:63CrossRefGoogle Scholar
  38. 38.
    Aravindhan R, Fathima NN, Rao JR, Nair BU (2007) Colloids Surf A 299:232CrossRefGoogle Scholar
  39. 39.
    Chen L, Li Y, Du Q, Wang Z, Xia Y, Yedinak E, Lou J, Ci L (2017) Carbohydr Polym 155:345CrossRefPubMedGoogle Scholar
  40. 40.
    Shi H, Li W, Zhong L, Xu C (2014) Ind Eng Chem Res 53:1108CrossRefGoogle Scholar
  41. 41.
    Shen Y, Fang Q, Chen B (2015) Environ Sci Technol 49:67CrossRefPubMedGoogle Scholar
  42. 42.
    Li L, Fan L, Sun M, Qiu H, Li X, Duan H, Luo C (2013) Int J Biol Macromol 58:169CrossRefPubMedGoogle Scholar
  43. 43.
    Fan L, Luo C, Sun M, Qiu H, Li X (2013) Colloids Surf B 103:601CrossRefGoogle Scholar
  44. 44.
    Bulut E, Özacar M, Şengil İA (2008) J Hazard Mater 154:613CrossRefPubMedGoogle Scholar
  45. 45.
    Gupta VK, Pathania D, Sharma S, Agarwal S, Singh P (2013) J Mol Liq 177:325CrossRefGoogle Scholar
  46. 46.
    Doğan M, Alkan M, Demirbaş Ö, Özdemir Y, Özmetin C (2006) Chem Eng J 124:89CrossRefGoogle Scholar
  47. 47.
    Ho YS, Chiang CC (2001) Adsorption 7:139CrossRefGoogle Scholar
  48. 48.
    Uzun İ (2006) Dyes Pigments 70:76CrossRefGoogle Scholar
  49. 49.
    Biswas K, Gupta K, Ghosh UC (2009) Chem Eng J 149:196CrossRefGoogle Scholar
  50. 50.
    Chen N, Zhang Z, Feng C, Zhu D, Yang Y, Sugiura N (2011) J Hazard Mater 186:863CrossRefPubMedGoogle Scholar
  51. 51.
    Neghlani PK, Rafizadeh M, Taromi FA (2011) J Hazard Mater 186:182CrossRefPubMedGoogle Scholar
  52. 52.
    Nasuha N, Hameed BH (2011) Chem Eng J 166:783CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Kaixuan Zhou
    • 1
  • Yanhui Li
    • 1
    • 2
  • Qi Li
    • 2
  • Qiuju Du
    • 2
  • Dechang Wang
    • 1
  • Kunyan Sui
    • 2
  • Cuiping Wang
    • 1
  • Hongliang Li
    • 2
  • Yanzhi Xia
    • 2
  1. 1.College of Mechanical and Electrical EngineeringQingdao UniversityQingdaoChina
  2. 2.Laboratory of Fiber Materials and Modern Textile, The Growing Base for State Key LaboratoryQingdao UniversityQingdaoChina

Personalised recommendations

Cite article

Buy options