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Two New NIR Luminescencent Er(III) Coordination Polymers with Potential Application Optical Amplification Devices

  • Yasemin AcarEmail author
  • Mustafa Burak Coban
  • Elif Gungor
  • Hulya KaraEmail author
Original Paper
  • 9 Downloads

Abstract

Two new Er(III)-cluster-based coordination compounds have been synthesized by hydrothermal technique using monosodium 2-sulfoterephthalate (2-stp) and 4,4′-bipyridyl (4,4′-bpy) ligands. Depending on synthetic procedure, monomeric and polymeric Er(III) products, isolated as {[Er(2-stp)2(H2O)6]0.2(4,4′-bipy)0.4(H2O)}, 1 and {[Er(2-stp)(4,4′-bipy)(H2O)](H2O)}n, 2. Both compounds have been characterized by elemental analysis, FT-IR, UV–visible and single-crystal X-ray diffraction and solid-state photoluminescence. The X-ray structure analyses show that Er atom is surrounded by two 2-stp ligands which have monodentate connection mode forming a monomeric structure in compound 1. However, in compound 2, Er atoms are coordinated by four bridging 2-stp ligands which adopt a hexadentate connection mode to form a central symmetrically dimeric building unit. The photoluminescence spectrums of the compounds have been exhibited intense blue emission for 1 and cyan-blue emission for 2. The band observed in NIR region at 1532 nm (for 1) and 1540 nm (for 2) are the typical ErIII emission. The excellent NIR luminescent properties, indicating their promising potential applications as gain medium materials in optical amplification devices.

Keywords

Er(III) cluster X-ray structure Photoluminescence 

Notes

Acknowledgements

The authors thanks to the Research Funds of Balikesir University (Grant No. BAP-2017/183) for the financial support, Dr. Muhittin Aygun and Dokuz Eylül University (Grant No. 2010.KB.FEN.13) for the use of the Agilent Xcalibur Eos diffractometer and also to BUBTAM (Balikesir University Science and Technology Application and Research Center) for the use of the Photoluminescence Spectrometer.

Supplementary material

10876_2019_1623_MOESM1_ESM.docx (83 kb)
Supplementary material 1 (DOCX 83 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of Physics, Faculty of Science and ArtBalikesir UniversityBalıkesirTurkey
  2. 2.Center of Science and Technology Application and ResearchBalikesir UniversityBalıkesirTurkey
  3. 3.Department of Energy, Graduate School of Natural and Applied SciencesMugla Sıtkı Kocman UniversityMuglaTurkey

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