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Synthesis, Crystal Structures, and Photocatalytic Activity of Two Nickel(II) Coordination Polymers with Flexible Bis(benzimidazol-1-yl)alkane and Polycarboxylate Ligands

  • Yong-Sheng Shi
  • Dong Liu
  • Yue-Hua Li
  • Gui-Ying DongEmail author
Article
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Abstract

Two ternary Ni(II) coordination polymers (CPs) named as: {[Ni2(L1)2(1,8-NDC)2(H2O)2]·2H2O}n (1), {[Ni2(L2)1.5(FA)(H2O)3]·3.75H2O}n (2), (L1 = 1,6-bis(5,6-dimethylbenzimidazol-1-yl)hexane, L2 = bis(5,6-dimethylbenzimidazol-1-yl)methane, 1,8-H2NDC = 1,8-naphthalenedicarboxylic acid, H4FA = 4,4′-(hexafluoroisopropylidene)diphthalic acid) were hydrothermally synthesized and characterized through physicochemical and spectroscopic methods. CP 1 features a 1D double straight-line chain and further extends into a 2D layers via π–π stacking interactions, while CP 2 shows a unique 2D (5,4,4)-connected network. The thermal stabilities, luminescence properties and photocatalytic activities of CPs 12 for methylene blue decomposition were also presented in detail.

Graphic Abstract

Two luminescent Ni(II) coordination polymers (CPs) were synthesized under hydrothermal condition. The crystal structure of CP 1 features a 1D double straight-line chain and further extends into a 2D layers via ππ stacking interactions, while CP 2 shows a unique 2D (5,4,4)-connected network. The photocatalytic experiments in the presence of catalysts CP 1 indicated higher degradation efficiency for MB solution than CP 2, and ·OH radical plays a key effect in the efficient degradation of MB.

Keywords

Bis(benzimidazol-l-yl)alkane Crystal structure Ni(II) coordination polymer Photocatalytic activity ππ stacking interaction 1,8-Naphthalenedicarboxylic acid 

Notes

Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation-Steel and Iron Foundation of Hebei Province (B2015209299).

Supplementary material

10904_2019_1228_MOESM1_ESM.doc (722 kb)
Supplementary material 1 (DOC 722 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Yong-Sheng Shi
    • 1
  • Dong Liu
    • 1
  • Yue-Hua Li
    • 1
  • Gui-Ying Dong
    • 1
    Email author
  1. 1.College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic MaterialsNorth China University of Science and TechnologyTangshanPeople’s Republic of China

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