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Journal of Cluster Science

, Volume 30, Issue 6, pp 1501–1510 | Cite as

Bis((pyridine-2-yl)-1,2,4-triazol-5-yl) Methane as Ligand in Three Zn(II) Complexes: Synthesis, Crystal Structures and Luminescent Properties

  • Yan Cao
  • Jian-fang Liu
  • Xing-mei Qin
  • Yan Zhang
  • Hai-Ye LiEmail author
  • He-Dong Bian
  • Han-Fu Liu
  • Fu-Ping HuangEmail author
Original Paper
  • 60 Downloads

Abstract

Reactions of the bis((pyridine-2-yl)-1,2,4-triazol-5-yl)methane (H2L) with Zn(NO3)2·6H2O and ZnCl2 conditions afforded three new Zn(II) complexes, namely, {[Zn3L′2(H2O)6]·2NO3} (1), [Zn4L2Cl4(H2O)2] (2) and [Zn6L4(CH3OH)4(NO3)4] (3). Notably in 1, the methylene group in L was in situ oxidized to a rigid ketone group in L′ (here, H2L′ = bis((pyridine-2-yl)-1,2,4-triazol-5-yl)ketone). The three Zn(II) complexes were synthesized under solvothermal conditions and characterized by techniques of Elemental analysis, Fourier transform infrared spectroscopy, Powder X-ray diffraction and single-crystal X-ray diffraction analysis. In addition, the thermogravimetric properties and the luminescent properties of 13 were investigated.

Keywords

Clusters Methylene group In situ oxidation Luminescent properties 

Notes

Funding

We gratefully acknowledge the National Nature Science Foundation of China (21861005), the Guangxi Natural Science Foundation of China (2016GXNSFFA380010), the Foundation of Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources (CMEMR2015-A11, CMEMR2016-A11).

Compliance with Ethical Standards

Conflict of interest

No potential conflict of interest was reported by the authors.

Supplementary material

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Supplementary material 1 (CIF 19 kb)
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Supplementary material 2 (CIF 20 kb)
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Supplementary material 3 (CIF 595 kb)
10876_2019_1593_MOESM4_ESM.pdf (180 kb)
Supplementary material 4 (PDF 180 kb)
10876_2019_1593_MOESM5_ESM.pdf (141 kb)
Supplementary material 5 (PDF 140 kb)
10876_2019_1593_MOESM6_ESM.pdf (234 kb)
Supplementary material 6 (PDF 234 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Yan Cao
    • 1
  • Jian-fang Liu
    • 1
  • Xing-mei Qin
    • 1
  • Yan Zhang
    • 1
  • Hai-Ye Li
    • 2
    Email author
  • He-Dong Bian
    • 1
  • Han-Fu Liu
    • 1
  • Fu-Ping Huang
    • 1
    Email author
  1. 1.State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and PharmacyGuangxi Normal UniversityGuilinPeople’s Republic of China
  2. 2.School of Chemistry and PharmacyGuangxi Normal UniversityGuilinPeople’s Republic of China

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