Lightweight SrM/CCTO/rGO nanocomposites for optoelectronics and Ku band microwave absorption

  • J. Mohammed
  • Tchouank Tekou Carol T.
  • H. Y. Hafeez
  • D. Basandrai
  • Gopala Ram Bhadu
  • Sachin Kumar Godara
  • S. B. Narang
  • A. K. SrivastavaEmail author


In this research, nanocomposites comprising M-type strontium hexaferrites (SrM) SrFe12−xCsxO19 (x = 0.0, 0.05, 0.10), calcium copper titanate (CCTO) CaCu3Ti4−yAlyO12 (y = 0.0, 0.1, 0.2) and reduced graphene oxide (rGO) have been prepared. XRD patterns shows the presence of single phase nanocrystalline SrM and CCTO which is further supported by Raman spectroscopy and FTIR analysis. The presence of secondary phase such as α-Fe2O3, CaTiO3, and CuO has not been observed. Characteristics absorption bands of Cs-substituted SrM and Al-substituted CCTO were observed at 446, 551 and 605 cm−1, these peaks gives the idea of the formation of SrM and CCTO phase. The D and G bands of GO were observed at 1358 and 1604 cm−1 respectively, while that of the rGO were respectively observed at 1351 and 1595 cm−1. FESEM micrograph show the incorporated SrM nanoparticles, CCTO nanoparticles and rGO sheets, reduction in surface energy and magnetic dipolar interaction prompt the SrM nanoparticles to surround the CCTO nanoparticles and decorate the surface of the rGO sheets. The non-magnetic CCTO phase in the nanocomposites causes the tuning of the magnetic properties. The band gap obtained from UV–vis NIR spectroscopy is within the range of UV-blue LED application. The sample SCR3 shows a maximum reflection loss of − 16.0 dB at 18.0 GHz and matching thickness of 2 mm. The obtained reflection loss is attributed to multiple absorption mechanism as a result of improved impedance matching between the dielectric and magnetic loss absorbents.



The authors thank Sophisticated Test and Instrumentation and Centre (STIC), Cochin University of Science and Technology, Kerala, India for UV–Vis-NIR Spectrophotometer characterization.

Supplementary material

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Supplementary material 1 (DOCX 11210 KB)


  1. 1.
    R.C. Pullar, Prog. Mater. Sci. 57, 1191–1334 (2012)CrossRefGoogle Scholar
  2. 2.
    R.C. Pullar, I.K. Bdikin, A.K. Bhattacharya, J. Eur. Ceram. Soc. 32, 905–913 (2012)CrossRefGoogle Scholar
  3. 3.
    S.M. Abbas, M. Chandra, A. Verma, R. Chatterjee, T.C. Goel, Compos. Part A 37, 2148–2154 (2006)CrossRefGoogle Scholar
  4. 4.
    A.G.D. Aloia, F. Marra, A. Tamburrano, G. De Bellis, M.S. Sarto, Carbon N. Y. 73, 175–184 (2014)CrossRefGoogle Scholar
  5. 5.
    T. Kaur, S. Kumar, J. Sharma, A.K. Srivastava, Beilstein J. Nantechnol 6, 1700–1707 (2015)CrossRefGoogle Scholar
  6. 6.
    D.A. Makeiff, T. Huber, Synth. Met. 156, 497–505 (2006)CrossRefGoogle Scholar
  7. 7.
    P. Saini, V. Choudhary, B.P. Singh, R.B. Mathur, S.K. Dhawan, Mater. Chem. Phys. 113, 919–926 (2009)CrossRefGoogle Scholar
  8. 8.
    F. Mohd, M. Hashim, Z. Abbas, I. Ismail, R. Nazlan, I. Riati, J. Magn. Magn. Mater. 405, 197–208 (2016)CrossRefGoogle Scholar
  9. 9.
    E. Schloemann, J. Magn. Magn. Mater. 209, 15–20 (2000)CrossRefGoogle Scholar
  10. 10.
    V.G. Harris, A. Geiler, Y. Chen, S. Dae, M. Wu, A. Yang, Z. Chen, P. He, P.V. Parimi, X. Zuo, C.E. Patton, M. Abe, O. Acher, C. Vittoria, J. Magn. Magn. Mater. 321, 2035–2047 (2009)CrossRefGoogle Scholar
  11. 11.
    Y. Guan, Y. Lin, L. Zou, Q. Miao, M. Zeng, Z. Liu, X. Gao, J. Liu, Y. Guan, Y. Lin, L. Zou, Q. Miao, M. Zeng, AIP Adv. 3, 122115 (2013)CrossRefGoogle Scholar
  12. 12.
    S.H. Mahmood, G.H. Dushaq, I. Bsoul, M. Awawdeh, H.K. Juwhari, B.I. Lahlouh, M.A. Aldamen, J. Appl. Math. Phys. 2, 77–87 (2014)CrossRefGoogle Scholar
  13. 13.
    E.D. Solov, E.V. Pashkova, A.E. Perekos, A.G. Belous, Inorg. Mater. 48(11), 1147–1152 (2012)CrossRefGoogle Scholar
  14. 14.
    S.K. Chawla, R.K. Mudsainiyan, S.S. Meena, S.M. Yusuf, J. Magn. Magn. Mater. 350, 23–29 (2014)CrossRefGoogle Scholar
  15. 15.
    O. Archer, J. Magn. Magn. Mater. 321, 2033–2034 (2009)CrossRefGoogle Scholar
  16. 16.
    T. Kaur, S. Kumar, S.B. Narang, A.K. Srivastava, J. Magn. Magn. Mater. 420, 336–342 (2016)CrossRefGoogle Scholar
  17. 17.
    Z. Mosleh, P. Kameli, A. Poorbaferani, M. Ranjbar, H. Salamati, J. Magn. Magn. Mater. 397, 314–318 (2016)CrossRefGoogle Scholar
  18. 18.
    J. Mohammed, T. Tekou Carol, T.H.Y. Hafeez, B.I. Adamu, Y.S. Wudil, Z.I. Takai, S.K. Godara, A.K. Srivastava, J. Phys. Chem. Solids 126, 85–92 (2019)CrossRefGoogle Scholar
  19. 19.
    L. Ramajo, R. Parra, J.A. Varela, M.M. Reboredo, M.A. Ramírez, M.S. Castro, J. Alloys Compd. 497, 349–353 (2010)CrossRefGoogle Scholar
  20. 20.
    C. Wang, S. Lin, K. Kao, Y. Chen, S. Weng, J. Alloys Compd. 491, 423–430 (2010)CrossRefGoogle Scholar
  21. 21.
    D.D.L. Chung, J. Mater. Sci. 37, 1475–1489 (2002)CrossRefGoogle Scholar
  22. 22.
    W.S. Hummers, R.E. Offeman, J. Am. Chem. Soc. 80(6), 1339 (1958)CrossRefGoogle Scholar
  23. 23.
    N.I. Kovtyukhova, P.J. Ollivier, B.R. Martin, T.E. Mallouk, S.A. Chizhik, E.V. Buzaneva, A.D. Gorchinskiy, Chem. Mater. 11(3), 771–778 (1999)CrossRefGoogle Scholar
  24. 24.
    J.K. Lee, K.B. Smith, M. Hayner, H.H. Kung, Chem. Commun. 46(12), 2025–2027 (2010)CrossRefGoogle Scholar
  25. 25.
    J.N. Ding, Y.B. Liu, N.Y. Yuan, G.Q. Ding, Y. Fan, C.T. Yu, Diam. Relat. Mater. 21, 11–15 (2012)CrossRefGoogle Scholar
  26. 26.
    C. Xu, X. Shi, A. Ji, L. Shi, C. Zhou, Y. Cui, PLoS ONE 10(12), e0144842 (2015)CrossRefGoogle Scholar
  27. 27.
    R.S. Alam, M. Moradi, H. Nikmanesh, J. Ventura, M. Rostami, J. Magn. Magn. Mater. 402, 20–27 (2016)CrossRefGoogle Scholar
  28. 28.
    M.R. Eraky, J. Magn. Magn. Mater. 324, 1034–1039 (2012)CrossRefGoogle Scholar
  29. 29.
    A. Baniasadi, A. Ghasemi, A. Nemati, M. Azami, E. Paimozd, J. Alloys Compd. 583, 325–328 (2014)CrossRefGoogle Scholar
  30. 30.
    Q.F. Ã, H. Cheng, K. Huang, J. Wang, R. Li, Y. Jiao, J. Magn. Magn. Mater. 294(3), 281–286 (2005)CrossRefGoogle Scholar
  31. 31.
    S.E.M. Ghahfarokhi, Z.A. Rostami, I. Kazeminezhad, J. Magn. Magn. Mater. 399, 130–142 (2016)CrossRefGoogle Scholar
  32. 32.
    S. Jiang, X. Liu, K.M.U. Rehman, M. Li, Y. Wu, J. Mater. Sci. Mater. Electron. 27, 12919–12924 (2016)CrossRefGoogle Scholar
  33. 33.
    P. Jing, J. Du, J. Wang, L. Pan, J. Li, Q. Liu, Sci. Rep. 5, 15089 (2015)CrossRefGoogle Scholar
  34. 34.
    T. Kaur, J. Sharma, S. Kumar, A.K. Srivastava, Cryst. Res. Technol. 52(9), 1700098 (2017)CrossRefGoogle Scholar
  35. 35.
    S. Jesurani, S. Kanagesan, M. Hashim, I. Ismail, J. Alloys Compd. 551, 456–462 (2013)CrossRefGoogle Scholar
  36. 36.
    A.K. Dubey, P. Singh, S. Singh, D. Kumar, O. Parkash, J. Alloys Compd. 509(9), 3899–3906 (2011)CrossRefGoogle Scholar
  37. 37.
    M. Rostami, M. Moradi, R.S. Alam, R. Mardani, Mater. Res. Bull. 83, 379–386 (2016)CrossRefGoogle Scholar
  38. 38.
    P. Thomas, K. Dwarakanath, K.B.R. Varma, T.R.N. Kutty, J. Therm. Anal. Calorim. 95(1), 267–272 (2009)CrossRefGoogle Scholar
  39. 39.
    T. Kaur, S. Kumar, B. Hamid, B. Basharat, A.K. Srivastava, Appl. Phys. A 119(4), 1531–1540 (2015)CrossRefGoogle Scholar
  40. 40.
    R. Shams, M. Moradi, M. Rostami, H. Nikmanesh, R. Moayedi, Y. Bai, J. Magn. Magn. Mater. 381, 1–9 (2015)CrossRefGoogle Scholar
  41. 41.
    L. Wang, J. Zhu, H. Yang, F. Wang, Y. Qin, T. Zhao, P. Zhang, J. Alloys Compd. 634, 232–238 (2015)CrossRefGoogle Scholar
  42. 42.
    Y. Chen, Y. Li, M. Yip, N. Tai, Compos. Sci. Technol. 80, 80–86 (2013)CrossRefGoogle Scholar
  43. 43.
    L. Wang, Y. Huang, C. Li, J. Chen, X. Sun, Compos. Sci. Technol. 108, 1–8 (2015)CrossRefGoogle Scholar
  44. 44.
    J. Luo, P. Shen, W. Yao, C. Jiang, J. Xu, Nanoscale Res. Lett. 11, 141 (2016)CrossRefGoogle Scholar
  45. 45.
    R. Bhargava, S. Khan, J. Phys. Condens. Matter 30, 335703 (2018)CrossRefGoogle Scholar
  46. 46.
    J. Mohammed, B.F. Abubakar, K.U. Yerima, H. Hamisu, U.T. Isma’il, A. Muhammad, U.F. Zulfatu, A. Abubakar, N.M. Salihu, M.S. Abubakar, Y. Saidu, T. Tchouank Tekou Carol, A.K. Srivastava, Mater. Today Proc. 5, 28462–28469 (2018)CrossRefGoogle Scholar
  47. 47.
    Q. Jia, W. Wang, J. Zhao, J. Xiao, L. Lu, H. Fan, J. Alloys Compd. 710, 717–724 (2017)CrossRefGoogle Scholar
  48. 48.
    H.Y. Hafeez, S.K. Lakhera, S. Bellamkonda, G.R. Rao, M.V. Shankar, D.W. Bahnemann, B. Neppolian, Int. J. Hydrog. Energy 43(8), 3892–3904 (2017)CrossRefGoogle Scholar
  49. 49.
    L. Gan, S. Shang, C. Wah, M. Yuen, S. Jiang, E. Hu, Appl. Surf. Sci. 351, 140–147 (2015)CrossRefGoogle Scholar
  50. 50.
    R. Bhargava, S. Khan, Adv. Powder Technol. 28(11), 2812–2819 (2017)CrossRefGoogle Scholar
  51. 51.
    J. Feng, F. Pu, Z. Li, X. Li, X. Hu, J. Bai, Carbon 104, 214–225 (2016)CrossRefGoogle Scholar
  52. 52.
    T. Huang, M. He, Y. Zhou, S. Li, B. Ding, W. Pan, S. Huang, Y. Tong, Synth. Met. 224, 46–55 (2017)CrossRefGoogle Scholar
  53. 53.
    F. Amaral, L.C. Costa, M.A. Valente, A.J.S. Fernandes, N. Franco, E. Alves, F.M. Costa, Acta Mater. 59(11), 102–111 (2011)CrossRefGoogle Scholar
  54. 54.
    F. Moura, A.Z. Simoes, R.C. Deus, M.R. Silva, J.A. Varela, E. Longo, Ceram. Int. 39, 3499–3506 (2013)CrossRefGoogle Scholar
  55. 55.
    P. Liu, Y. Huang, X. Zhang, Mater. Lett. 129, 35–38 (2014)CrossRefGoogle Scholar
  56. 56.
    P. Liu, Y. Huang, X. Zhang, Synth. Met. 201, 76–81 (2015)CrossRefGoogle Scholar
  57. 57.
    S. Asiri, S. Güner, A.D. Korkmaz, M. Amir, K.M. Batoo, M.A. Almessiere, H. Gungunes, H. Sözeri, A. Baykal, J. Magn. Magn. Mater. 451, 463–472 (2018)CrossRefGoogle Scholar
  58. 58.
    A. Hojjati-najafabadi, A. Ghasemi, A. Ghasemi, Ceram. Int. 43(1), 244–249 (2017)CrossRefGoogle Scholar
  59. 59.
    A.H. Najafabadi, A. Ghasemi, R. Mozaffarinia, Ceram. Int. 42, 13625–13634 (2016)CrossRefGoogle Scholar
  60. 60.
    R. Al-gaashani, S. Radiman, Y. Al-douri, N. Tabet, A.R. Daud, J. Alloys Compd. 521, 71–76 (2012)CrossRefGoogle Scholar
  61. 61.
    Z. Zhong, F. Qian, D. Wang, C.M. Lieber, Nano Lett. 3(3), 343–346 (2003)CrossRefGoogle Scholar
  62. 62.
    A.O. Turky, M.M. Rashad, Z.I. Zaki, I.A. Ibrahim, M. Bachelany, RSC Adv. 5, 18767–18772 (2015)CrossRefGoogle Scholar
  63. 63.
    A.O. Turky, M.M. Rashad, M. Bechelany, Mater. Des. 90, 54–59 (2016)CrossRefGoogle Scholar
  64. 64.
    J. Mohammed, A.B. Suleiman, H.Y. Hafeez, T. Tchouank Tekou Carol, J. Sharma, G.R. Bhadu, S.K. Godara, A.K. Srivastava, Mater. Res. Express 5, 086106 (2018)CrossRefGoogle Scholar
  65. 65.
    P. Kaur, S.K.C. Sukhleen, B. Narang, K. Pubby, J. Supercond. Nov. Magn. 30(3), 635–645 (2016)CrossRefGoogle Scholar
  66. 66.
    R.K. Mudsainiyan, S.K. Chawla, S.S. Meena, J. Alloys Compd. 615, 875–881 (2014)CrossRefGoogle Scholar
  67. 67.
    H. Nikmanesh, M. Moradi, G.H. Bordbar, R.S. Alam, Ceram. Int. 42(13), 14342–14349 (2016)CrossRefGoogle Scholar
  68. 68.
    M. Zhang, J. Zheng, L. Liang, F. Jiang, Y. Wang, J. Magn. Magn. Mater. 368, 198–201 (2014)CrossRefGoogle Scholar
  69. 69.
    J. Lv, S. Zhai, C. Gao, N. Zhou, Q. An, B. Zhai, Chem. Eng. J. 289, 261–269 (2016)CrossRefGoogle Scholar
  70. 70.
    J. Yan, Y. Huang, X. Chen, C. Wei, Synth. Met. 221, 291–298 (2016)CrossRefGoogle Scholar
  71. 71.
    K. Zhang, X. Gao, Q. Zhang, T. Li, H. Chen, X. Chen, J. Alloys Compd. 721, 268–275 (2017)CrossRefGoogle Scholar
  72. 72.
    Y. Zhang, Y. Huang, H. Chen, Z. Huang, Y. Yang, P. Xiao, Y. Zhou, Y. Chen, Carbon 105, 438–447 (2016)CrossRefGoogle Scholar
  73. 73.
    T. Wu, K. Lu, C. Peng, Y. Hong, C. Hwang, Mater. Res. Bull. 70, 486–493 (2015)CrossRefGoogle Scholar
  74. 74.
    H. Zhang, X. Tian, C. Wang, H. Luo, J. Hu, Y. Shen, A. Xie, Appl. Surf. Sci. 14, 228–232 (2014)CrossRefGoogle Scholar
  75. 75.
    P. Liu, Z. Yao, J. Zhou, Ceram. Int. 42, 9241–9249 (2016)CrossRefGoogle Scholar
  76. 76.
    Y. Wang, Y. Fu, X. Wu, W. Zhang, Q. Wang, J. Li, Ceram. Int. 43(14), 11367–11375 (2017)CrossRefGoogle Scholar
  77. 77.
    J. Wang, J. Wang, B. Zhang, Y. Sun, W. Chen, T. Wang, J. Magn. Magn. Mater. 401, 209–216 (2015)CrossRefGoogle Scholar
  78. 78.
    X. Liu, C. Cui, T. Li, A. Xia, Y. Lv, J. Alloys Compd. 678, 234–240 (2016)CrossRefGoogle Scholar
  79. 79.
    G. Liu, W. Jiang, D. Sun, Y. Wang, F. Li, Appl. Surf. Sci. 314, 523–529 (2014)CrossRefGoogle Scholar

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Authors and Affiliations

  1. 1.Department of Physics, School of Physical Sciences and Chemical EngineeringLovely Professional UniversityPhagwaraIndia
  2. 2.Department of Physics, Faculty of ScienceFederal University DutseDutseNigeria
  3. 3.SRM Research InstituteSRM UniversityChennaiIndia
  4. 4.Analytic Division and Centralised Instrument FacilityCSIR-Central Salt and Marine Chemicals Research InstituteBhavnagarIndia
  5. 5.Department of ChemistryGuru Nanak Dev UniversityAmritsarIndia
  6. 6.Department of Electronics and CommunicationGuru Nanak Dev UniversityAmritsarIndia

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