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Enhancement in the adhesion properties of polycarbonate surfaces through chemical functionalization with organosilicon coupling agents

  • Jin Woong Lee
  • Jun Hyuk HeoEmail author
  • Byoungsang Lee
  • Hui Hun Cho
  • Taekyung KimEmail author
  • Jung Heon LeeEmail author
Article
  • 80 Downloads

Abstract

Although polycarbonate (PC) materials are well known to have poor adhesion to other surfaces, few studies have been conducted on the improvement of their adhesive properties via surface chemical functionalization. Herein, we report the enhancement in the adhesion properties of PC by adapting two silane coupling agents, namely (3-glycidoxypropyl) methyldiethoxysilane (GPTMS) and (3-aminopropyl) trimethoxysilane (APTMS), on the surface. We tested the adhesion with an epoxy-based adhesive consisting of bisphenol A diglycidyl ether (BADGE) and trientine (trien). The chemical interaction between the amine groups of the hardener (trien) and the epoxy rings of an epoxy-functionalized PC (PC-GPTMS) sample surface was observed with X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. We found that the amine-functionalized PC (PC-APTMS) can also form crosslinked polymeric structures with the BADGE after curing. Compared to the bare PC, an increase in the shear strength of up to 168% and 163% was observed from the PC-GPTMS and PC-APTMS, respectively. In contrast, the ultraviolet-ozone (UVO) and O2 plasma-treated samples showed a negligible increase in adhesion strength. These results strongly suggest that the chemical functionalization of PC substrates with coupling agents significantly enhances the adhesion properties of PCs.

Notes

Acknowledgements

This research was supported by the Basic Science Research Program of the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2019R1A6A1A03033215) and GRRC program of Gyeonggi Province (Grant No. GRRC Sungkyunkwan 2017-B01).

Supplementary material

10854_2019_2128_MOESM1_ESM.docx (138 kb)
Supplementary material 1 (DOCX 137 kb)

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of Advanced Materials Science and EngineeringSungkyunkwan University (SKKU)Suwon-siRepublic of Korea
  2. 2.SKKU Advanced Institute of Nanotechnology (SAINT)Sungkyunkwan University (SKKU)Suwon-siRepublic of Korea
  3. 3.Advanced Materials Technology Research CenterSungkyunkwan University (SKKU)Suwon-siRepublic of Korea
  4. 4.Department of Materials Science and EngineeringHongik UniversitySejongRepublic of Korea

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