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Journal of Cluster Science

, Volume 29, Issue 6, pp 1039–1049 | Cite as

Novel Branched Template for the Use in Construction of [CuNCS]n Polypseudorotaxane: Synthesis, Structures, and Photocatalytic Properties

  • Min Xiao
  • Ya-Bin Lu
  • Zi-Yan Li
  • Yun-Yin Niu
Original Paper
  • 47 Downloads

Abstract

Three novel extended supramolecular structures based on pseudohalides (SCN) and the flexible cationic template 1, n-bis(4-aminopyridine)alkane cations(n = 2–4), namely {(bape)0.5[Cu(SCN)2]}n (bape = 1, 2-bis(4-aminopyridine)ethane) (1), {(bapp) [Cu2(SCN)4]}n (bapp = 1, 3-bis(4-aminopyridine)propane) (2),{(bapb)0.5[Cu(SCN)2]}n (bapb = 1, 4-bis(4-aminopyridine)butane) (3) have been synthesized and characterized by IR spectroscopy, thermal gravimetric analysis, X-ray Powder Diffraction (PXRD), UV–Visdiffuse reflectance spectra and single-crystal X-ray diffraction in the solid state. Compounds 1 and 3 exhibit infinite two-dimensional polypseudorotaxane architecture. In compound 2, the cationic template bapp2+ induced [Cu2(SCN)4]2− cluster unit to generate a 3D coordination framework. The structural diversities show that the branched cationic template should very likely be excellent candidates to construct higher dimensional threading supramolecular architectures. In addition, the optical band gap, photocatalytic and the structure–property relationship of compounds 1–3 were also investigated.

Keywords

Template Polypseudorotaxane Photocatalytic Supramolecular polymers 

Notes

Acknowledgements

We gratefully acknowledge the financial support by the National Natural Science Foundation of China (No. 21671177).

Supplementary material

10876_2018_1415_MOESM1_ESM.docx (168 kb)
Supplementary material 1 (DOCX 167 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Chemistry and Molecular EngineeringZhengzhou UniversityZhengzhouPeople’s Republic of China

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