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Synthesis and Application of Fe3O4@SiO2@Carboxyl-Terminated PAMAM Dendrimer Nanocomposite for Heavy Metal Removal

  • Armin Zarei
  • Shahab Saedi
  • Farzad seidi
Article
  • 6 Downloads

Abstract

In present study Fe3O4 magnetic nanoparticles (MNPs) were prepared using co-precipitation method. Prepared MNPs were coated by SiO2 layer via sol–gel process. Subsequent Michel-addition reaction and amidation were used to synthesize G3 polyamidoamine dendrimer on prepared Fe3O4@SiO2. Fe3O4@SiO2@ PAMAM dendrimer was reacted with monochloroacetic acid for preparation of final Fe3O4@SiO2@Carboxyl-terminated PAMAM dendrimer nanocomposite. Successful synthesis of Fe3O4@SiO2@Carboxyl-terminated PAMAM dendrimer nanocomposite was confirmed by FTIR spectroscopy and CHN analysis. The nanostructure of prepared composite MNPs was investigated using TEM. X-ray diffraction pattern and thermal stability of pure MNPs and composite MNPs were studied using XRD and TGA analysis respectively. Unmodified and modified MNPs were used as adsorbent for the removal of Cu(II), Cd(II) and Pb(II) form aqueous solutions. It was observed that the modification of MPNs enhances the ability of MPNs for removal of these heavy metals significantly. Also it was shown that this modification enhances the accessibility of MNPs to heavy metal ions at low concentrations.

Keywords

Magnetic nanoparticles Polyamidoamine dendrimer Cu(II) Cd(II) Pb(II) 

References

  1. 1.
    L. Hui et al., Adsorption behavior and adsorption mechanism of Cu(II) ions on amino-functionalized magnetic nanoparticles. Trans. Nonferrous Met. Soc. China 23(9), 2657–2665 (2013)CrossRefGoogle Scholar
  2. 2.
    A.N. Baghani et al., One-pot synthesis, characterization and adsorption studies of amine-functionalized magnetite nanoparticles for removal of Cr(VI) and Ni(II) ions from aqueous solution: kinetic, isotherm and thermodynamic studies. J. Environ. Health Sci. Eng. 14(1), 11 (2016)CrossRefGoogle Scholar
  3. 3.
    F. Fu, Q. Wang, Removal of heavy metal ions from wastewaters: a review. J. Environ. Manage. 92(3), 407–418 (2011)CrossRefGoogle Scholar
  4. 4.
    K. Chen et al., Removal of cadmium and lead ions from water by sulfonated magnetic nanoparticle adsorbents. J. Colloid Interface Sci. 494, 307–316 (2017)CrossRefGoogle Scholar
  5. 5.
    X. Bai et al., Design of multi-N-functional magnetic PVA microspheres for the rapid removal of heavy metal ions with different valence. Desalin. Water Treat. 56(7), 1809–1819 (2015)CrossRefGoogle Scholar
  6. 6.
    S. Hanif, A. Shahzad, Removal of chromium(VI) and dye Alizarin Red S (ARS) using polymer-coated iron oxide (Fe3O4) magnetic nanoparticles by co-precipitation method. J. Nanopart. Res. 16(6), 2429 (2014)CrossRefGoogle Scholar
  7. 7.
    S. Zhang et al., Thiol modified Fe3O4@ SiO2 as a robust, high effective, and recycling magnetic sorbent for mercury removal. Chem. Eng. J. 226, 30–38 (2013)CrossRefGoogle Scholar
  8. 8.
    S. Venkateswarlu, S.H. Kumar, N. Jyothi, Rapid removal of Ni(II) from aqueous solution using 3-mercaptopropionic acid functionalized bio magnetite nanoparticles. Water Resour. Ind. 12, 1–7 (2015)CrossRefGoogle Scholar
  9. 9.
    M. Moazzen et al., Multi-walled carbon nanotubes modified with iron oxide and silver nanoparticles (MWCNT-Fe3O4/Ag) as a novel adsorbent for determining PAEs in carbonated soft drinks using magnetic SPE-GC/MS method. Arab. J. Chem. (2018).  https://doi.org/10.1016/j.arabjc.2018.03.003 Google Scholar
  10. 10.
    Y. Wei et al., Synthesis of Fe3O4 nanoparticles and their magnetic properties. Proced. Eng. 27, 632–637 (2012)CrossRefGoogle Scholar
  11. 11.
    M. Takafuji et al., Preparation of poly(1-vinylimidazole)-grafted magnetic nanoparticles and their application for removal of metal ions. Chem. Mater. 16(10), 1977–1983 (2004)CrossRefGoogle Scholar
  12. 12.
    J. CHANG et al., Fabrication of poly(γ-glutamic acid)-coated Fe3O4 magnetic nanoparticles and their application in heavy metal removal. Chin. J. Chem. Eng. 21(11), 1244–1250 (2013)CrossRefGoogle Scholar
  13. 13.
    E. Ghasemi, A. Heydari, M. Sillanpää, Superparamagnetic Fe3O4@ EDTA nanoparticles as an efficient adsorbent for simultaneous removal of Ag(I), Hg(II), Mn(II), Zn(II), Pb(II) and Cd(II) from water and soil environmental samples. Microchem. J. 131, 51–56 (2017)CrossRefGoogle Scholar
  14. 14.
    M.E. Mahmoud, M.S. Abdelwahab, E.M. Fathallah, Design of novel nano-sorbents based on nano-magnetic iron oxide–bound-nano-silicon oxide–immobilized-triethylenetetramine for implementation in water treatment of heavy metals. Chem. Eng. J. 223, 318–327 (2013)CrossRefGoogle Scholar
  15. 15.
    X. Xin et al., Highly efficient removal of heavy metal ions by amine-functionalized mesoporous Fe3O4 nanoparticles. Chem. Eng. J. 184, 132–140 (2012)CrossRefGoogle Scholar
  16. 16.
    J. Wang et al., Amino-functionalized Fe3O4@ SiO2 core–shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal. J. Colloid Interface Sci. 349(1), 293–299 (2010)CrossRefGoogle Scholar
  17. 17.
    A. Masoumi, M. Ghaemy, A.N. Bakht, Removal of metal ions from water using poly (MMA-co-MA)/modified-Fe3O4 magnetic nanocomposite: isotherm and kinetic study. Ind. Eng. Chem. Res. 53(19), 8188–8197 (2014)CrossRefGoogle Scholar
  18. 18.
    C.-M. Chou, H.-L. Lien, Dendrimer-conjugated magnetic nanoparticles for removal of zinc(II) from aqueous solutions. J. Nanopart. Res. 13(5), 2099–2107 (2011)CrossRefGoogle Scholar
  19. 19.
    W. Stöber, A. Fink, E. Bohn, Controlled growth of monodisperse silica spheres in the micron size range. J. Colloid Interface Sci. 26(1), 62–69 (1968)CrossRefGoogle Scholar
  20. 20.
    Y. Huang, A.N. Fulton, A.A. Keller, Simultaneous removal of PAHs and metal contaminants from water using magnetic nanoparticle adsorbents. Sci. Total Environ. 571, 1029–1036 (2016)CrossRefGoogle Scholar
  21. 21.
    F.E. Peer, N. Bahramifar, H. Younesi, Removal of Cd(II), Pb(II) and Cu(II) ions from aqueous solution by polyamidoamine dendrimer grafted magnetic graphene oxide nanosheets. J. Taiwan Inst. Chem. Eng. 87, 225–240 (2018)CrossRefGoogle Scholar
  22. 22.
    A. Zhang et al., Preparation of anti-fouling silicone elastomers by covalent immobilization of carboxybetaine. RSC Adv. 5(107), 88456–88463 (2015)CrossRefGoogle Scholar
  23. 23.
    L.P. Lingamdinne et al., Biogenic reductive preparation of magnetic inverse spinel iron oxide nanoparticles for the adsorption removal of heavy metals. Chem. Eng. J. 307, 74–84 (2017)CrossRefGoogle Scholar
  24. 24.
    R.X. Li et al., Preparation and characterization of cross-linked β-cyclodextrin polymer/Fe3O4 composite nanoparticles with core-shell structures. Chin. Chem. Lett. 22(2), 217–220 (2011)CrossRefGoogle Scholar
  25. 25.
    J. Qu et al., A novel sensor based on Fe3O4 nanoparticles–multiwalled carbon nanotubes composite film for determination of nitrite. Sens. Bio-Sens. Res. 3, 74–78 (2015)CrossRefGoogle Scholar
  26. 26.
    A.S. Ertürk, G. Elmacı, PAMAM dendrimer functionalized manganese ferrite magnetic nanoparticles: microwave-assisted synthesis and characterization. J. Inorg. Organomet. Polym. Mater. 28, 1–8 (2018)CrossRefGoogle Scholar
  27. 27.
    M. Huysal, M. Şenel, Dendrimer functional hydroxyapatite nanoparticles generated by functionalization with siloxane-cored PAMAM dendrons. J. Colloid Interface Sci. 500, 105–112 (2017)CrossRefGoogle Scholar
  28. 28.
    U. Kurtan, A. Baykal, H. Sözeri, Synthesis and characterization of sulfamic-acid functionalized magnetic Fe3O4 nanoparticles coated by poly(amidoamine) dendrimer. J. Inorg. Organomet. Polym. Mater. 24(6), 948–953 (2014)CrossRefGoogle Scholar
  29. 29.
    M. Tajabadi, M.E. Khosroshahi, S. Bonakdar, An efficient method of SPION synthesis coated with third generation PAMAM dendrimer. Colloids Surf. A 431, 18–26 (2013)CrossRefGoogle Scholar
  30. 30.
    S. Venkateswarlu et al., A novel green synthesis of Fe3O4 magnetic nanorods using Punica Granatum rind extract and its application for removal of Pb(II) from aqueous environment. Arab. J. Chem. (2014).  https://doi.org/10.1016/j.arabjc.2014.09.006 Google Scholar
  31. 31.
    Pan, B.-f., F., Gao, H. Gu, Dendrimer modified magnetite nanoparticles for protein immobilization. J. Colloid Interface Sci. 284(1), 1–6 (2005)CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemistry, Sanandaj BranchIslamic Azad UniversitySanandajIran
  2. 2.Department of Materials Science and Engineering, School of Molecular Science and EngineeringVidyasirimedhi Institute of Science and TechnologyRayongThailand

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