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Efficient energy transfer and luminescence properties of green–blue emission in Ce/Tb Co-doped Sr3NaY(PO4)3F phosphors

  • Jinling Li
  • Denghui Xu
  • Chao Wei
  • Jiangnan Du
  • Xuedong Gao
  • Xiong Li
  • Jiayue Sun
Article
  • 58 Downloads

Abstract

Ce3+ and Ce3+/Tb3+-activated Sr3NaY(PO4)3F phosphors are synthesized by the high temperature solid-state reaction, which can be efficiently excited by near ultraviolet (NUV) light-emitting diode (LED) chips. The X-ray diffraction profiles (XRD), photoluminescence(PL) spectra, the decay curves, thermal properties and energy transfer of the phosphors were systematically investigated in detail. The PL spectrum of Sr3NaY(PO4)3F:Ce3+/Tb3+ shows a broad hump ranging from 300 to 450 nm of Ce3+ ions and characteristic line of Tb3+ ions. The emission intensity of Tb3+ increased and that of Ce3+ decreased with the increase of content of Tb3+. The color of the Sr3NaY(PO4)3F:Ce3+/Tb3+ phosphors can shift from blue to green by varying Tb3+ content. The decay curves of Sr3NaY(PO4)3F:Ce3+/Tb3+ indicated that energy transfer process from Ce3+ to Tb3+ existed in the host and the quadrupole–quadrupole interaction to be demonstrated for energy transfer mechanism. In addition, the Sr3NaY(PO4)3F:Ce3+/Tb3+ phosphor exhibits excellent thermal stability, 90% initial emission intensity still remained at temperatures over 100 °C. The obtained results reveal that Sr3NaY(PO4)3F:Ce3+/Tb3+ phosphors can be served as a green-emitting candidate material for phosphor-converted white-light NUV-LEDs.

Notes

Acknowledgements

This work was supported by Scientific Research Ability Promotion Plan of Graduate Student of Beijing Technology and Business University; Importation and Development of High-Caliber Talents Project of Beijing Municipal Institutions(CIT&TCD201404030); National Natural Science Foundation of China (Grant Nos. 21576002, 61705003), and Scientific Research Common Program of Beijing Municipal Commission of Education (Grant No. SQKM201710011009).

References

  1. 1.
    E.F. Schubert, J.K. Kim, Solid-state light sources getting smart. Science 308, 1274–1278 (2005)CrossRefGoogle Scholar
  2. 2.
    W. Lu, J. Huo, Y. Feng, S. Zhao, H. You, Photoluminescence, energy transfer and tunable color of Ce3+, Tb3+ and Eu2+ activated oxynitride phosphors with high brightness. Dalton Trans. 45, 9676–9683 (2016)CrossRefGoogle Scholar
  3. 3.
    E. Jang, S. Jun, H. Jang, J. Lim, B. Kim, Y. Kim, White-light-emitting diodes with quantum dot color converters for display backlights. Adv. Mater. 22, 3076–3080 (2010)CrossRefGoogle Scholar
  4. 4.
    Z.F. Yang, D.H. Xu, J.Y. Sun, J.N. Du, X.D. Gao, Luminescence properties and energy transfer investigations of Sr3Lu(PO4)3:Ce3+, Tb3+ phosphors. Mater. Sci. Eng. B 211, 13–19 (2016)CrossRefGoogle Scholar
  5. 5.
    H.Y. Xiao, Z.G. Xia, L.B. Liao, J. Zhou, J.Q. Zhuang, Luminescence properties of a new greenish blue emitting phosphor Na5Ca4(PO4)4F:Eu2+. J. Alloys Compd. 543, 97 (2012)CrossRefGoogle Scholar
  6. 6.
    Z. Xia, A. Meijerink, Ce3+-doped garnet phosphors: composition modification, luminescence properties and applications. Chem. Soc. Rev. 46(1), 275–299 (2017)CrossRefGoogle Scholar
  7. 7.
    N. Guo, Y.J. Huang, M. Yang, Y.H. Song, Y.H. Zheng, H.P. You, A tunable single-component warm white-light Sr3Y(PO4)3:Eu2+, Mn2+ phosphor for white-light emitting diodes. Phys. Chem. 13, 15077 (2011)Google Scholar
  8. 8.
    Q.G. Xu, J.Y. Sun, D.P. Cui, Q.M. Di, J.H. Zeng, Synthesis and luminescence properties of novel Sr3Gd(PO4)3:Dy3+ phosphor. J. Lumin. 158, 301 (2015)CrossRefGoogle Scholar
  9. 9.
    R.J. Yu, B. Deng, G.G. Zhang, Y. An, J.H. Zhang, J. Wang, Luminescence properties of Ce3+-activated SrLaGa3S6O and application in White LEDs. J. Electrochem. Soc. 158, J255–J259 (2011)CrossRefGoogle Scholar
  10. 10.
    W.J. Ding, J. Wang, Z.M. Liu, M. Zhang, Q. Su, J.K. Tang, An intense green/yellow dual-chromatic calcium chlorosilicate phosphor Ca3SiO4Cl2:Eu2+–Mn2+ for yellow and white LED. J. Electrochem. Soc. 155, J122 (2008)CrossRefGoogle Scholar
  11. 11.
    Q.B. Liu, Y.F. Liu, Y.J. Ding, Z.M. Peng, X.D. Tian, Q.M. Yu, G.Y. Dong, A white light emitting luminescent material Ba3Y(PO4)3:Dy3+. Ceram. Int. 40, 10125 (2014)CrossRefGoogle Scholar
  12. 12.
    X. Zhang, J. Zhang, M. Gong, Synthesis and luminescent properties of UV-excited thermal stable red-emitting phosphor Ba3Lu(PO4)3:Eu3+ for NUV LED. Opt. Mater. 36, 850 (2014)CrossRefGoogle Scholar
  13. 13.
    L. Han, Y.M. Sun, J.Y. Sun, Synthesis and luminescence properties of white-light-emitting phosphor Sr3GdNa(PO4)3F:Dy3+. J. Rare. Earths 34, 12–16 (2016)CrossRefGoogle Scholar
  14. 14.
    D.H. Xu, Z.F. Yang, J.Y. Sun, X.D. Gao, J.N. Du, Synthesis and luminescence properties of double-perovskite white emitting phosphor. J. Mater. Sci.: Mater. Electron. 27, 8370–8377 (2016)Google Scholar
  15. 15.
    J.L. Zhang, X.G. Zhang, M.L. Gong, J.X. Shi, L.P. Yu, C.Y. Rong, S.X. Lian, LiSrBO3: Eu2+: a novel broad-band red phosphor under the excitation of a blue light. Mater. Lett. 79, 100 (2012)CrossRefGoogle Scholar
  16. 16.
    D. Wen, G. Yang, H. Yang, J. Shi, M. Gong, M. Wu, Photoluminescence properties of color-tunable novel Na2Ca4(PO4)2SiO4:Ce3+, Tb3+near ultraviolet convertible phosphors. Mater. Lett. 125, 63 (2014)CrossRefGoogle Scholar
  17. 17.
    R.Y. Mi, C.L. Zhao, Z.G. Xia, Synthesis, structure, and tunable luminescence properties of novel Ba3NaLa(PO4)3F:Eu2+, Mn2+ phosphors. J. Am. Ceram. Soc. 97, 1802–1808 (2014)CrossRefGoogle Scholar
  18. 18.
    R. Rudel, F. Zite-Ferenczy, Interpretation of light diffraction by cross-striated muscle as Bragg reflexion of light by the lattice of contractile proteins. J. Physiol. 290, 317–330 (1979)CrossRefGoogle Scholar
  19. 19.
    F. Yang, Y.F. Liu, X.D. Tian, G.Y. Dong, Q.M. Yu, Luminescence properties of phosphate phosphor Ba3Y(PO4)3:Sm3+. J. Solid State Chem. 225, 19–23 (2015)CrossRefGoogle Scholar
  20. 20.
    G. Blasse, Energy transfer in oxidic phosphors. Phys. Lett. A 28, 444–445 (1968)CrossRefGoogle Scholar
  21. 21.
    S.H. Miao, Z.G. Xia, J. Zhang, Q.L. Liu, Increased Eu2+ content and co-doping Mn2+ induced tunable fullcolor emitting phosphor Ba1.55Ca0.45SiO4:Eu2+, Mn2+. Inorg. Chem. 53, 10386 (2014)CrossRefGoogle Scholar
  22. 22.
    G. Blasse, Energy transfer in oxidic phosphors. Philips Res. Rep. 24, 131–144 (1969)Google Scholar
  23. 23.
    R.J. Yu, H.M. Noh, B.K. Moon, B.C. Choi, J.H. Jeong, H.S. Lee, K. Jang, S.S. Yi, Photoluminescence characteristics of Sm3+ doped Ba3La(PO4)3 as new orange-red emitting phosphors. J. Lumin. 145, 717–722 (2014)CrossRefGoogle Scholar
  24. 24.
    L.G. Van Uitert, Characterization of energy transfer interactions between rare earth ions. J. Electrochem. Soc. 114, 1048–1053 (1967)CrossRefGoogle Scholar
  25. 25.
    D. Dexter, J.H. Schulman, Theory of concentration quenching in inorganic phosphors. J. Chem. Phys. 22, 1063–1070 (1954)CrossRefGoogle Scholar
  26. 26.
    Z. Tao, Y. Huang, H.J. Seo, Blue luminescence and structural properties of Ce3+-activated phosphosilicate apatite Sr5(PO4)2(SiO4). Dalton Trans. 42(6), 2121–2129 (2013)CrossRefGoogle Scholar
  27. 27.
    X.G. Zhang, J.H. Song, C.Y. Zhou, L.Y. Zhou, M.L. Gong, High efficiency and broad band blue-emitting NaCaBO3:Ce3+ phosphor for NUV light-emitting diodes. J. Lumin. 149, 69–74 (2014)CrossRefGoogle Scholar
  28. 28.
    J. Barbier, J.E. Greedan, T. Asaro, G.J. McCarthy, Structural features: variant of Bi4(SiO4)3 with the PO4 tetrahedra in orientational disorder. Eur. J. Solid State Inorg. Chem. 27, 855 (1990)Google Scholar
  29. 29.
    A. Balakishna, O.M. Ntwaeborwa, Study of luminescent behavior and crystal defects of different MNa[PO4]-Dy3+ phosphors (M = Mg, Ca, Sr and Ba). Sens. Actuators B 242, 305–317 (2017)CrossRefGoogle Scholar
  30. 30.
    R.J. Xie, N. Hirosaki, 2-phosphor-converted white light-emitting diodes using oxynitride/nitride phosphors. Appl. Phys. Lett. 90, 191101 (2007)CrossRefGoogle Scholar
  31. 31.
    Z.G. Xia, R.S. Liu, K.W. Huang, V. Droid, Ca2Al3O6F:Eu2+: a green-emitting oxyfluoride phosphor for white light-emitting diodes. J. Mater. Chem. 20, 15183–15189 (2014)Google Scholar
  32. 32.
    X. Mi, J. Sun, P. Zhou, H. Zhou, D. Song, K. Li, M. Shang, J. Lin, Tunable luminescence and energy transfer properties in Ca8MgLu(PO4)7:Ce3+,Tb3+,Mn2+ phosphors. J. Mater. Chem. C 3, 4471–4481 (2015)CrossRefGoogle Scholar
  33. 33.
    C. Liang, H.P. You, Y.B. Fu, X.M. Teng, K. Liu, J.H. He, A novel tunable blue–green-emitting CaGdGaAl2O7:Ce3+,Tb3+ phosphor via energy transfer for UV-excited white LEDs. Dalton Trans. 44, 8100 (2015)CrossRefGoogle Scholar
  34. 34.
    J. Zhang, A.L. Yu, Z.H. Hua, S.Z. Wen, Luminescence of emission-tunable Na15.6Ca3.84Si12O36:Ce3+,Tb3+,Na+ phosphors for near-ultraviolet light-emitting diodes. J. Rare Earths 34, 565 (2016)CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of ScienceBeijing Technology and Business UniversityBeijingChina

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