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Luminescent Pr(III)-Based Coordination Polymer: Syntheses, Structures, N2 and CO2 Adsorption Properties

  • Qiang Liu
  • Yuqi LiuEmail author
  • Qingqing Zhang
  • Xinying Wang
  • Wei LiEmail author
Original Paper
  • 14 Downloads

Abstract

A new Pr(III)-based metal organic framework with formula {[Pr2(C8H3O6N)(SO4)2]·5H2O}n was hydrothermally synthesized and characterized by techniques of single crystal X-ray diffraction, infrared spectra (IR), thermogravimetric analysis (TGA), elemental analysis, powder X-ray diffraction (PXRD), and luminescent measurements. X-ray crystal structure analyses reveal that complex 1 is binuclear structure and all Pr(III) atoms show a coordination number of nine with a tricapped trigonal prismatic coordination geometry. Throughout the molecular structure, this lanthanide metal–organic frameworks exhibits a 3D architecture built by the 1D double-stranded chains of Pr ions linked by the 5-nitroisophthalic acid ligand and 2D Pr–SO42− grid. In addition, the fluorescence, nitrogen adsorption properties and carbon dioxide adsorption properties of complex 1 were also investigated. The results indicate that the complex is not only a luminescent and mesoporous material, but also a potential material for selective absorption of carbon dioxide.

Keywords

Pr-based compound Single crystal structure Luminescence Carbon dioxide adsorption Nitrogen adsorption 

Notes

Supplementary material

10876_2019_1667_MOESM1_ESM.docx (194 kb)
Supplementary material 1 (DOCX 193 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Faculty of ScienceKunming University of Science and TechnologyKunmingPeople’s Republic of China
  2. 2.The State Key Laboratory of Complex Nonferrous Metal Resources Clean UtilizationKunmingPeople’s Republic of China
  3. 3.Faculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunmingPeople’s Republic of China

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