Journal of Materials Science: Materials in Electronics

, Volume 29, Issue 17, pp 15022–15028 | Cite as

Synthesis and photoluminescence properties of novel yellow-emitting Ba2Gd5−xDyxB5O17 phosphors

  • R. Vijayakumar
  • Xiaoyong HuangEmail author


Single phase yellow-emitting Dy3+ ions doped Ba2Gd5B5O17 phosphors were synthesized by solid-state reaction technique at high temperature. The phase identification and photoluminescence properties of as-prepared phosphors were characterized by X-ray diffraction patterns, excitation and emission spectra, decay curves and temperature-dependent luminescence spectral measurements. Under 276 and 354 nm near-UV excitations, the studied phosphors exhibited two intense emission bands in blue (486 nm) and yellow (575 nm) regions due to the magnetic dipole (4F9/26H15/2) and electric dipole (4F9/26H13/2) transitions, respectively. The optimal doping concentration of Dy3+ ions was found to be x = 0.07 for Ba2Gd5−xDyxB5O17 phosphors. Under 354 nm excitation, the color coordinates (x, y) of Ba2Gd4.93Dy0.07B5O17 phosphor were located in the yellow region of Commission International de I-Eclairage 1931 diagram and hence it can be used as a potential yellow component in the fabrication of white light-emitting diodes. Furthermore, the decay curves were fitted to double-exponential function to find the excited state lifetimes of Dy3+ ions. Besides, the temperature-dependent luminescence measurements were made to explore the thermal stability and activation energy of the concentration-optimized Ba2Gd4.93Dy0.07B5O17 phosphor. The results obtained from the present investigation were discussed in detail and compared with the similar reported literatures.



This work was supported by the National Natural Science Foundation of China (No. 51502190), the Program for the Outstanding Innovative Teams of Higher Learning Institutions of Shanxi, and the Open Fund of the State Key Laboratory of Luminescent Materials and Devices (South China University of Technology, No. 2017-skllmd-01).


  1. 1.
    B. Han, Y. Dai, J. Zhang, H. Shi, Mater. Lett. 204, 145 (2017)CrossRefGoogle Scholar
  2. 2.
    Q. Sun, X. Li, Y. Du, B. Zhao, H. Li, Y. Huang, Z. Ci, J. Zhang, J. Ma, Y. Wang, J. Am. Ceram. Soc. 100, 193 (2017)CrossRefGoogle Scholar
  3. 3.
    P.S. Babu, P.P. Rao, S. Mahesh, T.L. Francis, T. Sreena, Mater. Lett. 170, 196 (2016)CrossRefGoogle Scholar
  4. 4.
    R. Nayar, S. Tamboli, A. Sahu, V. Nayar, S. Dhoble, J. Fluoresc. 27, 251 (2017)CrossRefGoogle Scholar
  5. 5.
    S. Liu, J. He, Z. Wu, J.H. Jeong, B. Deng, R. Yu, J. Lumin. 200, 164 (2018)CrossRefGoogle Scholar
  6. 6.
    X. Huang, Nat. Photonics 8, 748 (2014)CrossRefGoogle Scholar
  7. 7.
    G. Wang, X. Gong, Y. Chen, J. Huang, Y. Lin, Z. Luo, Y. Huang, Opt. Mater. 36, 1255 (2014)CrossRefGoogle Scholar
  8. 8.
    R. Zhang, T. Maeda, R. Maruta, S. Kusaka, B. Ding, K. Murai, T. Moriga, J. Solid State Chem. 183, 620 (2010)CrossRefGoogle Scholar
  9. 9.
    Y.-C. Chiu, W.-R. Liu, C.-K. Chang, C.-C. Liao, Y.-T. Yeh, S.-M. Jang, T.-M. Chen, J. Mater. Chem. 20, 1755 (2010)CrossRefGoogle Scholar
  10. 10.
    P. Du, X. Huang, J.S. Yu, Chem. Eng. J. 337, 91 (2018)CrossRefGoogle Scholar
  11. 11.
    X. Huang, J. Alloys Compd. 690, 356 (2017)CrossRefGoogle Scholar
  12. 12.
    H. Guo, X. Huang, Y. Zeng, J. Alloys Compd. 741, 300 (2018)CrossRefGoogle Scholar
  13. 13.
    X. Huang, B. Li, H. Guo, D. Chen, Dyes Pigm. 143, 86 (2017)CrossRefGoogle Scholar
  14. 14.
    X. Huang, B. Li, H. Guo, J. Alloys Compd. 695, 2773 (2017)CrossRefGoogle Scholar
  15. 15.
    X. Huang, H. Guo, B. Li, J. Alloys Compd. 720, 29 (2017)CrossRefGoogle Scholar
  16. 16.
    B. Li, X. Huang, H. Guo, Y. Zeng, Dyes Pigm. 150, 67 (2018)CrossRefGoogle Scholar
  17. 17.
    G. Li, J. Guoqi, Y. Baozhu, L. Xu, J. Litao, Y. Zhiping, F. Guangsheng, J. Rare Earths 29, 540 (2011)CrossRefGoogle Scholar
  18. 18.
    Q. Long, C. Wang, Y. Li, J. Ding, X. Wang, Y. Wang, Mater. Res. Bull. 71, 21 (2015)CrossRefGoogle Scholar
  19. 19.
    W. Geng, G. Zhu, Y. Shi, Y. Wang, J. Lumin. 155, 205 (2014)CrossRefGoogle Scholar
  20. 20.
    J. Zhao, S.-X. Huang, D. Zhao, J. Chen, Y. Tian, Q. Zong, Y.-C. Fan, C.-K. Nie, B.-Z. Liu, Optik 161, 342 (2018)CrossRefGoogle Scholar
  21. 21.
    X. Zhang, Y. Chen, S. Zeng, L. Zhou, J. Shi, M. Gong, Ceram. Int. 40, 14537 (2014)CrossRefGoogle Scholar
  22. 22.
    J. Li, H. Yan, F. Yan, Optik 127, 4541 (2016)CrossRefGoogle Scholar
  23. 23.
    G. Dillip, B. Ramesh, C.M. Reddy, K. Mallikarjuna, O. Ravi, S. Dhoble, S. Joo, B.D.P. Raju, J. Alloys Compd. 615, 719 (2014)CrossRefGoogle Scholar
  24. 24.
    Y. Liu, Z. Yang, Q. Yu, X. Li, Y. Yang, P. Li, Mater. Lett. 65, 1956 (2011)CrossRefGoogle Scholar
  25. 25.
    G. Sowjanya, R. Moorthy, B. Ch, C. Jayasankar, Spectrochim. Acta A 170, 206 (2017)CrossRefGoogle Scholar
  26. 26.
    X. Zhang, J. Zhang, Y. Chen, Dyes Pigm. 149, 696 (2018)CrossRefGoogle Scholar
  27. 27.
    L. Zhao, D. Meng, Y. Li, Y. Zhang, H. Wang, J. Alloys Compd. 728, 564 (2017)CrossRefGoogle Scholar
  28. 28.
    M. Ferhi, S. Toumi, K. Horchani-Naifer, M. Ferid, J. Alloys Compd. 714, 144 (2017)CrossRefGoogle Scholar
  29. 29.
    W. Wang, J. Li, G. Duan, W. Zhao, B. Cao, Z. Liu, J. Lumin. 192, 1056 (2017)CrossRefGoogle Scholar
  30. 30.
    R. Shrivastava, J. Kaur, V. Dubey, J. Fluoresc. 26, 105 (2016)CrossRefGoogle Scholar
  31. 31.
    Z.-W. Zhang, X.-Y. Sun, L. Liu, Y. Peng,, W.-G. Zhang, D.-J. Wang, X.-h. Shen, Ceram. Int. 39, 1723 (2013)CrossRefGoogle Scholar
  32. 32.
    L. Zhang, H. Zhong, X. Li, L. Cheng, L. Yao, J. Sun, J. Zhang, R. Hua, B. Chen, Phys. B 407, 68 (2012)CrossRefGoogle Scholar
  33. 33.
    X. Zhang, Z. Lu, F. Meng, L. Hu, X. Xu, J. Lin, C. Tang, Mater. Lett. 79, 292 (2012)CrossRefGoogle Scholar
  34. 34.
    G. Blasse, Philips Res. Rep. 24, 131 (1969)Google Scholar
  35. 35.
    G. Blasse, J. Solid State Chem. 62, 207 (1986)CrossRefGoogle Scholar
  36. 36.
    Q. Shao, H. Ding, L. Yao, J. Xu, C. Liang, J. Jiang, RSC Adv. 8, 12035 (2018)CrossRefGoogle Scholar
  37. 37.
    D.L. Dexter, J. Chem. Phys. 21, 836 (1953)CrossRefGoogle Scholar
  38. 38.
    D. Dexter, J.H. Schulman, J. Chem. Phys. 22, 1063 (1954)CrossRefGoogle Scholar
  39. 39.
    L. Van Uitert, J. Electrochem. Soc. 114, 1048 (1967)CrossRefGoogle Scholar
  40. 40.
    Y. Shi, Y. Wang, Z. Yang, J. Alloys Compd. 509, 3128 (2011)CrossRefGoogle Scholar
  41. 41.
    P. Kumari, J. Manam, RSC Adv. 5, 107575 (2015)CrossRefGoogle Scholar
  42. 42.
    Y. Guo, B.K. Moon, B.C. Choi, J.H. Jeong, J.H. Kim, J. Lumin. 181, 96 (2017)CrossRefGoogle Scholar
  43. 43.
    D. Rajesh, M.D. Naidu, Y. Ratnakaram, ‎J. Phys. Chem. Solids 75, 1210 (2014)CrossRefGoogle Scholar
  44. 44.
    U. Fawad, H. Kim, S. Khan, M. Khan, L. Al, Solid State Sci. 62, 1 (2016)CrossRefGoogle Scholar
  45. 45.
    K.V. Krishnaiah, K.U. Kumar, C.K. Jayasankar, Mater. Expr. 3, 61 (2013)CrossRefGoogle Scholar
  46. 46.
    C.-H. Huang, W.-R. Liu, T.-M. Chen, J. Phys. Chem. C 114, 18698 (2010)CrossRefGoogle Scholar
  47. 47.
    H. Guo, B. Devakumar, B. Li, X. Huang, Dyes Pigm. (2017)Google Scholar
  48. 48.
    B. Li, S. Wang, Q. Sun, C. Lu, H. Guo, X. Huang, Dyes Pigm. 154, 252 (2018)CrossRefGoogle Scholar
  49. 49.
    B. Li, Q. Sun, S. Wang, H. Guo, X. Huang, RSC Adv. 8, 9879 (2018)CrossRefGoogle Scholar
  50. 50.
    F. Xiong, S. Liu, H. Lin, X. Meng, S. Lian, W. Zhu, Opt. Laser Technol. 106, 29 (2018)CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Key Lab of Advanced Transducers and Intelligent Control System, Ministry of Education and Shanxi Province, College of Physics and OptoelectronicsTaiyuan University of TechnologyTaiyuanPeople’s Republic of China

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