Low-temperature sintered SnO2 electron transport layer for efficient planar perovskite solar cells

  • Yuqian Yang
  • Jihuai WuEmail author
  • Panfeng Guo
  • Xuping Liu
  • Qiyao Guo
  • Quanzhen Liu
  • Hui Luo


Lead amine halide perovskite solar cells (PSCs) have become dominant photovoltaic research topic in this decade. Electron transport layer (ETL) play a crucial role on PSCs. Here, we use tin tetrachloride as Sn source to synthesize SnO2 nanocrystals in a simple hydrothermal method. The as-synthesized SnO2 is spin-coated on FTO substrate, and then sintered under low temperature to form the ETL of planar PSCs. The concentration of SnO2 spin-coating solution and sintering temperature have great influence on the ETL quality and charge transportation in PSCs. Through optimized treatment (0.15 M SnO2, 120 °C sintering), the high quality SnO2 ETL with a uniform coverage, appropriate thickness, less charge recombination and low resistance can be obtained. Based on the ETL, a planar PSC with FAxMA1−xPbI3 achieves a high power conversion efficiency (PCE) of 19.34%. In addition, the planar PSCs based on SnO2 exhibit a stable PCE output and slight hysteresis. These researches provide a low-cost, easy strategy to fabricate tin oxide, and present potential to replace traditional titanium oxide (TiO2) in PSCs in the future.



The authors acknowledge the financial joint support by the National Natural Science Foundation of China (Nos. U1705256, 91422301, 51472094, 61474047).


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Authors and Affiliations

  1. 1.Engineering Research Center of Environment-Friendly Functional Materials for Ministry of Education, Fujian Provincial Key Laboratory of Photoelectric Functional Materials, Institute of Materials Physical ChemistryHuaqiao UniversityXiamenChina

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