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Synthesis of Hybrid Aminated Polymers with Ag Sensitive to Electromagnetic Pulses, as Potential Inhibitors or Stimulators of Cell Growth in the Central Nervous System

  • Lidia Ma. Gómez
  • Ma. Guadalupe Olayo
  • Maribel González-Torres
  • Juan Morales
  • Roberto Olayo
  • Ma. Rosario Mejía-Cuero
  • Guillermo J. Cruz
Article

Abstract

Hybrid compounds of polypyrrole and polyallylamine doped with iodine and silver (PPy/I/Ag) (PAl/I/Ag) were synthesized combining polymerization and metallic plasma ablation simultaneously with the objective to build hybrid materials sensitive to electromagnetic pulses. Both compounds were obtaining as films with similar chemical structures, low content of Ag atoms, 0.03–0.41% and average thicknesses of 79.5 and 35.2 µm, respectively. The electrical conductivity of the hybrid compounds from 35 to 100 °C was between 10− 8 and 10− 4 S/m with activation energy in the − 0.06 to 3.02 eV interval with 2 semiconductor and 1 conductor mechanisms of charge transference due to the influence of the metallic particles in the polymers. The hybrid compounds showed similar complex electromagnetic absorption in the 200–400 nm wavelength interval, increasing and decreasing with four absorption mechanisms, which suggest internal modifications in the electronic orbitals. The activation energy has 3 values in the UV and 2 in the Visible interval, from − 14.3 to 0.3 eV, suggesting 5 different absorption mechanisms, which indicate that these polymers are sensitive to electromagnetic absorption in the wavelength interval studied.

Keywords

Polyallylamine Polypyrrole Silver Plasma UV–Vis absorption 

Notes

Acknowledgements

The authors thank CONACyT for the partial support to this work with the FC-152 project and for the doctoral scholarship to Ma. Rosario Mejia-Cuero; and to PROMEP for the pos-doctoral fellowships to Lidia Ma. Gómez and Maribel González-Torres.

References

  1. 1.
    E. Colín, M.G. Olayo, G.J. Cruz, L. Carapia, J. Morales, R. Olayo, Prog. Org. Coat. 64, 322 (2009)CrossRefGoogle Scholar
  2. 2.
    G.J. Cruz, R. Mondragón-Lozano, A. Diaz-Ruiz, J. Manjarrez, R. Olayo, H. Salgado-Ceballos, M.G. Olayo, J. Morales, A.L. Alvarez-Mejía, A. Morales, M. Méndez-Armenta, N. Plascencia, M.C. Fernandez, C. Ríos, J. Mater. Sci. Mater. Med. 23, 2583 (2012)CrossRefPubMedGoogle Scholar
  3. 3.
    M. González-Torres, G.J. Cruz, M.G. Olayo, L.M. Gómez, O.G. López, V. Sánchez-Mendieta, C. De Jesús, Superficies y Vacío 25, 179 (2012)Google Scholar
  4. 4.
    G.J. Cruz, L.M. Gómez, M. Gonzalez-Torres, F. Gonzalez-Salgado, R. Basurto, E. Colín, J.C. Palacios, M.G. Olayo, J. Mater. Sci. Lett. 52, 1005 (2017)CrossRefGoogle Scholar
  5. 5.
    N.K. Manninen, S. Calderon, I. Carvalho, M. Henriques, A. Cavaleiro, S. Carvalho, Appl. Surf. Sci. 377, 283 (2016)CrossRefGoogle Scholar
  6. 6.
    P. Boomi, H.G. Prabu, P. Manisankar, S. Ravikumar, Appl. Surf. Sci. 300, 66 (2014)CrossRefGoogle Scholar
  7. 7.
    A. Saad, E. Cabet, A. Lilienbaum, S. Hamadi, M. Abderrabba, M.M. Chehimi, J. Taiwan Inst. Chem. Eng. (2017).  https://doi.org/10.1016/j.jtice.2017.09.024 CrossRefGoogle Scholar
  8. 8.
    S. Daikh, F.Z. Zeggai, A. Bellil, A. Benyoucef, J. Phys. Chem. Solids (2018).  https://doi.org/10.1016/j.jpcs.2018.02.003 CrossRefGoogle Scholar
  9. 9.
    K. Yamani, R. Berenguer, A. Benyoucef, E. Morallón, J. Therm. Anal. Calorim. (2018).  https://doi.org/10.1007/s10973-018-7347-z CrossRefGoogle Scholar
  10. 10.
    P. Hlídek, H. Biederman, A. Choukourov, D. Slavínská, Plasma Process. Polym. 6, 34 (2009)CrossRefGoogle Scholar
  11. 11.
    E. Ozkazanc, H. Ozkazanc, O. Gundogdu, J. Inorg. Organomet. Polym. (2018).  https://doi.org/10.1007/s10904-018-0887-7 CrossRefGoogle Scholar
  12. 12.
    S. Roy, S. Mishra, P. Yogi, S.K. Saxena, P.R. Sagdeo, R. Kumar, J. Inorg. Organomet. Polym. (2017).  https://doi.org/10.1007/s10904-017-0680-z CrossRefGoogle Scholar
  13. 13.
    L. Ghasemi-Mobarakeh, M.P. Prabhakaran, M. Morshed, M.H. Nasr-Esfahani, H. Baharvand, S. Kiani, S.S. Al-Deyab, S. Ramakrishna, J. Tissue Eng. Regen. Med. 5, 17 (2011)CrossRefGoogle Scholar
  14. 14.
    D. Peer, J.M. Karp, S. Hong, O.C. Farokhzad, R. Margalit, R. Langer, Nat. Nanotechnol. 2, 751 (2007)CrossRefPubMedGoogle Scholar
  15. 15.
    S. Benyakhou, A. Belmokhtar, A. Zehhaf, A. Benyoucef, J. Mol. Struct. 1150, 580 (2017)CrossRefGoogle Scholar
  16. 16.
    S. Benykhlef, A. Bekhoukh, R. Berenguer, A. Benyoucef, E. Morallon, Colloid. Polym. Sci. (2016).  https://doi.org/10.1007/s00396-016-3955-y CrossRefGoogle Scholar
  17. 17.
    F. Chouli, I. Radja, E. Morallon, A. Benyoucef, Polym. Compos. (2015).  https://doi.org/10.1002/pc.23837 CrossRefGoogle Scholar
  18. 18.
    F. González-Salgado, M.G. Olayo, G. García-Rosales, L.M. Gómez, M. González-Torres, G.J. Cruz, Appl. Phys. A 122, 545 (2016)CrossRefGoogle Scholar
  19. 19.
    J.E. Osorio, Compósitos polianilina/alcohol polivinílico codopados con ácido clorhidríco y ácido canforsulfónico (MS thesis). Instituto Politécnico Nacional, México D.F., 2009, pp. 67Google Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Lidia Ma. Gómez
    • 1
    • 2
    • 3
  • Ma. Guadalupe Olayo
    • 1
  • Maribel González-Torres
    • 1
    • 3
  • Juan Morales
    • 3
  • Roberto Olayo
    • 3
  • Ma. Rosario Mejía-Cuero
    • 1
    • 4
  • Guillermo J. Cruz
    • 1
  1. 1.Departamento de FísicaInstituto Nacional de Investigaciones NuclearesOcoyoacacMexico
  2. 2.División de Estudios de Posgrado e InvestigaciónTecnológico Nacional de México / Instituto Tecnológico de TolucaMetepecMexico
  3. 3.Departamento de FísicaUniversidad Autónoma Metropolitana IztapalapaMexico CityMexico
  4. 4.Facultad de IngenieríaUniversidad Autónoma del Estado de México Cerro de CoatepecTolucaMexico

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