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Supramolecular Assembly Created Through Weak Non-covalent C–H···Cl and C–H···O Interaction in the Crystal Structure of Homo-Binuclear Ru(II) Complex

  • Sunshine D. KurbahEmail author
  • D. L. Buam
  • D. Kharbani
  • R. A. Lal
Brief Communication

Abstract

In this article, we described the structural studies of Ru(II) compound containing pyrazole ligands. On the basis of structural analysis, the complex exhibit non-covalent C–H···Cl interaction. Hirshfeld surface analysis showed that the structure of compound is mainly characterized by Cl···H, and O···H contacts but other contribution was also observed from Cl···O and C···H contacts. DFT calculation show that theoretical bond lengths and bond angles are in good agreements with the experimental values obtained from single crystal x-ray crystallography.

Graphic Abstract

The complex exhibit weak non-covalent C–H···Cl interaction. Figure showing 2D dimensional non-covalent C–H···Cl interactions supramolecular assembly.

Keywords

Hirshfeld surface Structural studies Weak interaction and supramolecular 

Notes

Acknowledgements

Sunshine D. Kurbah would like to thank UGC NFST, New Delhi for providing financial assistance and Computer Centre, North Eastern Hill University, Shillong, for providing high performance computing facilities.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Centre for Advanced Studies in ChemistryNorth-Eastern Hill UniversityShillongIndia
  2. 2.Chemistry Department, Shillong CollegeNorth-Eastern Hill UniversityShillongIndia

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