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Effect of Zinc Content on Structural, Functional, Morphological, Resonance, Thermal and Magnetic Properties of Co1−xZnxFe2O4/PVP Nanocomposites

  • R. SagayarajEmail author
  • S. Aravazhi
  • G. Chandrasekaran
Article
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Abstract

Integrate Zinc substituted cobalt ferrites have incorporated by the Co-precipitation technique. The XRD pattern shows the formation and microstructure evolutions of nanocomposites. Cationic coordination, exchange interactions raised between the tetrahedral site in high frequency and octahedral site in the lower frequency described FTIR results. The SEM images showed that the spongy morphology with PVP matrix and fewer agglomerated grains. It exposes the grains and the range of grains recovered from 1μ to 400 nm, which is in compromise with the test of grain size of XRD. VSM study reveals that the magnetization of substances raises by incrementing the non-magnetic (Zn) material incorporated cobalt ferrite. EPR confirmed that synthesized materials exhibited ferromagnetic properties from Lande g-factor. TGA/DSC curve reports the weight loss and heat flow by endothermic absorption through exothermic emission in the ferrite. It used these materials for the potential effort like magneto-optical recording media and magnetic sensors.

Keywords

Structural Ferrites Surface morphology Magnetization Heat flow Endothermic Ferromagnetic Frequency 

Notes

Acknowledgements

We remain grateful to the Nanotechnology and Crystal Growth Lab, Department of Physics, St. Joseph’s College of Arts and Science (Autonomous), Cuddalore, Tamil Nadu, India for providing the wet lab facilities. One of the authors is R. Sagayaraj, thank Rev. Fr. Dr. S. Xavier, Department of Physics, St. Joseph’s College of Arts & Science, Cuddalore, India, for their continuous encouragement.

References

  1. 1.
    M. Saidani, W. Belkacem, J.F. Bardeau, A. Bezergheanu, L. Patout, N. Mliki, J. Alloy. Compd. 695, 183 (2017)CrossRefGoogle Scholar
  2. 2.
    L. Avazpour, M.A. Zandikhajeh, M.R. Toroghinejad, H. Shokrollahi, J. Alloys Compd. 637, 497 (2015)CrossRefGoogle Scholar
  3. 3.
    K. Nadeem, F. Zeb, M. Azeem Abid, M. Mumtaz, M. Anis ur Rehman, J. Non-Cryst Solids 400, 45 (2014)CrossRefGoogle Scholar
  4. 4.
    R.S. Yadav, J. Havlica, M. Hnatko, P. Šajgalík, C. Alexander, M. Palou, E. Bartoníčková, M. Boháč, F. Frajkorová, J. Masilko, M. Zmrzlý, L. Kalina, M. Hajdúchová, V. Enev, J. Magn. Magn. Mater. 378, 190 (2015)CrossRefGoogle Scholar
  5. 5.
    F. Gözüak, Y. Köseoğlu, A. Baykal, H. Kavas, J. Magn. Magn. Mater. 321, 2170 (2009)CrossRefGoogle Scholar
  6. 6.
    T. Tatarchuk, M. Bououdina, W. Macyk, O. Shyichuk, N. Paliychuk, I. Yaremiy, B. Al-Najar, M. Pacia, Nanoscale Res. Lett. 12, 141 (2017)CrossRefGoogle Scholar
  7. 7.
    N. Somaiah, T.V. Jayaraman, P.A. Joy, D. Das, J. Magn. Magn. Mater. 324, 2286 (2012)CrossRefGoogle Scholar
  8. 8.
    R. Roongtao, R. Baitahe, N. Vittayakorn, W. Klysubun, W.C. Vittayakorn, Integr Ferroelectr. 148, 145 (2013)CrossRefGoogle Scholar
  9. 9.
    M. Ben Ali, K. El Maalam, H. El Moussaoui, O. Mounkachi, M. Hamedoun, R. Masrour, E.K. Hlil, A. Benyoussef, J. Magn. Magn. Mater. 398, 20 (2016)CrossRefGoogle Scholar
  10. 10.
    A.G. Olabi, A. Grunwald, Mater. Des. 29, 469 (2008)CrossRefGoogle Scholar
  11. 11.
    M. Schmidt, H.L. Andersen, C. Granados-Miralles, M. Saura-Múzquiz, M. Stingaciu, M. Christensen, Dalton Transit. 45, 6439 (2016)CrossRefGoogle Scholar
  12. 12.
    S. Singhal, R. Sharma, T. Namgyal, S. Jauhar, S. Bhukal, J. Kaur, Ceram. Int. 38, 2773 (2012)CrossRefGoogle Scholar
  13. 13.
    X. Guan, X. Dong, O. Jinping, J. Magn. Magn. Mater. 320, 158 (2008)CrossRefGoogle Scholar
  14. 14.
    A.P.B. Selvadurai, V. Pazhanivelu, C. Jagadeeshwaran, R. Murugaraj, P.M. Mohammed Gazzali, Appl. Phys. A. 123, 1 (2017)Google Scholar
  15. 15.
    A.I. Veinger, A.G. Zabrodskii, T.V. Tisnek, E.N. Mokhov, Semiconductors 38, 782 (2004)CrossRefGoogle Scholar
  16. 16.
    L. Kumar, P. Kumar, M. Kar, J. Alloy. Compd. 551, 72 (2013)CrossRefGoogle Scholar
  17. 17.
    R. Elilarassi, G. Chandrasekaran, J. Mater. Sci. 28, 14536 (2017)Google Scholar
  18. 18.
    N. Sanpo, C.C. Berndt, C. Wen, J. Wang, Acta Biomater. 9, 5830 (2013)CrossRefGoogle Scholar
  19. 19.
    A. Poorbafrani, H. Salamati, P. Kameli, Ceram. Int. 41, 1603 (2015)CrossRefGoogle Scholar
  20. 20.
    R.S. Yadav, I. Kuřitka, J. Havlica, M. Hnatko, C. Alexander, J. Masilko, L. Kalina, M. Hajdúchová, J. Rusnak, V. Enev, J. Magn. Magn. Mater. 447, 48 (2018)CrossRefGoogle Scholar
  21. 21.
    R. Sagayaraj, S. Aravazhi, P. Praveen, G. Chandrasekaran, J. Mater. Sci. 29, 2151 (2018)Google Scholar
  22. 22.
    P. Sivakumar, R. Ramesh, A. Ramanand, S. Ponnusamy, C. Muthamizhchelvan, Appl. Surf. Sci. 258, 6648 (2012)CrossRefGoogle Scholar
  23. 23.
    B. Bhujun, M.T.T. Tan, A.S. Shanmugam, Results Phys. 7, 345 (2017)CrossRefGoogle Scholar
  24. 24.
    A.-H. Lu, E.L. Salabas, F. Schth, J. Magn. Nanoparticles 46, 1222 (2007)Google Scholar
  25. 25.
    M.V. Chaudhari, R.H. Kadam, S.B. Shelke, S.E. Shirsath, A.B. Kadam, D.R. Mane, Powder Technol. 259, 14 (2014)CrossRefGoogle Scholar
  26. 26.
    C. Murugesan, N. Kambhala, S. Angappane, G. Chandrasekaran, J. Magn. Magn. Mater. 443, 334 (2017)CrossRefGoogle Scholar
  27. 27.
    A. Ghasemi, S. Ekhlasi, M. Mousavinia, J. Magn. Magn. Mater. 354, 136 (2014)CrossRefGoogle Scholar
  28. 28.
    G. Barrera, M. Coisson, F. Celegato, S. Raghuvanshi, F. Mazaleyrat, S.N. Kane, P. Tiberto, J. Magn. Magn. Mater. 456, 372 (2018)CrossRefGoogle Scholar
  29. 29.
    M.A. Gabal, A.A. Al-Juaid, S.M. Al-Rashed, M.A. Hussein, F. Al-Marzouki, J. Magn. Magn. Mater. 426, 670 (2017)CrossRefGoogle Scholar
  30. 30.
    W. Ma, L. Chen, J. Dai, C. Li, Y. Yan, RSC Adv. 6, 48875 (2016)CrossRefGoogle Scholar
  31. 31.
    S.D. Bhame, P.A. Joy, J. Magn. Magn. Mater. 447, 150 (2018)CrossRefGoogle Scholar
  32. 32.
    R. Sridhar, D. Ravinder, K. VijayaKumar, Adv. Mater. Phys. Chem. 2, 192 (2012)CrossRefGoogle Scholar
  33. 33.
    Ct Singh, S. Jauhar, V. Kumar, J. Singh, S. Singhal, Mater. Chem. Phys. 156, 188 (2015)CrossRefGoogle Scholar
  34. 34.
    R. Arulmurugan, G. Vaidyanathan, S. Sendhilnathan, B. Jeyadevan, J. Magn. Magn. Mater. 303, 131 (2006)CrossRefGoogle Scholar
  35. 35.
    B. Chandra Sekhar, G.S.N. Rao, O.F. Caltun, B. Dhana Lakshmi, B. Parvatheeswara Rao, P.S.V. Subba Rao, J. Magn. Magn. Mater. 398, 59 (2016)CrossRefGoogle Scholar
  36. 36.
    M. Tzvetkov, M. Milanova, Z. Cherkezova-Zheleva, I. Spassova, E. Valcheva, J. Zaharieva, I. Mitov, Acta Chim. Slov. 64, 299 (2017)CrossRefGoogle Scholar
  37. 37.
    R. Guicheteau, J.-L. Bobet, T. Miyasaki, A. Kawasaki, Y. Lu, J.-F. Silvain, J. Alloys Compd. 724, 711 (2017)CrossRefGoogle Scholar
  38. 38.
    A. Goyal, S. Bansal, V. Kumar, J. Singh, S. Singhal, Appl. Surf. Sci. 324, 877 (2015)CrossRefGoogle Scholar
  39. 39.
    N. Sanpo, C.C. Berndt, J. Wang, J. Appl. Phys. 112, 084333 (2012)CrossRefGoogle Scholar
  40. 40.
    A.V. Raut, R.S. Barkule, D.R. Shengule, K.M. Jadhav, J. Magn. Magn. Mater. 358–359, 87 (2014)CrossRefGoogle Scholar
  41. 41.
    R. Sagayaraj, S. Aravazhi, C. Selva kumar, S. Senthil kumar, G. Chandrasekaran, SN Appl. Sci. 1, 271 (2019)CrossRefGoogle Scholar
  42. 42.
    V.S. Kiran, S. Sumathi, J. Magn. Magn. Mater. 421, 113 (2017)CrossRefGoogle Scholar
  43. 43.
    L. Khanna, N.K. Verma, J. Magn. Magn. Mater. 336, 1 (2013)CrossRefGoogle Scholar
  44. 44.
    M.K. Lima-Tenório, E.T. Tenório-Neto, F.P. Garcia, C.V. Nakamura, M.R. Guilherme, E.C. Muniz, E.A.G. Pineda, A.F. Rubira, J. Mol. Liquids 210, 100 (2015)CrossRefGoogle Scholar
  45. 45.
    R. Sagayaraj, S. Aravazhi, G. Chandrasekaran, J. Supercond. Novel Magn. 31, 603 (2018)CrossRefGoogle Scholar
  46. 46.
    N.N.S. Murthy, M.G. Natera, S.I. Youssef, R.J. Begum, Yafet-Kittel angles in zinc–nickel ferrites. Phys. Rev. B 181, 969 (1969)CrossRefGoogle Scholar
  47. 47.
    M.H. Alimuddin, S. Kumar, S.E. Shirsath, R.K. Kotnala, J. Shah, R. Kumar, Mater. Chem. Phys. 139, 364 (2013)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.PG& Research Department of PhysicsSt. Joseph’s College of Arts and Science (Autonomous)CuddaloreIndia
  2. 2.Department of PhysicsArignar Anna Arts CollegeVillupuramIndia
  3. 3.Department of PhysicsPondicherry UniversityPondicherryIndia

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