Tunable luminescence and energy transfer properties based on La2O3-P2O5:Dy3+/Tm3+ glasses

  • Tao ZhangEmail author
  • Jingxuan Wang
  • Yifan Xin
  • Xin Wang
  • Libo Yuan


The white-LED material Dy3+/Tm3+ co-doped phosphate glass was prepared by a conventional melting method. The energy transfer in the two rare earth ions was supposed by changing the concentration of one doping ion and was further demonstrated by the fluorescence lifetime. The energy level transition mechanism between the rare earth ions was analyzed using the Inokuti–Hirayama theory. There were two kinds of energy transfer mechanisms from the dipole–quadrupole interaction (Dy3+ → Tm3+) and the quadrupole–quadrupole interaction (Tm3+→Dy3+). The luminescence color was tuned from a blue to a near standard white light emission using 350 nm excitation and adjusting the rare earth ion doping ratio. The results show that 15La2O3-85P2O5:xDy2O3-yTm2O3 glass is a promising UV-excited white photodiode material.



This work was supported by the Science-Technology Creative Foundation for Young Scientists of Harbin City (No. 2015RAQXJ055), partially supported by China Postdoctoral Science Foundation (Grant No. 2013M531013), by the Foundation of Guilin University of Electronic Technology (No. HKY19002), and by the 111 Project (B13015) to the Harbin Engineering University.

Compliance with ethical standards

Conflicts of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.


  1. 1.
    C. Bouzigues, T. Gacoin, A. Alexandrou, Biological applications of rare-earth based nanoparticles. ACS Nano 5, 8488–8505 (2011). CrossRefGoogle Scholar
  2. 2.
    Pan Z, Yuan H, Dai X, Cai H, Serres JM, Mateos X, Aguiló M, Díaz F, Wang Y, Zhao Y, Loiko P, Griebner U, Petrov V (2018) Growth, characterization and laser operation of Tm3+, Na+codoped CNGG (Tm: CNNGG) disordered garnet, In: Conference on Lasers and Electro-Optics/Pacific Rim, Hong Kong, China, 2018, pp. W4A.2.
  3. 3.
    A. Górny, M. Sołtys, J. Pisarska, W.A. Pisarski, Spectroscopy and energy transfer in lead borate glasses doubly doped with Tm3+ and Dy3+ ions. Spectrochim. Acta. A 192, 140–145 (2018). CrossRefGoogle Scholar
  4. 4.
    P. Du, L. Wang, J.S. Yu, Luminescence properties and energy transfer behavior of single-component NaY(WO4)2: Tm3+/Dy3+/Eu3+ phosphors for ultraviolet-excited white light-emitting diodes. J. Alloys Compd. 673, 426–432 (2016). CrossRefGoogle Scholar
  5. 5.
    S. Wang, Y.X. Zhou, S.X. Dai, X.S. Wang, X. Shen, F.F. Chen, Influence of high phonon energy oxide on spectroscopic properties of Er3+/Ce3+co-doped tellurite glasses. Wuji Cailiao Xuebao 27(8), 865–870 (2012)Google Scholar
  6. 6.
    Y. Chen, M. Zheng, Y. Xiao, H. Dong, H. Zhang, J. Zhuang, H. Hu, B. Lei, Y. Liu, A self-quenching-resistant carbon-dot powder with tunable solid-state fluorescence and construction of dual-fluorescence morphologies for white light-emission. Adv. Mater. 28(2), 312–318 (2016). CrossRefGoogle Scholar
  7. 7.
    R. Zhang, H. Lin, Y. Yu, D. Chen, J. Xu, Y. Wang, A new-generation color converter for high-power white LED: transparent Ce3+: YAG phosphor-in-glass. Laser Photonics Rev. 8, 158–164 (2014). CrossRefGoogle Scholar
  8. 8.
    K. Bando, K. Sakano, Y. Noguchi, Y. Shimizu, Development of high-bright and pure-white LED lamps. J. Light Visual Environ. 22(1), 12–15 (1998)CrossRefGoogle Scholar
  9. 9.
    Y. Yu, Z. Liu, N. Dai, Y. Sheng, H. Luan, J. Peng, Z. Jiang, H. Li, J. Li, L. Yang, Ce-Tb-Mn co-doped white light emitting glasses suitable for long-wavelength UV excitation. Opt. Express 19, 19473–19479 (2011). CrossRefGoogle Scholar
  10. 10.
    N. Wei, T. Lu, F. Li, W. Zhang, B. Ma, Z. Lu, J. Qi, Transparent Ce: Y3Al5O12 ceramic phosphors for white light-emitting diodes. Appl. Phys. Lett. 101, 061902 (2012). CrossRefGoogle Scholar
  11. 11.
    J. Wang, C.C. Tsai, W.C. Cheng, M.H. Chen, C.H. Chung, W.H. Cheng, High thermal stability of phosphor-converted white light - emitting diodes employing Ce: YAG-doped glass. IEEE J. Sel. Top. Quantum Electron. 17, 741–746 (2011). CrossRefGoogle Scholar
  12. 12.
    S. Liu, G. Zhao, X. Lin, H. Ying, J. Liu, J. Wang, G. Han, White luminescence of Tm-Dy ions co-doped aluminoborosilicate glasses under UV light excitation. J. Solid State Chem. 181, 2725–2730 (2008). CrossRefGoogle Scholar
  13. 13.
    A.N. Meza-Rocha, G. Muñoz, A. Speghini, M. Bettinelli, U. Caldiño, Neutral and warm white light emission in Tb3+/Sm3+ zinc phosphate glasses. Opt. Mater. 47, 537–542 (2015). CrossRefGoogle Scholar
  14. 14.
    Y. Jiang, H. Xia, S. Yang, J. Zhang, D. Jiang, C. Wang, Z. Feng, J. Zhang, X. Gu, J. Zhang, H. Jiang, B. Chen, Luminescence of Tb3+/Eu3+codoped LiYF4 single crystals under UV excitation for white-light LEDs. Chinese Opt. Lett. 13(7), 071601 (2015)CrossRefGoogle Scholar
  15. 15.
    D. Rajesh, K. Brahmachary, Y.C. Ratnakaram, N. Kiran, A.P. Baker, G.G. Wang, Energy transfer based emission analysis of Dy3+/Eu3+ co-doped ZANP glasses for white LED applications. J. Alloys Compd. 646, 1096–1103 (2015). CrossRefGoogle Scholar
  16. 16.
    Z. Cui, R. Ye, D. Deng, Y. Hua, S. Zhao, G. Jia, C. Li, S. Xu, Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED. J. Alloys Compd. 509, 3553–3558 (2011). CrossRefGoogle Scholar
  17. 17.
    X. Liang, S. Yuan, Y. Yang, G. Chen, The luminescence properties of Er3+-doped and Er3+-Tm3+-co-doped phosphate glasses for white light emitting diode. J. Lumin. 130, 429–433 (2010). CrossRefGoogle Scholar
  18. 18.
    L. Xing, Y. Xu, R. Wang, W. Xu, Influence of temperature on upconversion multicolor luminescence in Ho3+/Yb3+/Tm3+-doped LiNbO3 single crystal. Opt. Lett. 38, 2535–2537 (2013). CrossRefGoogle Scholar
  19. 19.
    V. Mahalingam, R. Naccache, F. Vetrone, J.A. Capobianco, Enhancing upconverted white light in Tm3+/Yb3+/Ho3+-doped GdVO4 nanocrystals via incorporation of Li+ ions. Opt. Express 20, 111–119 (2012). CrossRefGoogle Scholar
  20. 20.
    X. Gao, T. Li, J. He, K. Ye, X. Song, N. Wang, J. Su, C. Hui, X. Zhang, Synthesis of Yb3+, Ho3+ and Tm3+ co-doped β-NaYF4 nanoparticles by sol-gel method and the multi-color upconversion luminescence properties. J. Mater. Sci. 28, 11644–11653 (2017). Google Scholar
  21. 21.
    X.Y. Sun, S. Wu, X. Liu, P. Gao, S.M. Huang, Intensive white light emission from Dy3+-doped Li2B4O7 glasses. J. Non-Cryst. Solids 368, 51–54 (2013). CrossRefGoogle Scholar
  22. 22.
    S. Gao, C. Sun, Y. Ji, Z. Zhu, Y. Wang, Z. You, Y. Wang, J. Feng, S. Lv, H. Wang, C. Tu, Photoluminescence properties and white emission of Dy3+, Tm3+: NaY (WO4)2 phosphors. Mater. Express 3, 127–134 (2013). CrossRefGoogle Scholar
  23. 23.
    P.A. Ryabochkina, S.A. Antoshkina, E.V. Bolshakova, M.A. Ivanov, V.V. Kochurihin, A.V. Malov, S.N. Ushakov, N.V. Shchuchkina, K.N. Nishchev, Hypersensitive transitions of Tm3+, Ho3+ and Dy3+ rare-earth ions in garnet crystals. J. Lumin. 132(8), 1900–1905 (2012)CrossRefGoogle Scholar
  24. 24.
    J. Wang, J. Wang, P. Duan, Luminescence and energy transfer of Tm3+ or/and Dy3+ co-doped in Sr3Y(PO4)3 phosphors with UV excitation for WLEDs. J. Lumin. 145, 1–5 (2014). CrossRefGoogle Scholar
  25. 25.
    J. Hu, X.H. Gong, Y.J. Chen, J.H. Huang, Y.F. Lin, Z.D. Luo, Y.D. Huang, Tunable luminescence of Dy3+ single-doped and Dy3+/Tm3+ co-doped tungsten borate glasses. Opt. Mater. 38, 108–112 (2014). CrossRefGoogle Scholar
  26. 26.
    A.V. Deepa, P. Murugasen, P. Muralimanohar, S.P. Kumar, Optical studies of lanthanum oxide doped phosphate glasses. Optik 160, 348–352 (2018). CrossRefGoogle Scholar
  27. 27.
    J.M. Cole, E.R. van Eck, G. Mountjoy, R.J. Newport, T. Brennan, G.A. Saunders, A neutron diffraction and 27Al MQMAS NMR study of rare-earth phosphate glasses,(R2O3)x(P2O5)1−x, x = 0.187–0.263, R = Ce, Nd, Tb containing Al impurities. J. Phys 11(47), 9165 (1999)Google Scholar
  28. 28.
    X. Xi, P. Dong, L. Han, R. Guan, G. Hou, Color-tunable emission and energy transfer in NaCaPO4: Tb3+/Mn2+ phosphors. J. Lumin. 159, 280–283 (2015). CrossRefGoogle Scholar
  29. 29.
    U. Caldiño, I. Camarillo, A. Speghini, M. Bettinelli, Down-shifting by energy transfer in Tb3+/Dy3+ co-doped zinc phosphate glasses. J. Lumin. 161, 142–146 (2015). CrossRefGoogle Scholar
  30. 30.
    M. Inokuti, F. Hirayama, Influence of energy transfer by the exchange mechanism on donor luminescence. J. Chem. Phys. 43, 1978–1989 (1965). CrossRefGoogle Scholar
  31. 31.
    X. Zhang, Y. Liu, J. Lin, Z. Hao, Y. Luo, Q. Liu, J. Zhang, Optical properties and energy transfers of Ce3+ and Mn2+ in Ba9Sc2(SiO4)6. J. Lumin. 146, 321–324 (2014). CrossRefGoogle Scholar
  32. 32.
    L. Xing, X. Wu, R. Wang, W. Xu, Y. Qian, Upconversion white-light emission in Ho3+/Yb3+/Tm3+tridoped LiNbO3 single crystal. Opt. Lett. 37, 3537–3539 (2012). CrossRefGoogle Scholar
  33. 33.
    H. Gong, D. Yang, X. Zhao, E.Y.B. Pun, H. Lin, Upconversion color tunability and white light generation in Tm3+/Ho3+/Yb3+ doped aluminum germanate glasses. Opt. Mater. 32, 554–559 (2010). CrossRefGoogle Scholar
  34. 34.
    A.N. Meza-Rocha, A. Speghini, R. Lozada-Morales, U. Caldino, Blue and white light emission in Tm3+ and Tm3+/Dy3+ doped zinc phosphate glasses upon UV light excitation. Opt. Mater. 58, 183–187 (2016). CrossRefGoogle Scholar

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Authors and Affiliations

  1. 1.College of Electronic InformationGuilin University of Electronic TechnologyGuangxi, BeihaiChina
  2. 2.College of ScienceHarbin Engineering UniversityHeilongjiang, HarbinChina

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