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Ionic liquid-solvent mixture of propylene carbonate and 1,2-dimethoxyethane as electrolyte for electric double-layer capacitor

  • Hai LuEmail author
  • Long He
  • Xiangyuan Li
  • Wei Zhang
  • Jingfeng Che
  • Xiao Liu
  • Zhenzhong Hou
  • Huiling Du
  • Yaohui QuEmail author
Article
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Abstract

Ionic liquid EMIBF4 (EMI) was combined with propylene carbonate (PC) and/or 1,2-dimethoxyethane (DME) for electric double-layer capacitors (EDLCs). The effects of these support solvents on physicochemical properties of the electrolyte and capacitance performances of the capacitor were investigated. Compared to pure EMI, the existence of support solvent of PC or PC-DME provides better power characteristic mainly profited from improved ion conductivity, but sacrifices the stable potential window to some extent. The capacitor employing activated carbon and the electrolyte EMI-PC-DME yields an active mass normalized energy density of 38.5 Wh kg−1 at ~ 900 W kg−1 for the cut-off voltage of 3 V. It is a significant performance improvement compared to EMI and EMI-PC system at identical operation condition. This research guides an attractive direction to construct advanced 3 V based EDLC with excellent overall properties.

Notes

Acknowledgements

This work was supported by the Natural Science Foundation of China (Nos. 51604221 and 51372197), the Key Innovation Team of Shaanxi Province (2014KCT-04), the Key Research and Development Program of Shaanxi Province (2017GY-133), and Youth Science Foundation of Jiangxi Province (No. 20171BAB216024).

References

  1. 1.
    F. Beguin, V. Presser, A. Balducci, E. Frackowiak, Adv. Mater. 26, 2219 (2014)CrossRefGoogle Scholar
  2. 2.
    C. Zhong, Y. Deng, W. Hu, J. Qiao, L. Zhang, J. Zhang, Chem. Soc. Rev. 44, 7484 (2015)CrossRefGoogle Scholar
  3. 3.
    A.R. Neale, S. Murphy, P. Goodrich, C. Schütter, C. Hardacre, S. Passerini, A. Balducci, J. Jacquemin, J. Power Sour. 326, 549 (2016)CrossRefGoogle Scholar
  4. 4.
    J. Tian, C. Cui, Q. Xie, W. Qian, C. Xue, Y. Miao, Y. Jin, G. Zhang, B. Guo, J. Mater. Chem. A 6, 3593 (2018)CrossRefGoogle Scholar
  5. 5.
    A.J.R. Rennie, N. Sanchez-Ramirez, R.M. Torresi, P.J. Hall, J. Phys. Chem. Lett. 4, 2970 (2013)CrossRefGoogle Scholar
  6. 6.
    C. Schütter, T. Husch, M. Korth, A. Balducci, J. Phys. Chem. C 119, 13413 (2015)CrossRefGoogle Scholar
  7. 7.
    D.R. MacFarlane, N. Tachikawa, M. Forsyth, J.M. Pringle, P.C. Howlett, G.D. Elliott, J.H. Davis, M. Watanabe, P. Simon, C.A. Angell, Energy Environ. Sci. 7, 232 (2014)CrossRefGoogle Scholar
  8. 8.
    A. Brandt, S. Pohlmann, A. Varzi, A. Balducci, S. Passerini, MRS Bull. 38, 554 (2013)CrossRefGoogle Scholar
  9. 9.
    B.R. Pan, S.W. Lee, C.J. Tseng, C.L. Chang, W.C. Hung, J.K. Chang, J. Solid State Electrochem. 22, 2197 (2018)CrossRefGoogle Scholar
  10. 10.
    X.L. Dong, S.Q. Wang, B. He, W.C. Li, Microporous Mesoporous Mater. 259, 229 (2018)CrossRefGoogle Scholar
  11. 11.
    Y. Zhu, S. Murali, M.D. Stoller, K.J. Ganesh, W. Cai, P.J. Ferreira, A. Pirkle, R.M. Wallace, K.A. Cychosz, M. Thommes, D. Su, E.A. Stach, R.S. Ruoff, Science 332, 1537 (2011)CrossRefGoogle Scholar
  12. 12.
    A. Krause, A. Balducci, Electrochem. Commun. 13, 814 (2011)CrossRefGoogle Scholar
  13. 13.
    C. Schütter, A.R. Neale, P. Wilde, P. Goodrich, C. Hardacre, S. Passerini, J. Jacquemin, A. Balducci, Electrochim. Acta 220, 146 (2016)CrossRefGoogle Scholar
  14. 14.
    A. Eftekhari, Energy Storage Mater. 9, 47 (2017)CrossRefGoogle Scholar
  15. 15.
    S. Vaquero, J. Palma, M. Anderson, R. Marcilla, J. Electrochem. Soc. 160, A2064 (2013)CrossRefGoogle Scholar
  16. 16.
    S. Pohlmann, C. RamirezCastro, A. Balducci, J. Electrochem. Soc. 162, A5020 (2015)CrossRefGoogle Scholar
  17. 17.
    P.W. Ruch, D. Cericola, A. Foelske, R. Kötz, A. Wokaun, Electrochim. Acta 55, 2352 (2010)CrossRefGoogle Scholar
  18. 18.
    M. Marcinek, J. Syzdek, M. Marczewski, M. Piszcz, L. Niedzicki, M. Kalita, A. Plewa-Marczewska, A. Bitner, P. Wieczorek, T. Trzeciak, M. Kasprzyk, P. Łężak, Z. Zukowska, A. Zalewska, W. Wieczorek, Solid State Ion. 276, 107 (2015)CrossRefGoogle Scholar
  19. 19.
    L. Zhi, T. Li, H. Yu, S. Chen, L. Dang, H. Xu, F. Shi, Z. Liu, Z. Lei, Carbon 113, 100 (2017)CrossRefGoogle Scholar
  20. 20.
    S. Wu, K. Hui, K. Hui, J. Yun, K. Kim, Chem. Eng. J. 317, 461 (2017)CrossRefGoogle Scholar
  21. 21.
    S. Pohlmann, A. Balducci, Electrochim. Acta 110, 221 (2013)CrossRefGoogle Scholar
  22. 22.
    X. Yu, D. Ruan, C. Wu, J. Wang, Z. Shi, J. Power Sour. 265, 309 (2014)CrossRefGoogle Scholar
  23. 23.
    A. Balducci, J. Power Sour. 326, 534 (2016)CrossRefGoogle Scholar
  24. 24.
    R.S. Kühnel, A. Balducci, J. Power Sour. 249, 163 (2014)CrossRefGoogle Scholar
  25. 25.
    J. Li, J. Tang, J. Yuan, K. Zhang, Q. Shao, Y. Sun, L.C. Qin, Electrochim. Acta 197, 84 (2016)CrossRefGoogle Scholar
  26. 26.
    R. Kühnel, J. Reiter, S. Jeong, S. Passerini, A. Balducci, Electrochem. Commun. 38, 117 (2014)CrossRefGoogle Scholar
  27. 27.
    L. Li, X. Wang, S. Wang, Z. Cao, Z. Wu, H. Wang, Y. Gao, J. Liu, Electroanalysis 28, 243 (2016)CrossRefGoogle Scholar
  28. 28.
    E. Teo, L. Muniandy, E. Ng, F. Adam, A. Mohamed, R. Jose, K. Chong, Electrochim. Acta 192, 110 (2016)CrossRefGoogle Scholar
  29. 29.
    K. Wang, N. Zhao, S. Lei, R. Yan, X. Tian, J. Wang, Y. Song, D. Xu, Q. Guo, L. Liu, Electrochim. Acta 166, 1 (2015)CrossRefGoogle Scholar
  30. 30.
    H. Wang, L. Zhi, K. Liu, L. Dang, Z. Liu, Z. Lei, C. Yu, J. Qiu, Adv. Funct. Mater. 25, 5420 (2015)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Hai Lu
    • 1
    Email author
  • Long He
    • 1
  • Xiangyuan Li
    • 2
  • Wei Zhang
    • 2
  • Jingfeng Che
    • 2
  • Xiao Liu
    • 1
  • Zhenzhong Hou
    • 1
  • Huiling Du
    • 1
  • Yaohui Qu
    • 3
    Email author
  1. 1.School of Materials Science and EngineeringXi’an University of Science and TechnologyXi’anChina
  2. 2.Xi’an Herong New Energy Technology Co., LtdXi’anChina
  3. 3.Jiangxi Key Laboratory of Nanomaterials and Sensors, School of Physics, Communication and ElectronicsJiangxi Normal UniversityNanchangChina

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