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A detailed study of magnetization and magnetoelectric effect in P(VDF-TrFe) based SmFeO3 nanocomposites

  • Anju AhlawatEmail author
  • Azam Ali Khan
  • Pratik Deshmukh
  • Malvika Tripathi
  • Mandar M. Shirolkar
  • S. SatapathyEmail author
  • R. J. Choudhary
  • A. K. Karnal
Article
  • 26 Downloads

Abstract

In this study, we investigate magnetoelectric (ME) properties in nanocomposite films (P(VDF-TrFe))/SmFeO3 consist of ferroelectric copolymer, poly(vinylindene fluoride-trifluoroethylene) (P(VDF-TrFe)) and magnetic SmFeO3 nanoparticles. Comparative magnetization vs magnetic field hysteresis loops for un-poled and electric field poled (P(VDF-TrFe))/SmFeO3 nanocomposite films demonstrate strong electric filed control of magnetization. The nanocomposite films exhibit large exchange biasing (EB) effects in magnetic measurements near spin switching temperature (~ 100 K) of SmFeO3 and the EB effects were significantly modified under electric field (E) poled conditions (at E = 200 kV/cm), indicating ME coupling. Remarkably, we observe electric field poling induced self biased converse ME effect in the (P(VDF-TrFe))/SmFeO3 nanocomposite films. The maximum magnetoelectric output voltage (α) obtained is 55 mV/cm/Oe at Hbias = 1 kOe and 25 mV/cm/Oe at Hbias = 0, after electric field poling. The discovery of self biasing phenomenon with converse ME effects at room temperature in flexible (P(VDF-TrFe))/SmFeO3 nanocomposite films is highly desirable for device applications such as electrically controlled thin memory devices and ME sensors etc.

Notes

Acknowledgement

Authors would like to acknowledge Department of Science and Technology (DST), India for financial support. Thanks to Mr. Prem Kumar for help in XRD measurements.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Anju Ahlawat
    • 1
    Email author
  • Azam Ali Khan
    • 1
    • 2
  • Pratik Deshmukh
    • 1
  • Malvika Tripathi
    • 3
  • Mandar M. Shirolkar
    • 4
  • S. Satapathy
    • 1
    • 2
    Email author
  • R. J. Choudhary
    • 3
  • A. K. Karnal
    • 1
    • 2
  1. 1.Laser and Functional Materials DivisionRaja Ramanna Centre for Advanced TechnologyIndoreIndia
  2. 2.Homi Bhabha National InstituteMumbaiIndia
  3. 3.UGC-DAE Consortium for Scientific ResearchIndoreIndia
  4. 4.Symbiosis Center for Nanoscience and Nanotechnology (SCNN)Symbiosis International (Deemed University) (SIU)PuneIndia

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