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Crystal Structures of Spiro Derivatives Including 6,10-Dioxaspiro[4.5]decane-7,9-dione Group and Their Spectral Studies

  • Wulan ZengEmail author
  • Xia Wang
Original Paper

Abstract

A new intermediate, C22H30N2O8 (J0) was attained by reaction of 6,10-dioxaspiro[4.5]decane-7,9-dione with 1,1-dimethoxy-n,n-dimethyl-methanamin in ethanol. The two oxaspirocyclic compounds C16H17NO4 (J1) and C16H17NO4 (J2) were prepared by adding 2-methylbenzenamine and 3-methylbenzenamine into to the ethanol solution of J0, respectively. Two crystals (J0 and J1) were determined by single-crystal X-ray diffraction. The compound of J0 includes one (C5 H13 N2)+ cation and one (C17 H17 O8) anion, which indicates it is a salt. There is no classical hydrogen bonds in J0. However, there is one kind of N–H⋅⋅⋅O intramolecular interactions and one kind of C–H⋅⋅⋅O intermolecular interactions in J1. In addition, the fluorescence spectra of J1 and J2 in dilute ethanol were studied, which they exhibit purplish red emission and reddish purple emission, respectively.

Graphical Abstract

A new intermediate, C22H30N2O8 (J0) was attained by reaction of 6,10-dioxaspiro[4.5]decane-7,9-dione with 1,1-dimethoxy-n,n-dimethyl-methanamin in ethanol. The two oxaspirocyclic compounds C16H17NO4 (J1) and C16H17NO4 (J2) were prepared by adding 2-methylbenzenamine and 3-methylbenzenamine into to the ethanol solution of J0, respectively.

Keywords

Crystal structure 6,10-Dioxaspiro[4.5]decane-7,9-dione Oxaspirocyclic compound Fluorescence spectra 

Notes

Acknowledgements

Financial assistance received from the Natural Science Foundation of Shandong Province (Grant No. ZR2017BEE038).

Supplementary material

10870_2018_746_MOESM1_ESM.pdf (119 kb)
Supplementary material 1 (PDF 118 KB)
10870_2018_746_MOESM2_ESM.pdf (106 kb)
Supplementary material 2 (PDF 105 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemistry, Chemical Engineering and Environmental EngineeringWeifang UniversityWeifangChina

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