Enhancement in thermoelectric performance of Cu3SbSe4 thin films by In(III) doping; synthesized by arrested precipitation technique
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Abstract
We have successfully synthesized p-type Cu3(Sb1−xInx)Se4 thin films by solution based arrested precipitation technique and studied their thermoelectric properties for the first time. The deposited thin films were characterized for their structural, morphological, compositional and electrical transport properties. Thin films shows enhancement in figure of merit (ZT) with increasing In(III) content. The maximum ZT 0.267 obtained for Cu3(Sb0.92In0.08)Se4 thin film at 300 K.
Notes
Acknowledgements
One of the authors VBG is thankful to Department of Chemistry, Yashwantrao Chavan Institute of Science, Satara. This research work was supported by Basics Science Research Program through the National Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2014R1A2054051). This work was also supported by Korea Research Fellowship Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (2016H1D3A1909289) for an outstanding overseas young researcher (Dr. Sawanta S. Mali).
References
- 1.B. Poudel, Q. Hao, Y. Ma et al., High-thermoelectric performance of nanostructured bismuth antimony telluride bulk alloys. Science 320, 634–638 (2008). https://doi.org/10.1126/science.1156446 CrossRefGoogle Scholar
- 2.E. Li, N. Wang, H. He, H. Chen, Improved thermoelectric performances of SrTiO3 ceramic doped with Nb by surface modification of nanosized titania. Nanoscale Res. Lett. 11, 188 (2016). https://doi.org/10.1186/s11671-016-1407-8 CrossRefGoogle Scholar
- 3.K. Kadel, L. Kumari, X. Wang et al., Synthesis and structure of undoped and indium-doped thermoelectric lead telluride nanoparticles. Nanoscale Res. Lett. 9, 227 (2014). https://doi.org/10.1186/1556-276X-9-227 CrossRefGoogle Scholar
- 4.M.L. Snedaker, Y. Zhang, C.S. Birkel et al., Silicon-based thermoelectrics made from a boron-doped silicon dioxide nanocomposite. Chem. Mater. 25, 4867–4873 (2013). https://doi.org/10.1021/cm401990c CrossRefGoogle Scholar
- 5.C.J. Vineis, A. Shakouri, A. Majumdar, M.G. Kanatzidis, Nanostructured thermoelectrics: big efficiency gains from small features. Adv. Mater. 22, 3970–3980 (2010). https://doi.org/10.1002/adma.201000839 CrossRefGoogle Scholar
- 6.D. Pinisetty, R.V. Devireddy, Thermal conductivity of semiconductor (bismuth–telluride)–semimetal (antimony) superlattice nanostructures. Acta Mater. 58, 570–576 (2010). https://doi.org/10.1016/j.actamat.2009.09.035 CrossRefGoogle Scholar
- 7.C. Chiritescu, D.G. Cahill, N. Nguyen et al., Ultra-low thermal conductivity in W/Al2O3 nanolaminates. Science 303, 989–990 (2004). https://doi.org/10.1126/science.1093711 CrossRefGoogle Scholar
- 8.J. Zhou, R. Yang, Quantum and classical thermoelectric transport in quantum dot nanocomposites. J. Appl. Phys. 110, 084317–084329 (2011). https://doi.org/10.1063/1.3653263 CrossRefGoogle Scholar
- 9.P.K. Rawat, B. Paul, P. Banerji, Exploration of Zn resonance levels and thermoelectric properties in I-doped PbTe with ZnTe nanostructures. ACS Appl Mater Interfaces 6, 3995–4004 (2014). https://doi.org/10.1021/am405410e CrossRefGoogle Scholar
- 10.V.B. Ghanwat, S.S. Mali, C.S. Bagade et al., Thermoelectric properties of indium (III)-doped copper antimony selenide thin films deposited using a microwave-assisted technique. Energy Technol. 4, 835–842 (2016). https://doi.org/10.1002/ente.201500508 CrossRefGoogle Scholar
- 11.Q. Zhang, H. Wang, W. Liu et al., Enhancement of thermoelectric figure-of-merit by resonant states of aluminium doping in lead selenide. Energy Environ. Sci. 5, 5246–5251 (2012). https://doi.org/10.1039/C1EE02465E CrossRefGoogle Scholar
- 12.R.B. Balow, E.P. Tomlinson, M.M. Abu-omar et al., Solution-based synthesis and characterization of earth abundant Cu3(As,Sb)Se4 nanocrystal alloys: towards scalable room-temperature thermoelectric devices. J. Mater. Chem. A 4, 2198–2204 (2016). https://doi.org/10.1039/C5TA07546G CrossRefGoogle Scholar
- 13.C. Yang, F. Huang, L. Wu, K. Xu, New stannite-like p-type thermoelectric material Cu3SbSe4. J. Phys. D 44, 295404–295408 (2011). https://doi.org/10.1088/0022-3727/44/29/295404 CrossRefGoogle Scholar
- 14.X.Y. Li, D. Li, H.X. Xin et al., Effects of bismuth doping on the thermoelectric properties of Cu3SbSe4 at moderate temperatures. J. Alloys Compd. 561, 105–108 (2013). https://doi.org/10.1016/j.jallcom.2013.01.131 CrossRefGoogle Scholar
- 15.D. Tang, J. Yang, F. Liu et al., One-step electrodeposition and annealing of CuSbSe2 thin films. Electrochem. Solid-State Lett. 15, D11–D13 (2011). https://doi.org/10.1149/2.007202esl CrossRefGoogle Scholar
- 16.D. Li, R. Li, X.Y. Qin et al., Co-precipitation synthesis of nanostructured Cu3SbSe4 and its Sn-doped sample with high thermoelectric performance. Dalton Trans. 43, 1888–1896 (2014). https://doi.org/10.1039/C3DT52447G CrossRefGoogle Scholar
- 17.J. Zhou, G.Q. Bian, Q.Y. Zhu et al., Solvothermal crystal growth of CuSbQ2 (Q = S, Se) and the correlation between macroscopic morphology and microscopic structure. J. Solid State Chem. 182, 259–264 (2009). https://doi.org/10.1016/j.jssc.2008.10.025 CrossRefGoogle Scholar
- 18.Y. Liu, J. Yang, E. Gu et al., Colloidal synthesis and characterisation of Cu3SbSe3 nanocrystals. J. Mater. Chem. A 2, 6363–6367 (2014). https://doi.org/10.1039/c4ta00085d CrossRefGoogle Scholar
- 19.C.S. Bagade, S.S. Mali, V.B. Ghanwat et al., A facile and low cost strategy to synthesize Cd1–xZnxSe thin films for photoelectrochemical performance: effect of zinc content. RSC Adv. 5, 55658–55668 (2015). https://doi.org/10.1039/C5RA08791K CrossRefGoogle Scholar
- 20.K.V. Khot, S.S. Mali, N.B. Pawar et al., Development of nanocoral-like Cd(SSe) thin films using an arrested precipitation technique and their application. New J. Chem. 38, 5964–5974 (2014). https://doi.org/10.1039/C4NJ01319K CrossRefGoogle Scholar
- 21.W. Li, M. Ibáñez, R.R. Zamani et al., Cu2HgSnSe4 nanoparticles: synthesis and thermoelectric properties. CrystEngComm 15, 8966–8971 (2013). https://doi.org/10.1039/c3ce41583j CrossRefGoogle Scholar
- 22.I.-H. Kim, S.-M. Choi, W.-S. Seo, D.-I. Cheong, Thermoelectric properties of Cu-dispersed bi0.5sb1.5te3. Nanoscale Res. Lett. 7, 2 (2012). https://doi.org/10.1186/1556-276X-7-2 CrossRefGoogle Scholar
- 23.V.B. Ghanwat, S.S. Mali, R.M. Mane et al., Thermoelectric properties of nanocrystalline Cu3SbSe4 thin films deposited by a self-organized arrested precipitation technique. New J. Chem. 39, 5661–5668 (2015). https://doi.org/10.1039/C5NJ00686D CrossRefGoogle Scholar
- 24.V.B. Ghanwat, S.S. Mali, S.D. Kharade et al., Microwave assisted synthesis, characterization and thermoelectric properties of nanocrystalline copper antimony selenide thin films. RSC Adv. 4, 51632–51639 (2014). https://doi.org/10.1039/C4RA07609E CrossRefGoogle Scholar
- 25.H. Kou, Y. Jiang, J. Li et al., Enhanced photoelectric performance of Cu2–xSe nanostructure by doping with In3+. J. Mater. Chem. 22, 1950–1956 (2012). https://doi.org/10.1039/c1jm14507j CrossRefGoogle Scholar
- 26.D. Tahir, S. Tougaard, Electronic and optical properties of Cu, CuO and Cu2O studied by electron spectroscopy. J. Phys. Condens. Matter 24, 175002–175009 (2012). https://doi.org/10.1088/0953-8984/24/17/175002 CrossRefGoogle Scholar
- 27.K. Sasaki, K. Takatsugi, K. Ishikura, T. Hirajima, Spectroscopic study on oxidative dissolution of chalcopyrite, enargite and tennantite at different pH values. Hydrometallurgy 100, 144–151 (2010). https://doi.org/10.1016/j.hydromet.2009.11.007 CrossRefGoogle Scholar
- 28.W.L. Li, S.Q. Lie, Y.Q. Du et al., Hydrophilic Cu2–xSe/reduced graphene oxide nanocomposites with tunable plasmonic properties and their applications in cellular dark-field microscopic imaging. J. Mater. Chem. B 2, 7027–7033 (2014). https://doi.org/10.1039/C4TB01099J CrossRefGoogle Scholar
- 29.N. Pollock, G. Fowler, L.J. Twyman, S.L. McArthur, Synthesis and characterization of immobilized PAMAM dendrons. Chem. Commun. 2007, 2482–2484 (2007). https://doi.org/10.1039/b701550j CrossRefGoogle Scholar
- 30.S. Aminorroaya-Yamini, C. Zhang, X. Wang, I. Nevirkovets, Crystal structure, electronic structure and thermoelectric properties of n-type BiSbSTe2. J. Phys. D 45, 125301–125306 (2012). https://doi.org/10.1088/0022-3727/45/12/125301 CrossRefGoogle Scholar
- 31.P. Liu, S. Yu, W. Fan, W. Shi, A new inorganic–organic hybrid In2Se3(en) as hollow nanospheres: hydrothermal synthesis and near-infrared photoluminescence properties. Dalton Trans. 42, 2887–2893 (2013). https://doi.org/10.1039/c2dt32589f CrossRefGoogle Scholar
- 32.H.L. Poh, P. Šimek, Z. Sofer et al., Boron and nitrogen doping of graphene via thermal exfoliation of graphite oxide in a BF3 or NH3 atmosphere: contrasting properties. J. Mater. Chem. A 1, 13146–13153 (2013). https://doi.org/10.1039/c3ta12460f CrossRefGoogle Scholar
- 33.Y. Liang, B. Kong, A. Zhu et al., A facile and efficient strategy for photoelectrochemical detection of cadmium ions based on in situelectrodeposition of CdSe clusters on TiO2 nanotubes. Chem. Commun. 48, 245–247 (2012). https://doi.org/10.1039/C1CC16060E CrossRefGoogle Scholar